Homochiral versus racemic polymorphs of spin-crossover iron(ii) complexes with reversible LIESST effect

2020 ◽  
Vol 7 (5) ◽  
pp. 1196-1204 ◽  
Author(s):  
Ting-Ting Ma ◽  
Xiao-Peng Sun ◽  
Zi-Shuo Yao ◽  
Jun Tao
Keyword(s):  
Intermolecular Interactions ◽  
Spin Crossover ◽  
Liesst Effect

Homochiral and racemic polymorphs show different spin-crossover behaviours due to different intermolecular interactions, and reversible LIESST effects can be realized on homochiral complexes.

Spin-Crossover Behaviors of Iron(III) Compounds with Strong Intermolecular Interactions

2006 ◽  
Vol 79 (3) ◽  
pp. 442-450 ◽  
Author(s):  
Shinya Hayami ◽  
Soushi Miyazaki ◽  
Masahiko Yamamoto ◽  
Kenji Hiki ◽  
Natsuko Motokawa ◽  
...  
Keyword(s):  
Intermolecular Interactions ◽  
Spin Crossover

scholarly journals Monte-Carlo simulations of spin-crossover phenomena based on a vibronic Ising-like model with realistic parameters

2015 ◽  
Vol 17 (10) ◽  
pp. 6801-6808 ◽  
Author(s):  
Hong-Zhou Ye ◽  
Chong Sun ◽  
Hong Jiang
Keyword(s):  
Monte Carlo ◽  
Monte Carlo Simulations ◽  
Intermolecular Interactions ◽  
Spin Crossover ◽  
Thermal Hysteresis

A new vibronic Ising-like model considering harmonic stretching-and-bending intermolecular interactions with realistic parameters describes thermal hysteresis in spin-crossover phenomena well.

Evidencing size-dependent cooperative effects on spin crossover nanoparticles following their HS→LS relaxation

2018 ◽  
Vol 6 (46) ◽  
pp. 12698-12706 ◽  
Author(s):  
Teresa Delgado ◽  
Cristian Enachescu ◽  
Antoine Tissot ◽  
Andreas Hauser ◽  
Laure Guénée ◽  
...  
Keyword(s):  
Spin State ◽  
Spin Crossover ◽  
Size Dependence ◽  
Relaxation Mechanism ◽  
Cooperative Effects ◽  
Size Dependent ◽  
Liesst Effect

The size dependence of the relaxation mechanism after photo-excitation through the Light-Induced Excited Spin-State Trapping (LIESST) effect of [Fe(pz)Pt(CN)4] micro- and nanoparticles is evidenced experimentally and simulated in the framework of the mechanoelastic model.

Critical temperature of the LIESST effect in iron(II) spin crossover compounds

1999 ◽  
Vol 313 (1-2) ◽  
pp. 115-120 ◽  
Author(s):  
Jean-François Létard ◽  
Laurence Capes ◽  
Guillaume Chastanet ◽  
Nicolas Moliner ◽  
Sylvie Létard ◽  
...  
Keyword(s):  
Critical Temperature ◽  
Spin Crossover ◽  
Liesst Effect

scholarly journals Photo-switching spin pairs—synergy between LIESST effect and magnetic interaction in an iron(ii) binuclear spin-crossover compound

2001 ◽  
pp. 819-820 ◽  
Author(s):  
Guillaume Chastanet ◽  
Jean-François Létard ◽  
Ana B. Gaspar ◽  
José Antonio Real
Keyword(s):  
Spin Crossover ◽  
Magnetic Interaction ◽  
Liesst Effect ◽  
Spin Pairs

scholarly journals Dilution Effects in a Spin Crossover System, Modelled in Terms of Direct and Indirect Intermolecular Interactions

1996 ◽  
Vol 6 (9) ◽  
pp. 1203-1216 ◽  
Author(s):  
H. Constant-Machado ◽  
J. Linares ◽  
F. Varret ◽  
J. G. Haasnoot ◽  
J. P. Martin ◽  
...  
Keyword(s):  
Intermolecular Interactions ◽  
Spin Crossover ◽  
Dilution Effects
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