scholarly journals Phenothiazine derivatives as photoredox catalysts for cationic and radical photosensitive resins for 3D printing technology and photocomposite synthesis

2019 ◽  
Vol 10 (45) ◽  
pp. 6145-6156 ◽  
Author(s):  
Mira Abdallah ◽  
Thanh-Tuân Bui ◽  
Fabrice Goubard ◽  
Dimitra Theodosopoulou ◽  
Frédéric Dumur ◽  
...  

New phenothiazine derivatives are synthesized and proposed as high performance visible light photoinitiators.

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2063 ◽  
Author(s):  
Mira Abdallah ◽  
Akram Hijazi ◽  
Frédéric Dumur ◽  
Jacques Lalevée

In this study, eight coumarins (coumarins 1–8) are proposed as near-UV and blue light sensitive photoinitiators/photosensitizers for the cationic polymerization (CP) of epoxysilicones when combined with 4-isopropyl-4’-methyldiphenyliodonium tetrakis(pentafluorophenyl)borate (IOD). Among these coumarins, four of them (coumarins 1, 2, 6 and 8) have never been reported in the literature, i.e., these structures have been specifically designed to act as photoinitiators for silicones upon near UV and visible irradiation. Good final reactive epoxy function conversions (FCs) and also high rates of polymerization (Rp) were achieved in the presence of the newly proposed coumarin-based systems. The polymers generated from the photopolymerization of epoxysilicones can be considered as attractive candidates for several applications such as: elastomers, coatings, adhesives, and so on. The goal of this study focuses also on the comparison of the new proposed coumarins with well-established photosensitizers i.e., 1-chloro-4-propoxythioxanthone (CPTX), 9,10-dibutoxyanthracene (DBA) or some commercial coumarins (Com. Coum). As example of their high performance, the new proposed coumarins were also used for laser write experiments upon irradiation with a laser diode at 405 nm in order to develop new cationic 3D printing systems.


2021 ◽  
pp. 2102649
Author(s):  
Sourav Chaule ◽  
Jongha Hwang ◽  
Seong‐Ji Ha ◽  
Jihun Kang ◽  
Jong‐Chul Yoon ◽  
...  

2020 ◽  
Vol 1 (1) ◽  
pp. 14-19 ◽  
Author(s):  
Hang Luo ◽  
Xuefan Zhou ◽  
Ru Guo ◽  
Xi Yuan ◽  
Hehao Chen ◽  
...  

High-performance flexible poly(vinylidene fluoride–chlorotrifluoroethylene) (P(VDF–CTFE)) nanocomposites with aligned BaTiO3 nanowires using 3D printing technology were demonstrated.


2021 ◽  
Vol 33 (38) ◽  
pp. 2170299
Author(s):  
Sourav Chaule ◽  
Jongha Hwang ◽  
Seong‐Ji Ha ◽  
Jihun Kang ◽  
Jong‐Chul Yoon ◽  
...  

Author(s):  
Mohd Nazri Ahmad ◽  
Ahmad Afiq Tarmeze ◽  
Amir Hamzah Abdul Rasib

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