scholarly journals Facile synthesis of aminated indole-based porous organic polymer for highly selective capture of CO2 by the coefficient effect of π–π-stacking and hydrogen bonding

RSC Advances ◽  
2019 ◽  
Vol 9 (21) ◽  
pp. 11851-11854 ◽  
Author(s):  
Qiang He ◽  
Yi Xu ◽  
Xiaoqiang Yang

It was demonstrated that the coefficient effect endows POP PIN-NH2 with outstanding CO2 absorption capacity and high selectivity.

2019 ◽  
Vol 136 (39) ◽  
pp. 47987 ◽  
Author(s):  
Yajing Li ◽  
Haijiang Wang ◽  
Weifeng Zhao ◽  
Xiaoqin Wang ◽  
Yidong Shi ◽  
...  

2021 ◽  
Vol 582 ◽  
pp. 631-637
Author(s):  
Lingchang Jiang ◽  
Pengyuan Wang ◽  
Yanju Wang ◽  
Yangang Wang ◽  
Xi Li ◽  
...  

Author(s):  
Chong Zhang ◽  
Zifang Peng ◽  
Yun Guo ◽  
Yanhao Zhang ◽  
Wuduo Zhao ◽  
...  

2020 ◽  
Vol 11 (27) ◽  
pp. 4382-4386
Author(s):  
Shengtai Hou ◽  
Xian Suo ◽  
Nanqing Chen ◽  
Pengfei Zhang ◽  
Sheng Dai

Synthesis of the linear porous organic polymer (L-POP) for selective separation of acetylene (C3H4) from ethylene (C3H6).


RSC Advances ◽  
2021 ◽  
Vol 11 (61) ◽  
pp. 38820-38828
Author(s):  
Yujie Sun ◽  
Zhenzhong Lu ◽  
Wenlin Ma ◽  
Rui Wang ◽  
Chengwu Zhang ◽  
...  

This communication reports a simple and efficient fluorescent biosensing platform to simultaneously detect multiplexed DNA depending on porous organic polymer (POP) nanospheres by electrostatic attraction and π–π stacking interaction.


2020 ◽  
Author(s):  
Abhishek Singh ◽  
Reman K. Singh ◽  
G Naresh Patwari

The rational design of conformationally controlled foldable modules can lead to a deeper insight into the conformational space of complex biological molecules where non-covalent interactions such as hydrogen bonding and π-stacking are known to play a pivotal role. Squaramides are known to have excellent hydrogen bonding capabilities and hence, are ideal molecules for designing foldable modules that can mimic the secondary structures of bio-molecules. The π-stacking induced folding of bis-squaraines tethered using aliphatic primary and secondary-diamine linkers of varying length is explored with a simple strategy of invoking small perturbations involving the length linkers and degree of substitution. Solution phase NMR investigations in combination with molecular dynamics simulations suggest that bis-squaraines predominantly exist as extended conformations. Structures elucidated by X-ray crystallography confirmed a variety of folded and extended secondary conformations including hairpin turns and 𝛽-sheets which are determined by the hierarchy of π-stacking relative to N–H···O hydrogen bonds.


2020 ◽  
Author(s):  
Abhishek Singh ◽  
Reman K. Singh ◽  
G Naresh Patwari

The rational design of conformationally controlled foldable modules can lead to a deeper insight into the conformational space of complex biological molecules where non-covalent interactions such as hydrogen bonding and π-stacking are known to play a pivotal role. Squaramides are known to have excellent hydrogen bonding capabilities and hence, are ideal molecules for designing foldable modules that can mimic the secondary structures of bio-molecules. The π-stacking induced folding of bis-squaraines tethered using aliphatic primary and secondary-diamine linkers of varying length is explored with a simple strategy of invoking small perturbations involving the length linkers and degree of substitution. Solution phase NMR investigations in combination with molecular dynamics simulations suggest that bis-squaraines predominantly exist as extended conformations. Structures elucidated by X-ray crystallography confirmed a variety of folded and extended secondary conformations including hairpin turns and 𝛽-sheets which are determined by the hierarchy of π-stacking relative to N–H···O hydrogen bonds.


2017 ◽  
Vol 35 (7) ◽  
pp. 688
Author(s):  
Hongwei WANG ◽  
Zhongshan LIU ◽  
Xiaojun PENG ◽  
Junjie OU ◽  
Mingliang YE

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