Regulating the structural dimensionality and dynamic properties of a porous dysprosium coordination polymer through solvent molecules

2020 ◽  
Vol 7 (4) ◽  
pp. 930-938
Author(s):  
Fang Ma ◽  
Rong Sun ◽  
Ai-Huan Sun ◽  
Jin Xiong ◽  
Hao-Ling Sun ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Dynamic Behavior ◽  
Quantum Tunneling ◽  
Dynamic Properties ◽  
Effective Energy ◽  
Energy Barriers ◽  
Structural Dimensionality ◽  
Solvent Molecules

The solvent molecules can regulate the structural dimensionality of a porous dysprosium coordination polymer from three to two and its dynamic behavior, as evidenced by the increase of the effective energy barriers and slowdown of quantum tunneling.

scholarly journals Crystal structure ofcatena-poly[hemi[1,3-bis(2,6-diisopropylphenyl)imidazolium] [[μ3-acetato-κ3O:O:O′-tri-μ2-acetato-κ6O:O′-dicopper(II)(Cu—Cu)]-μ-chlorido] dichloromethane sesquisolvate]

2015 ◽  
Vol 71 (8) ◽  
pp. m148-m149
Author(s):  
Mohammad Iqbal ◽  
James Raftery ◽  
Peter Quayle
Keyword(s):  
Coordination Polymer ◽  
Rotation Axis ◽  
Metal Organic Framework ◽  
Solvent Molecule ◽  
Central Metal ◽  
Imidazolium Cation ◽  
One Dimensional ◽  
Paddle Wheel ◽  
Internuclear Axis ◽  
Solvent Molecules

The title copper(II) complex, {(C27H37N2)[Cu4(CH3COO)8Cl]·3CH2Cl2}n, is a one-dimensional coordination polymer. The asymmetric unit is composed of a copper(II) tetraacetate paddle-wheel complex, a Cl−anion situated on a twofold rotation axis, half a 1,3-bis(2,6-diisopropylphenyl)imidazolium cation (the whole molecule being generated by twofold rotation symmetry) and one and a half of a dichloromethane solvent molecule (one being located about a twofold rotation axis). The central metal-organic framework comprises of a tetranuclear copper(II) acetate `paddle-wheel' complex which arises from the dimerization of the copper(II) tetraacetate core comprising of three μ2-bidentate acetate and one μ3-tridentate acetate ligands per binuclear paddle-wheel complex. Both CuIIatoms of the binuclear component adopt a distorted square-pyramidal coordination geometry (τ = 0.04), with a Cu...Cu separation of 2.6016 (2) Å. The apical coordination site of one CuIIatom is occupied by an O atom of a neighbouring acetate bridge [Cu—O = 2.200 (2) Å], while that of the second CuIIatom is occupied by a bridging chloride ligand [Cu...Cl = 2.4364 (4) Å]. The chloride bridge is slightly bent with respect to the Cu...Cu internuclear axis [Cu—Cl—Cu = 167.06 (6)°] and the tetranuclear units are located about a twofold rotation axis, forming the one-dimensional polymer that propagates along [101]. Charge neutrality is maintained by the inclusion of the 1,3-bis(2,6-diisopropylphenyl)imidazolium cation within the crystal lattice. In the crystal, the cation and dichloromethane solvent molecules are linked to the coordination polymer by various C—H...O and C—H...Cl hydrogen bonds. There are no other significant intermolecular interactions present.

Modeling and Experimental Characterization of Viscoelastic 3D Printed Spring/Damper Systems

2017 ◽  
Author(s):  
Heather L. Lai ◽  
Cuiyu Kuang ◽  
Jared Nelson
Keyword(s):  
Dynamic Behavior ◽  
Material Properties ◽  
Dynamic Properties ◽  
Viscoelastic Materials ◽  
Vibration Isolators ◽  
Damping Behavior ◽  
Wide Range ◽  
3D Printed ◽  
Printed Materials

The development of flexible, viscoelastic materials for consumer 3D printers has provided the opportunity for a wide range of devices with damping behavior such as tuned vibration isolators to be innovatively developed and inexpensively manufactured. However, there is currently little information available about the dynamic behavior of these 3D printed materials necessary for modeling of dynamic behavior prior to print. In order to fully utilize these promising materials, a deeper understanding of the material properties, and the subsequent dynamic behavior is critical. This study evaluates the use of three different types of models: transient response, frequency response and hysteretic response to predict the dynamic behavior of viscoelastic 3D printed materials based on static and dynamic material properties. Models of viscoelastic materials are presented and verified experimentally using two 3D printable materials and two traditional viscoelastic materials. The experimental response of each of the materials shows agreement with the modeled behavior, and underscores the need for improved characterization of the dynamic properties of viscoelastic 3D printable materials.

