scholarly journals Novel Al2O3/GO/halloysite nanotube composite for sequestration of anionic and cationic dyes

RSC Advances ◽  
2019 ◽  
Vol 9 (24) ◽  
pp. 13916-13926 ◽  
Author(s):  
M. A. Barakat ◽  
Rajeev Kumar ◽  
M. Balkhyour ◽  
Md. Abu Taleb

In this study, an Al2O3/graphene oxide/halloysite nanotube (Al2O3/GO/HNT) nanocomposite has been synthesized and used as an adsorbent for the sequestration of cationic methylene blue (MB) and anionic congo red (CR) dyes from wastewater.

2021 ◽  
Author(s):  
Lijuan Zhang ◽  
Dongqing Zhao ◽  
Yao Lu ◽  
Jinghan Chen ◽  
Haotian Li ◽  
...  

A highly efficient strategy was developed to fabricate graphene oxide modified cellulose nanocrystal/PNIPAAm IPN (GO-CNC/PNIPAAm IPN) hydrogel, which was capable of effectively adsorbing cationic and anionic dyes. The adsorption of...


Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1917
Author(s):  
Guangpu Zhang ◽  
Rong Wo ◽  
Zhe Sun ◽  
Gazi Hao ◽  
Guigao Liu ◽  
...  

A magnetic metal−organic frameworks adsorbent (Fe3O4@MIL-53(Al)) was prepared by a typical solvothermal method for the removal of bisphenol A (BPA), tetracycline (TC), congo red (CR), and methylene blue (MB). The prepared Fe3O4@MIL-53(Al) composite adsorbent was well characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), and fourier transform infrared spectrometer (FTIR). The influence of adsorbent quantity, adsorption time, pH and ionic strength on the adsorption of the mentioned pollutants were also studied by a UV/Vis spectrophotometer. The adsorption capacities were found to be 160.9 mg/g for BPA, 47.8 mg/g for TC, 234.4 mg/g for CR, 70.8 mg/g for MB, respectively, which is superior to the other reported adsorbents. The adsorption of BPA, TC, and CR were well-fitted by the Langmuir adsorption isotherm model, while MB followed the Freundlich model, while the adsorption kinetics data of all pollutants followed the pseudo-second-order kinetic models. The thermodynamic values, including the enthalpy change (ΔH°), the Gibbs free energy change (ΔG°), and entropy change (ΔS°), showed that the adsorption processes were spontaneous and exothermic entropy-reduction process for BPA, but spontaneous and endothermic entropy-increasing processes for the others. The Fe3O4@MIL-53(Al) was also found to be easily separated after external magnetic field, can be a potential candidate for future water treatment.


2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Gen Liu ◽  
Wei Ma ◽  
Yan Luo ◽  
Deng-ming Sun ◽  
Shuang Shao

Poly(methylene blue) and electrochemically reduced graphene oxide composite film modified electrode (PMB-ERGO/GCE) was successfully fabricated by electropolymerization and was used for simultaneous determination of uric acid (UA) and xanthine (Xa). Based on the excellent electrocatalytic activity of PMB-ERGO/GCE, the electrochemical behaviors of UA and Xa were studied by cyclic voltammetry (CV) and square wave voltammetry (SWV). Two anodic sensitive peaks at 0.630 V (versus Ag/AgCl) for UA and 1.006 V (versus Ag/AgCl) for Xa were given by CV in pH 3.0 phosphate buffer. The calibration curves for UA and Xa were obtained in the range of 8.00 × 10−8~4.00 × 10−4 M and 1.00 × 10−7~4.00 × 10−4 M, respectively, by SWV. The detection limits for UA and Xa were3.00×10-8 M and5.00×10-8 M, respectively. Finally, the proposed method was applied to simultaneously determine UA and Xa in human urine with good selectivity and high sensitivity.


Author(s):  
K. D. R. N. Kalubowila ◽  
M. Siyath Gunewardene ◽  
J. Lakmini Kaushalya Jayasingha ◽  
Dhammike Dissanayake ◽  
Charith Jayathilaka ◽  
...  

Plants ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 384
Author(s):  
Ahmed Labena ◽  
Ahmed E. Abdelhamid ◽  
Abeer S. Amin ◽  
Shimaa Husien ◽  
Liqaa Hamid ◽  
...  

Biosorption is a bioremediation approach for the removal of harmful dyes from industrial effluents using biological materials. This study investigated Methylene blue (M. blue) and Congo red (C. red) biosorption from model aqueous solutions by two marine macro-algae, Ulva fasciata and Sargassum dentifolium, incorporated within acrylic fiber waste to form composite membranes, Acrylic fiber-U. fasciata (AF-U) and Acrylic fiber-S. dentifolium (AF-S), respectively. The adsorption process was designed to more easily achieve the 3R process, i.e., removal, recovery, and reuse. The process of optimization was implemented through one factor at a time (OFAT) experiments, followed by a factorial design experiment to achieve the highest dye removal efficiency. Furthermore, isotherm and kinetics studies were undertaken to determine the reaction nature. FT-IR and SEM analyses were performed to investigate the properties of the membrane. The AF-U membrane showed a significant dye removal efficiency, of 88.9% for 100 ppm M. blue conc. and 79.6% for 50 ppm C. red conc. after 240 min sorption time. AF-S recorded a sorption capacity of 82.1% for 100 ppm M. blue conc. after 30 min sorption time and 85% for 100 ppm C. red conc. after 240 min contact time. The membranes were successfully applied in the 3Rs process, in which it was found that the membranes could be used for five cycles of the removal process with stable efficiency.


Sign in / Sign up

Export Citation Format

Share Document