A facile approach to thermomechanically enhanced fatty acid-containing bioplastics using metal–ligand coordination

2019 ◽  
Vol 10 (48) ◽  
pp. 6570-6579 ◽  
Author(s):  
Meghan E. Lamm ◽  
Lingzhi Song ◽  
Zhongkai Wang ◽  
Benjamin Lamm ◽  
Lin Fu ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Thermomechanical Properties ◽  
Biobased Polymers ◽  
Ligand Coordination ◽  
Chain Entanglements ◽  
Metal Ligand ◽  
Physical Crosslinking

Dynamic metal–ligand coordination creates physical crosslinking and thus improves chain entanglements for enhancing the thermomechanical properties of biobased polymers.

scholarly journals Modulating the thermomechanical properties and self-healing efficiency of siloxane-based soft polymers through metal–ligand coordination

2020 ◽  
Vol 44 (21) ◽  
pp. 8977-8985 ◽  
Author(s):  
Julia Pignanelli ◽  
Zhiyuan Qian ◽  
Xiaodan Gu ◽  
Mohammed Jalal Ahamed ◽  
Simon Rondeau-Gagné
Keyword(s):  
Thermomechanical Properties ◽  
Self Healing ◽  
Efficient Strategy ◽  
Healing Efficiency ◽  
Ligand Coordination ◽  
Metal Ligand ◽  
Soft Polymers

An efficient strategy to modulate the thermomechanical properties and self-healing of soft polymers has been developed by rationally selecting the metal used for supramolecular crosslinking.

scholarly journals Self-Assembled Nanomaterials Based on Complementary Sn(IV) and Zn(II)-Porphyrins, and Their Photocatalytic Degradation for Rhodamine B Dye

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3598
Author(s):  
Nirmal K. Shee ◽  
Hee-Joon Kim
Keyword(s):  
Aqueous Solution ◽  
Visible Light Irradiation ◽  
Rhodamine B ◽  
Self Assembly ◽  
The Self ◽  
Assembly Process ◽  
Absorption Bands ◽  
Ligand Coordination ◽  
Rhodamine B Dye ◽  
Metal Ligand

A series of porphyrin triads (1–6), based on the reaction of trans-dihydroxo-[5,15-bis(3-pyridyl)-10,20-bis(phenyl)porphyrinato]tin(IV) (SnP) with six different phenoxy Zn(II)-porphyrins (ZnLn), was synthesized. The cooperative metal–ligand coordination of 3-pyridyl nitrogens in the SnP with the phenoxy Zn(II)-porphyrins, followed by the self-assembly process, leads to the formation of nanostructures. The red-shifts and remarkable broadening of the absorption bands in the UV–vis spectra for the triads in CHCl3 indicate that nanoaggregates may be produced in the self-assembly process of these triads. The emission intensities of the triads were also significantly reduced due to the aggregation. Microscopic analyses of the nanostructures of the triads reveal differences due to the different substituents on the axial Zn(II)-porphyrin moieties. All these nanomaterials exhibited efficient photocatalytic performances in the degradation of rhodamine B (RhB) dye under visible light irradiation, and the degradation efficiencies of RhB in aqueous solution were observed to be 72~95% within 4 h. In addition, the efficiency of the catalyst was not impaired, showing excellent recyclability even after being applied for the degradation of RhB in up to five cycles.

Template-free multicomponent coordination-driven self-assembly of Pd(ii)/Pt(ii) molecular cages

2014 ◽  
Vol 50 (18) ◽  
pp. 2239-2248 ◽  
Author(s):  
Sandip Mukherjee ◽  
Partha Sarathi Mukherjee
Keyword(s):  
Self Assembly ◽  
Assembly Process ◽  
Molecular Cages ◽  
Recent Developments ◽  
Ligand Coordination ◽  
Template Free ◽  
Metal Ligand

This article summarizes the recent developments in the construction of multicomponent molecular hollowed-out cages through the metal–ligand coordination-driven self-assembly process, with a focus on the decreasing relevance of the use of templates.

scholarly journals The structural diversity of heterocycle-fused potassium cyclopentadienides

RSC Advances ◽  
2019 ◽  
Vol 9 (50) ◽  
pp. 29195-29204 ◽  
Author(s):  
Ilya E. Nifant'ev ◽  
Alexander A. Vinogradov ◽  
Mikhail E. Minyaev ◽  
Pavel D. Komarov ◽  
Konstantin A. Lyssenko ◽  
...  
Keyword(s):  
Crystal Packing ◽  
Structural Diversity ◽  
Ligand Coordination ◽  
Metal Ligand

Heterocycle-fused cyclopentadienides of potassium demonstrate remarkable diversity in metal–ligand coordination and crystal packing.

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