Effect of Aging Treatment on Dynamic Behavior of Mg-Gd-Y Alloy

2012 ◽  
Vol 13 (2) ◽  
pp. 111-116
Author(s):  
Lin Wang ◽  
Qiao-Yun Qin ◽  
Fan Zhang ◽  
Cheng-Wen Tan
Keyword(s):  
Plastic Deformation ◽  
Rare Earth ◽  
Magnesium Alloy ◽  
Dynamic Behavior ◽  
Deformation Mechanism ◽  
Dynamic Properties ◽  
Dynamic Compression ◽  
Aging Treatment ◽  
Dislocation Slip ◽  
Plastic Deformation Mechanism

Abstract Magnesium alloy is very attractive in many industrial applications due to its low density. The structure-property relationships of the magnesium alloy under quasi-static loading have been extensively investigated. However, the dynamic behavior, particularly the mechanism of high-rate plastic deformation, of the magnesium alloy requires more in-depth investigations. In this paper, the effect of aging treatment on the quasi-static and dynamic properties of a typical rare earth Mg-Gd-Y magnesium alloy is investigated. In particular, the plastic deformation mechanism under dynamic compression loading is discussed. Split Hopkinson Pressure Bar (SHPB) was used to carry out dynamic compression tests with controllable plastic deformation by using stopper rings. The experimental results demonstrate that both static and dynamic properties of the Mg-Gd-Y alloy vary under various aging treatment conditions (under-aged, peak-aged and over-aged conditions), due to two different kinds of second phases: remnant micro size phase from solid solution treatment and nano precipitation from aging treatment. The results of microstructure characterization and statistic analysis of the metallographic phase are presented. The area fraction of the twinned grains increases due to aging treatment and dynamic loading. The main plastic deformation mechanism of the rare earth Mg-Gd-Y magnesium alloy is possibly dislocation slip, rather than twinning for the conventional AZ31 magnesium alloy under high strain rate loading.

scholarly journals Studies on Dynamic Properties of Ultracapacitors Using Infinite r–C Chain Equivalent Circuit and Reverse Fourier Transform

Energies ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4583
Author(s):  
Shailendra Rajput ◽  
Alon Kuperman ◽  
Asher Yahalom ◽  
Moshe Averbukh
Keyword(s):  
Mathematical Model ◽  
Fourier Transform ◽  
Equivalent Circuit ◽  
Dynamic Behavior ◽  
Double Layer ◽  
Electrochemical Impedance ◽  
Dynamic Properties ◽  
Internal Resistance ◽  
Simulation Software ◽  
Specific Power

The specific power storage capabilities of double-layer ultracapacitors are receiving significant attention from engineers and scientific researchers. Nevertheless, their dynamic behavior should be studied to improve the performance and for efficient applications in electrical devices. This article presents an infinite resistor–capacitor (r–C) chain-based mathematical model for the analysis of double layer ultracapacitors. The internal resistance and capacitance were measured for repetitive charging and discharging cycles. The magnitudes of internal resistance and capacitance showed approximately ±10% changes for charge-discharge processes. Electrochemical impedance spectroscopy investigations revealed that the impedance of a double-layer ultracapacitor does not change significantly in the temperature range of (−30 °C to +30 °C) and voltage range of (0.3376–2.736 V). The analysis of impedance data using the proposed mathematical model showed good agreement between the experimental and theoretical data. The dynamic behavior of the ultracapacitor was successfully represented by utilizing the proposed infinite r–C chains equivalent circuit, and the reverse Fourier transform analysis. The r–C electrical equivalent circuit was also analyzed using the PSIM simulation software to study the dynamic behavior of ultracapacitor parameters. The simulation study yields an excellent agreement between the experimental and calculated voltage characteristics for repetitive charging-discharging processes.

