scholarly journals Catalytic strategies towards 1,3-polyol synthesis by enantioselective cascades creating multiple alcohol functions

2020 ◽  
Vol 18 (6) ◽  
pp. 1025-1035 ◽  
Author(s):  
Céline Sperandio ◽  
Jean Rodriguez ◽  
Adrien Quintard
Keyword(s):  
Polyol Synthesis ◽  
Rapid Preparation ◽  
Enantioselective Catalyst

This review highlights the different enantioselective catalyst-controlled cascades creating multiple alcohol functions and ensuring through subsequent simple derivatization, the rapid preparation of extended 1,3-polyols.

scholarly journals Simple Synthesis of Red Iridium(III) Complexes with Sulfur-Contained Four-Membered Ancillary Ligands for OLEDs

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2599
Author(s):  
Meng-Xi Mao ◽  
Fang-Ling Li ◽  
Yan Shen ◽  
Qi-Ming Liu ◽  
Shuai Xing ◽  
...  
Keyword(s):  
Indium Tin Oxide ◽  
Quantum Yields ◽  
Rapid Preparation ◽  
Maximum Brightness ◽  
Ancillary Ligands ◽  
Light Emitting ◽  
Maximum Current ◽  
Electron Donating Groups ◽  
Sulfur Containing ◽  
Main Ligand

Phosphorescent iridium(III) complexes have been widely researched for the fabrication of efficient organic light-emitting diodes (OLEDs). In this work, three red Ir(III) complexes named Ir-1, Ir-2, and Ir-3, with Ir-S-C-S four-membered framework rings, were synthesized efficiently at room temperature within 5 min using sulfur-containing ancillary ligands with electron-donating groups of 9,10-dihydro-9,9-dimethylacridine, phenoxazine, and phenothiazine, respectively. Due to the same main ligand of 4-(4-(trifluoromethyl)phenyl)quinazoline, all Ir(III) complexes showed similar photoluminescence emissions at 622, 619, and 622 nm with phosphorescence quantum yields of 35.4%, 50.4%, and 52.8%, respectively. OLEDs employing these complexes as emitters with the structure of ITO (indium tin oxide)/HAT-CN (dipyra-zino[2,3-f,2′,3′-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile, 5 nm)/TAPC (4,4′-cyclohexylidenebis[N,N-bis-(4-methylphenyl)aniline], 40 nm)/TCTA (4,4″,4″-tris(carbazol-9-yl)triphenylamine, 10 nm)/Ir(III) complex (10 wt%): 2,6DCzPPy (2,6-bis-(3-(carbazol-9-yl)phenyl)pyridine, 10 nm)/TmPyPB (1,3,5-tri(mpyrid-3-yl-phenyl)benzene, 50 nm)/LiF (1 nm)/Al (100 nm) achieved good performance. In particular, the device based on complex Ir-3 with the phenothiazine unit showed the best performance with a maximum brightness of 22,480 cd m−2, a maximum current efficiency of 23.71 cd A−1, and a maximum external quantum efficiency of 18.1%. The research results suggest the Ir(III) complexes with a four-membered ring Ir-S-C-S backbone provide ideas for the rapid preparation of Ir(III) complexes for OLEDs.

Polyol Synthesis of Lithium Iron Phosphate with Carbon Nanotubes: Effect of Dispersion on Crystallinity and Electrochemical Performance

2014 ◽  
Vol 1678 ◽  
Author(s):  
Wesley D. Tennyson
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Black ◽  
Lithium Iron Phosphate ◽  
Iron Phosphate ◽  
Polyol Synthesis ◽  
Battery Life ◽  
Unique Challenge ◽  
Weight Percentage ◽  
Conductive Additive ◽  
Power Capability

ABSTRACTCarbon nanotubes (CNTs) have been shown to be a viable conductive additive in Li-Ion batteries [1]. By using CNTs battery life, energy, and power capability can all be improved over carbon black, the traditional conductive additive. A significantly smaller weight percentage (5% CNTs) is needed to get the same conductivity as 20% carbon black. Many of the previous efforts found that a combination of conductive additives was most advantageous [2]. Unfortunately many of these efforts did not attend to the unique challenge that dispersing nanotubes presents and used non-optimal methods to disperse CNTs (e.g. ball milling) [3,4]. With poor dispersion a stable and resilient conductive network in the cathode is hard to form with CNTs alone. Here we investigate the formation of LiFePO₄ with CNTs using a polyol process synthesis.

Structural, Morphological, Magnetic and Self-Heating Studies of One-Step Polyol Synthesized Manganese Ferrite (MnFe2O4) Nanoparticles

2019 ◽  
Vol 19 (01) ◽  
pp. 1950003
Author(s):  
P. R. Ghutepatil ◽  
S. H. Pawar
Keyword(s):  
Room Temperature ◽  
Synthesis Method ◽  
Average Crystallite Size ◽  
Superparamagnetic Nanoparticles ◽  
Polyol Synthesis ◽  
X Ray Diffraction ◽  
Self Heating ◽  
Transmission Electron ◽  
One Step ◽  
Mnfe2o4 Nanoparticles

In this paper, uniform and superparamagnetic nanoparticles have been prepared using one-step polyol synthesis method. Structural, morphological and magnetic properties of obtained MnFe2O4 nanoparticles have been investigated by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM) and thermogravimetric analysis (TGA) techniques. Structural investigation showed that the average crystallite size of obtained nanoparticles was about 10[Formula: see text]nm. Magnetic study revealed that the nanoparticles were superparamagnetic at room temperature with magnetization 67[Formula: see text]emu/g at room temperature. The self-heating characteristics of synthesized MnFe2O4 nanoparticles were studied by applying external AC magnetic field of 167.6 to 335.2[Formula: see text]Oe at a fixed frequency of 265[Formula: see text]kHz. The SAR values of MnFe2O4 nanoparticles were calculated for 2, 5, 10[Formula: see text]mg[Formula: see text]mL[Formula: see text] concentrations and it is observed that the threshold hyperthermia temperature is achieved for all concentrations.

Holey graphene nanosheets: large-scale rapid preparation and their application toward highly-effective water cleaning

Nanoscale ◽  
2014 ◽  
Vol 6 (20) ◽  
pp. 11659-11663 ◽  
Author(s):  
Zhicai Xing ◽  
Jingqi Tian ◽  
Qian Liu ◽  
Abdullah M. