High temperature Fe(iii) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes

2020 ◽  
Vol 7 (7) ◽  
pp. 1526-1531
Author(s):  
Zhi-Jian Ouyang ◽  
Xiao-Ying Mo ◽  
Meng Yang ◽  
Li Zhong ◽  
Wen-Bin Chen ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Trinuclear Complexes

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H3ATD) was used to synthesize three FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal FeIII ions.

scholarly journals Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding

2015 ◽  
Vol 22 (1) ◽  
pp. 331-339 ◽  
Author(s):  
Sipeng Zheng ◽  
Niels R. M. Reintjens ◽  
Maxime A. Siegler ◽  
Olivier Roubeau ◽  
Elisabeth Bouwman ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
High Temperature ◽  
Spin State ◽  
Spin Crossover ◽  
Mononuclear Iron

High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex

2014 ◽  
Vol 53 (19) ◽  
pp. 10009-10011 ◽  
Author(s):  
Joanna Palion-Gazda ◽  
Anna Świtlicka-Olszewska ◽  
Barbara Machura ◽  
Thais Grancha ◽  
Emilio Pardo ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover

High-temperature spin crossover in the [Fe(L)2][Fe(L)(NCS)3](NCS)·2H2O complex, L=tris(pyrazol-1-yl)methane

Polyhedron ◽  
2012 ◽  
Vol 31 (1) ◽  
pp. 64-68 ◽  
Author(s):  
O.G. Shakirova ◽  
L.G. Lavrenova ◽  
D.Yu. Naumov ◽  
V.A. Daletsky ◽  
L.A. Sheludyakova
Keyword(s):  
High Temperature ◽  
Spin Crossover

Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine

2020 ◽  
Vol 44 (15) ◽  
pp. 5834-5840 ◽  
Author(s):  
A. D. Ivanova ◽  
E. V. Korotaev ◽  
V. Yu. Komarov ◽  
L. A. Sheludyakova ◽  
V. A. Varnek ◽  
...  
Keyword(s):  
High Temperature ◽  
Coordination Compounds ◽  
Spin Crossover

Novel iron(ii) bromide, nitrate and dicyanamide complexes with 2,6-bis(benzimidazol-2-yl)pyridine possessing high-temperature 1A1 ↔ 5T2 spin crossover were obtained.

High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine

2020 ◽  
Vol 65 (11) ◽  
pp. 1687-1694
Author(s):  
A. D. Ivanova ◽  
L. G. Lavrenova ◽  
E. V. Korotaev ◽  
S. V. Trubina ◽  
L. A. Sheludyakova ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover

High-temperature photo-induced switching and pressure-induced transition in a cooperative molecular spin-crossover material

2014 ◽  
Vol 43 (2) ◽  
pp. 729-737 ◽  
Author(s):  
Gavin A. Craig ◽  
Jose Sánchez Costa ◽  
Olivier Roubeau ◽  
Simon J. Teat ◽  
Helena J. Shepherd ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Molecular Spin

High-Temperature Spin Crossover Behavior in a Nitrogen-Rich FeIII-Based System

2013 ◽  
Vol 52 (4) ◽  
pp. 1825-1831 ◽  
Author(s):  
Cyril Cook ◽  
Fatemah Habib ◽  
Tomoko Aharen ◽  
Rodolphe Clérac ◽  
Anguang Hu ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Crossover Behavior

High temperature spin crossover in [Fe(pyrazine){Ag(CN)2}2] and its solvate

2016 ◽  
Vol 40 (11) ◽  
pp. 9012-9016 ◽  
Author(s):  
Il'ya A. Gural'skiy ◽  
Sergii I. Shylin ◽  
Bohdan O. Golub ◽  
Vadim Ksenofontov ◽  
Igor O. Fritsky ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Metal Organic Framework ◽  
Spin Transition ◽  
Thermally Induced ◽  
Metal Organic ◽  
Organic Framework

Thermally induced spin transition at 370 K has been observed in a Hofmann-clathrate-like metal–organic framework.

Reversible thermo-induced spin crossover in a mononuclear cis-dicyanamido-cobalt(ii) complex containing a macrocyclic tetradentate ligand

2020 ◽  
Vol 49 (27) ◽  
pp. 9208-9212 ◽  
Author(s):  
Subrata Ghosh ◽  
Subramani Selvamani ◽  
Sakshi Mehta ◽  
Abhishake Mondal
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Tetradentate Ligand ◽  
Mononuclear Cobalt ◽  
Crossover Behavior ◽  
First Time

For the first time, a mononuclear cobalt(ii) complex with dicyanamide coligands exhibiting reversible spin crossover behavior at high temperature is reported.

scholarly journals Cooperative High-Temperature Spin Crossover Accompanied by a Highly Anisotropic Structural Distortion

2016 ◽  
Vol 2016 (19) ◽  
pp. 3191-3195 ◽  
Author(s):  
Il'ya A. Gural'skiy ◽  
Bohdan O. Golub ◽  
Sergii I. Shylin ◽  
Vadim Ksenofontov ◽  
Helena J. Shepherd ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Structural Distortion
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