ZnIIand CuIIcomplexes generated from 5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3H)-thione

2013 ◽  
Vol 69 (7) ◽  
pp. 716-720 ◽  
Author(s):  
Hang-Ju Zhao ◽  
Jian-Ping Ma ◽  
Qi-Kui Liu ◽  
Yu-Bin Dong
Keyword(s):  
Coordination Polymer ◽  
Stacking Interactions ◽  
The Novel ◽  
Two Dimensional ◽  
Compound I ◽  
Coordination Environment ◽  
Dimensional Network ◽  
Solvent Molecules ◽  
Compound Ii ◽  
Nitrate Anions

A new 1,3,4-oxadiazole-containing bispyridyl ligand, namely 5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3H)-thione (L), has been used to create the novel complexes tetranitratobis{μ-5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3H)-thione}zinc(II), [Zn2(NO3)4(C14H12N4OS)2], (I), andcatena-poly[[[dinitratocopper(II)]-bis{μ-5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3H)-thione}] nitrate acetonitrile sesquisolvate dichloromethane sesquisolvate], {[Cu(NO3)(C14H12N4OS)2]NO3·1.5CH3CN·1.5CH2Cl2}n, (II). Compound (I) presents a distorted rectangular centrosymmetric Zn2L2ring (dimensions 9.56 × 7.06 Å), where each ZnIIcentre lies in a {ZnN2O4} coordination environment. These binuclear zinc metallocycles are linked into a two-dimensional network through nonclassical C—H...O hydrogen bonds. The resulting sheets lie parallel to theacplane. Compound (II), which crystallizes as a nonmerohedral twin, is a coordination polymer with double chains of CuIIcentres linked by bridgingLligands, propagating parallel to the crystallographicaaxis. The CuIIcentres adopt a distorted square-pyramidal CuN4O coordination environment with apical O atoms. The chains in (II) are interlinkedviatwo kinds of π–π stacking interactions along [0\overline 11]. In addition, the structure of (II) contains channels parallel to the crystallographicadirection. The guest components in these channels consist of dichloromethane and acetonitrile solvent molecules and uncoordinated nitrate anions.

The double-stranded ladder-like structure of poly[[bis(μ2-acetato-κ2O:O′)bis(acetato-κO)bis(μ-4,4′-bipyridine-κ2N:N′)dicopper(II)] 4-nitrophenol disolvate tetrahydrate]

2013 ◽  
Vol 69 (10) ◽  
pp. 1100-1103
Author(s):  
Sizwe J. Zamisa ◽  
Patrick Ndungu ◽  
Bernard Omondi
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymer ◽  
Title Compound ◽  
Basal Plane ◽  
Copper Acetate ◽  
Water Solvent ◽  
Hydrogen Bonding Interactions ◽  
Complex Forms ◽  
Solvent Molecules ◽  
Unit Cell Length

The reaction of 4,4′-bipyridine with copper acetate in the presence of 4-nitrophenol led to the formation of the title compound, {[Cu(CH3COO)2(C10H8N2)]·C6H5NO3·2H2O}n. The complex forms a double-stranded ladder-like coordination polymer extending along thebaxis. The double-stranded polymers are separated by 4-nitrophenol and water solvent molecules. The two CuIIcentres of the centrosymmetric Cu2O2ladder rungs have square-pyramidal coordination environments, which are formed by two acetate O atoms and two 4,4′-bipyridine N atoms in the basal plane and another acetate O atom at the apex. The ladder-like double strands are separated from each other by one unit-cell length along thecaxis, and are connected by the water and 4-nitrophenol molecules through a series of O—H...O and C—H...O hydrogen-bonding interactions and two unique intermolecular π–π interactions.

