Substrate-independent Cu(0)-mediated controlled radical polymerization: grafting of block copolymer brushes from poly(dopamine) modified surfaces

Daniel Hafner; Rainer Jordan

doi:10.1039/c9py01343a

Substrate-independent Cu(0)-mediated controlled radical polymerization: grafting of block copolymer brushes from poly(dopamine) modified surfaces

Polymer Chemistry ◽

10.1039/c9py01343a ◽

2020 ◽

Vol 11 (12) ◽

pp. 2129-2136 ◽

Cited By ~ 3

Author(s):

Daniel Hafner ◽

Rainer Jordan

Keyword(s):

Block Copolymer ◽

Radical Polymerization ◽

Surface Properties ◽

Polymer Brushes ◽

Controlled Radical Polymerization ◽

Original Surface ◽

Modified Surfaces ◽

Copolymer Brushes ◽

Substrate Independent

A method is presented combining poly(dopamine) chemistry and surface-initiated Cu(0)-mediated controlled radical polymerization (SI-CuCRP). Polymer brushes and block copolymer brushes are grafted independent of the original surface properties.

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Control of Surface Properties Using Fluorinated Polymer Brushes Produced by Surface-Initiated Controlled Radical Polymerization

Langmuir ◽

10.1021/la049264f ◽

2004 ◽

Vol 20 (24) ◽

pp. 10498-10506 ◽

Cited By ~ 69

Author(s):

Luisa Andruzzi ◽

Alexander Hexemer ◽

Xuefa Li ◽

Christopher K. Ober ◽

Edward J. Kramer ◽

...

Keyword(s):

Radical Polymerization ◽

Surface Properties ◽

Polymer Brushes ◽

Controlled Radical Polymerization ◽

Fluorinated Polymer

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Degradable Polymer Brushes Prepared via Surface-Initiated Controlled Radical Polymerization

Macromolecules ◽

10.1021/ma901537x ◽

2009 ◽

Vol 42 (21) ◽

pp. 8076-8081 ◽

Cited By ~ 40

Author(s):

Carl Riachi ◽

Nicolas Schüwer ◽

Harm-Anton Klok

Keyword(s):

Radical Polymerization ◽

Polymer Brushes ◽

Controlled Radical Polymerization ◽

Degradable Polymer

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Supported Cu0 nanoparticles catalyst for controlled radical polymerization reaction and block-copolymer synthesis

Scientific Reports ◽

10.1038/s41598-017-10760-w ◽

2017 ◽

Vol 7 (1) ◽

Cited By ~ 1

Author(s):

Aurel Diacon ◽

Edina Rusen ◽

Alexandra Mocanu ◽

Leona Cristina Nistor

Keyword(s):

Block Copolymer ◽

Radical Polymerization ◽

Controlled Radical Polymerization ◽

Polymerization Reaction

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Photoinduced controlled radical polymerization of methyl acrylate and vinyl acetate by xanthate

Polymer Chemistry ◽

10.1039/c8py00050f ◽

2018 ◽

Vol 9 (21) ◽

pp. 2897-2904 ◽

Cited By ~ 11

Author(s):

Jiajia Li ◽

Xiangqiang Pan ◽

Na Li ◽

Jian Zhu ◽

Xiulin Zhu

Keyword(s):

Block Copolymer ◽

Radical Polymerization ◽

Vinyl Acetate ◽

Methyl Acrylate ◽

Raft Polymerization ◽

Controlled Radical Polymerization

A block copolymer of PMA-b-PVAc was successfully synthesized using photo-induced RAFT polymerization with a xanthate.

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Precise growth of polymer brushes on silica-based nanocomposites via visible-light-regulated controlled radical polymerization

Journal of Materials Chemistry A ◽

10.1039/c9ta00905a ◽

2019 ◽

Vol 7 (11) ◽

pp. 6173-6179 ◽

Cited By ~ 8

Author(s):

Xue Li ◽

Sunjie Ye ◽

Ya Huang ◽

Jia Le Li ◽

Tao Cai

Keyword(s):

Physicochemical Properties ◽

Visible Light ◽

Radical Polymerization ◽

Polymer Nanocomposites ◽

Polymer Brushes ◽

Controlled Radical Polymerization ◽

Crucial Importance ◽

Grafted Polymer ◽

Precise Control

Precise control over molecular variables of grafted polymer brushes is of crucial importance for obtaining polymer nanocomposites with desirable architectures and physicochemical properties, yet it remains a significant synthetic challenge.

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Synthesis of alkyne-terminated xanthate RAFT agents and their uses for the controlled radical polymerization ofN-vinylpyrrolidone and the synthesis of its block copolymer using click chemistry

Journal of Applied Polymer Science ◽

10.1002/app.38037 ◽

2012 ◽

Vol 127 (6) ◽

pp. 4305-4317 ◽

Cited By ~ 26

Author(s):

Vijay Kumar Patel ◽

Niraj Kumar Vishwakarma ◽

Avnish Kumar Mishra ◽

Chandra Sekhar Biswas ◽

Pralay Maiti ◽

...

Keyword(s):

Block Copolymer ◽

Click Chemistry ◽

Radical Polymerization ◽

Controlled Radical Polymerization

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Surface-Initiated Controlled Radical Polymerization: State-of-the-Art, Opportunities, and Challenges in Surface and Interface Engineering with Polymer Brushes

Chemical Reviews ◽

10.1021/acs.chemrev.6b00314 ◽

2017 ◽

Vol 117 (3) ◽

pp. 1105-1318 ◽

Cited By ~ 393

Author(s):

Justin O. Zoppe ◽

Nariye Cavusoglu Ataman ◽

Piotr Mocny ◽

Jian Wang ◽

John Moraes ◽

...

Keyword(s):

Radical Polymerization ◽

Polymer Brushes ◽

State Of The Art ◽

Controlled Radical Polymerization ◽

Interface Engineering ◽

Surface And Interface

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Correction to Substrate-Independent Micropatterning of Polymer Brushes Based on Photolytic Deactivation of Chemical Vapor Deposition Based Surface-Initiated Atom-Transfer Radical Polymerization Initiator Films

ACS Applied Materials & Interfaces ◽

10.1021/acsami.8b16748 ◽

2018 ◽

Vol 10 (44) ◽

pp. 38656-38658

Author(s):

Ramya Kumar ◽

Alexander Welle ◽

Fabian Becker ◽

Irina Kopyeva ◽

Joerg Lahann

Keyword(s):

Chemical Vapor Deposition ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Vapor Deposition ◽

Polymer Brushes ◽

Chemical Vapor ◽

Atom Transfer ◽

Substrate Independent

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Surface-initiated Cu(0) mediated controlled radical polymerization (SI-CuCRP) using a copper plate

Polymer Chemistry ◽

10.1039/c5py00093a ◽

2015 ◽

Vol 6 (14) ◽

pp. 2726-2733 ◽

Cited By ~ 56

Author(s):

Tao Zhang ◽

Yunhao Du ◽

Felix Müller ◽

Ihsan Amin ◽

Rainer Jordan

Keyword(s):

Radical Polymerization ◽

Polymer Brushes ◽

Copper Plate ◽

Living Radical Polymerization ◽

Controlled Radical Polymerization ◽

Controlled Living Radical Polymerization

We report on a new, extremely fast, very simple and versatile method to produce polymer brushes by surface-initiated controlled/living radical polymerization.

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