A heterotrimetallic synthetic approach in versatile functionalization of nanosized {MxCu13–xW7}3+ and {M1Cu8W6} (M = Co, Ni, Mn, Fe) metal–cyanide magnetic clusters

2019 ◽  
Vol 6 (11) ◽  
pp. 3104-3118 ◽  
Author(s):  
Michal Liberka ◽  
Jedrzej Kobylarczyk ◽  
Tadeusz M. Muziol ◽  
Shin-ichi Ohkoshi ◽  
Szymon Chorazy ◽  
...  
Keyword(s):  
Cluster System ◽  
Synthetic Approach ◽  
Magnetic Clusters ◽  
Metal Cyanide ◽  
Magnetic Features

The addition of 3d metal heteroatom into CuII(Me3tacn)[W(CN)8]n− cluster system governs its structural and magnetic features.

scholarly journals Surface Compositional Change of Iron Oxide Porous Nanorods: A Route for Tuning their Magnetic Properties

Molecules ◽  
2020 ◽  
Vol 25 (5) ◽  
pp. 1234 ◽  
Author(s):  
Alberto Casu ◽  
Danilo Loche ◽  
Sergio Lentijo-Mozo ◽  
Andrea Falqui
Keyword(s):  
Magnetocrystalline Anisotropy ◽  
Shape Anisotropy ◽  
Colloidal Synthesis ◽  
Oxide Shell ◽  
Synthetic Approach ◽  
Magnetic Response ◽  
Compositional Change ◽  
The Core ◽  
Magnetic Hardening ◽  
Magnetic Features

The capability of synthesizing specific nanoparticles (NPs) by varying their shape, size and composition in a controlled fashion represents a typical set of engineering tools that tune the NPs magnetic response via their anisotropy. In particular, variations in NP composition mainly affect the magnetocrystalline anisotropy component, while the different magnetic responses of NPs with isotropic (i.e., spherical) or elongated shapes are mainly caused by changes in their shape anisotropy. In this context, we propose a novel route to obtain monodispersed, partially hollow magnetite nanorods (NRs) by colloidal synthesis, in order to exploit their shape anisotropy to increase the related coercivity; we then modify their composition via a cation exchange (CE) approach. The combination of a synthetic and post-synthetic approach on NRs gave rise to dramatic variations in their magnetic features, with the pores causing an initial magnetic hardening that was further enhanced by the post-synthetic introduction of a manganese oxide shell. Indeed, the coupling of the core and shell ferrimagnetic phases led to even harder magnetic NRs.

Dislocations, Ordering and Antiferromagnetic Domains in MnO

1970 ◽  
Vol 28 ◽  
pp. 522-523
Author(s):  
D. J. Barber ◽  
R. G. Evans
Keyword(s):  
Electron Diffraction ◽  
Single Crystal ◽  
Optical Microscopy ◽  
Defect Chemistry ◽  
Magnetic Structures ◽  
Optically Transparent ◽  
Magnetic Features ◽  
Antiferromagnetic Domains

Manganese (II) oxide, MnO, in common with CoO, NiO and FeO, possesses the NaCl structure and shows antiferromagnetism below its Neel point, Tn∼ 122 K. However, the defect chemistry of the four oxides is different and the magnetic structures are not identical. The non-stoichiometry in MnO2 small (∼2%) and below the Tn the spins lie in (111) planes. Previous work reported observations of magnetic features in CoO and NiO. The aim of our work was to find explanations for certain resonance results on antiferromagnetic MnO.Foils of single crystal MnO were prepared from shaped discs by dissolution in a mixture of HCl and HNO3. Optical microscopy revealed that the etch-pitted foils contained cruciform-shaped precipitates, often thick and proud of the surface but red-colored when optically transparent (MnO is green). Electron diffraction and probe microanalysis indicated that the precipitates were Mn2O3, in contrast with recent findings of Co3O4 in CoO.