INVESTIGATION OF DYNAMIC PROPERTIES OF ELASTOMERIC BEARING COMPONENTS VIA MODAL ANALYSIS

2015 ◽  
Vol 76 (8) ◽  
Author(s):  
A. I. Yusuf ◽  
M. A. Norliyati ◽  
M. A. Yunus ◽  
M. N. Abdul Rani
Keyword(s):  
Modal Analysis ◽  
Dynamic Behavior ◽  
Natural Frequencies ◽  
Dynamic Properties ◽  
Experimental Modal Analysis ◽  
Mode Shapes ◽  
Seismic Loads ◽  
Ground Structure ◽  
Elastomeric Bearing ◽  
Earthquake Load

Elastomeric bearing is a significant device in structures such as in bridges and buildings. It is used to isolate the ground structure (substructure) and the above ground structure (superstructure) from seismic loads such as earthquake load. Understanding the dynamic behavior of the elastomeric bearing in terms of natural frequencies, mode shapes and damping are increasingly important especially in improving the design and the failure limit of the elastomeric bearing. Modal analysis is one of the methods used to determine the dynamic properties of any materials. Hence, the main objective of this research is to determine the dynamic properties of elastomeric bearing components in terms of natural frequencies, mode shapes, and damping via numerical and experimental modal analysis. This method had been successfully performed in investigating the dynamic behavior of rubber and steel shim plate.

A Novel Coordination Polymer Incorporating a Dimeric Silver Unit: Increasing Structural Dimensionality through Ag–Ag and Ag–Hetero Atom Interactions

2004 ◽  
Vol 33 (6) ◽  
pp. 648-649 ◽  
Author(s):  
Keiichi Adachi ◽  
Sumio Kaizaki ◽  
Koichi Yamada ◽  
Susumu Kitagawa ◽  
Satoshi Kawata
Keyword(s):  
Coordination Polymer ◽  
Structural Dimensionality

Dynamic Properties of Multi-Lobe Water Lubricated Bearings With Temporal and Convective Inertia Considerations

2017 ◽  
Author(s):  
Saeid Dousti ◽  
Paul Allaire ◽  
Bradley Nichols ◽  
Jianming Cao ◽  
Timothy Dimond
Keyword(s):  
Stability Analysis ◽  
Dynamic Behavior ◽  
Reynolds Equation ◽  
Dynamic Properties ◽  
Added Mass ◽  
Damping Properties ◽  
Inertia Effects ◽  
The Stability ◽  
Water Pumps ◽  
Stiffness And Damping

In this paper, the extended Reynolds equation proposed by Dousti et al. [1] is applied to predict the dynamic behavior of different fixed geometry bearings used in vertical water pumps. The influence of convective and temporal inertia effects is studied in regular and preloaded multi-lobe bearings. It is shown that the convective inertia is more influential at the presence of preload and higher rotational speeds and alters the stiffness and damping properties of the bearing. The temporal inertia leads to the prediction of considerable lubricant added mass coefficients in the order of journal mass. The stability analysis shows depending upon the geometry of the bearing, the new extended Reynolds equation may predict higher or lower logarithmic decrement.

Dynamic Behavior of Slab Induced by Pedestrian Traffic

2019 ◽  
Vol 19 (12) ◽  
pp. 1950154
Author(s):  
Yan-An Gao ◽  
Qing-Shan Yang ◽  
Yun Dong ◽  
Chao Chen ◽  
Tao-Ping Ye
Keyword(s):  
Dynamic Behavior ◽  
Body Mass ◽  
Dynamic Properties ◽  
Damping Capacity ◽  
Model Parameters ◽  
Leg Stiffness ◽  
Structural Responses ◽  
Pedestrian Traffic ◽  
Mass Spring ◽  
Pseudo Excitation

This study comprehensively explores the dynamic behavior of a slender slab due to the excitation of pedestrian traffic. Three kinds of excitation models are adopted to describe the vibration of the slab induced by pedestrians. A comparison of the structural responses shows that the bipedal model results in larger vibrations than the mass–spring–damper or pseudo-excitation models. Further research indicates that the pedestrians evidently alter the dynamic properties of the slab by affecting its frequency and damping capacity. The slab tends to be more flexible at a lower frequency as the pedestrian walks across its surface while its damping capacity is improved. In contrast, the slab can increase the frequency, while decreasing the damping of the pedestrian model. Thus, the slab also alters the properties of the pedestrians. In addition, an investigation of the bipedal model parameters indicates that the variations of the leg stiffness, damping, and body mass have distinct effects on the slab characteristics and vibrations. In order to assess the response of the slab to a crowd, a new simplified theory is introduced to describe the dynamic properties of the slab under multi-layout excitations, including human influences resulting from different body properties. The results of this study provide potential ways for understanding the vibratory mechanisms of slender structures such as footbridges, grandstands, or stations under crowd excitations.

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