EXPERIMENTAL EVIDENCES OF MAGNETIC CLUSTERS IN AN AMORPHOUS Fe0.34Sn0.66 ALLOYS

1980 ◽  
Vol 41 (C8) ◽  
pp. C8-666-C8-669
Author(s):  
S. Nikolov ◽  
M. Piecuch ◽  
G. Marchal ◽  
Chr. Janot
Keyword(s):  
Magnetic Clusters

New Insights into the Nature of the Band Gap of CuGeO3 Nanoparticles: Synthesis, Electronic Structure, and Optical and Photocatalytic Properties

2019 ◽  
Author(s):  
Victor Y. Suzuki ◽  
Luís Henrique Cardozo Amorin ◽  
Natália H. de Paula ◽  
Anderson R. Albuquerque ◽  
Julio Ricardo Sambrano ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Band Gap ◽  
Material Design ◽  
Photocatalytic Properties ◽  
Critical Parameters ◽  
Synthetic Approach ◽  
Microwave Assisted ◽  
Theoretical Approaches ◽  
Nanoparticles Synthesis ◽  
First Time

<p>We report, for the first time, new insights into the nature of the band gap of <a>CuGeO<sub>3</sub> </a>(CGO) nanocrystals synthesized from a microwave-assisted hydrothermal method in the presence of citrate. To the best of our knowledge, this synthetic approach has the shortest reaction time and it works at the lowest temperatures reported in the literature for the preparation of these materials. The influence of the surfactant on the structural, electronic, optical, and photocatalytic properties of CGO nanocrystals is discussed by a combination of experimental and theoretical approaches, and that results elucidates the nature of the band gap of synthetized CGO nanocrystals. We believe that this particular strategy is one of the most critical parameters for the development of innovative applications and that result could shed some light on the emerging material design with entirely new properties.</p> <p><b> </b></p>

General Cyclopropane Assembly via Enantioselective Redox-Active Carbene Transfer to Aliphatic Olefins

2018 ◽  
Author(s):  
Marc Montesinos-Magraner ◽  
Matteo Costantini ◽  
Rodrigo Ramirez-Contreras ◽  
Michael E. Muratore ◽  
Magnus J. Johansson ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Asymmetric Synthesis ◽  
Chemical Space ◽  
Synthetic Approach ◽  
Asymmetric Cyclopropanation ◽  
Redox Active ◽  
Wide Range ◽  
Leaving Group ◽  
Stereoelectronic Properties ◽  
Carbene Transfer

Asymmetric cyclopropane synthesis currently requires bespoke strategies, methods, substrates and reagents, even when targeting similar compounds. This limits the speed and chemical space available for discovery campaigns. Here we introduce a practical and versatile diazocompound, and we demonstrate its performance in the first unified asymmetric synthesis of functionalized cyclopropanes. We found that the redox-active leaving group in this reagent enhances the reactivity and selectivity of geminal carbene transfer. This effect enabled the asymmetric cyclopropanation of a wide range of olefins including unactivated aliphatic alkenes, enabling the 3-step total synthesis of (–)-dictyopterene A. This unified synthetic approach delivers high enantioselectivities that are independent of the stereoelectronic properties of the functional groups transferred. Our results demonstrate that orthogonally-differentiated diazocompounds are viable and advantageous equivalents of single-carbon chirons<i>.</i>

Using Ansys for Design and Numerical Study of a Specific Fixed Wing UAV

2018 ◽  
Vol 55 (4) ◽  
pp. 652-657 ◽  
Author(s):  
Gabriel Murariu ◽  
Razvan Adrian Mahu ◽  
Adrian Gabriel Murariu ◽  
Mihai Daniel Dragu ◽  
Lucian P. Georgescu ◽  
...  
Keyword(s):  
Numerical Simulations ◽  
Unmanned Aerial Vehicle ◽  
Numerical Study ◽  
Flight Time ◽  
Cluster System ◽  
Numerical Results ◽  
Operational Performance ◽  
Gliding Flight ◽  
Aerial Vehicle ◽  
Constant Altitude

This article presents the design of a specific unmanned aerial vehicle UAV prototype own building. Our UAV is a flying wing type and is able to take off with a little boost. This system happily combines some major advantages taken from planes namely the ability to fly horizontal, at a constant altitude and of course, the great advantage of a long flight-time. The aerodynamic models presented in this paper are optimized to improve the operational performance of this aerial vehicle, especially in terms of stability and the possibility of a long gliding flight-time. Both aspects are very important for the increasing of the goals� efficiency and for the getting work jobs. The presented simulations were obtained using ANSYS 13 installed on our university� cluster system. In a next step the numerical results will be compared with those during experimental flights. This paper presents the main results obtained from numerical simulations and the obtained magnitudes of the main flight coefficients.

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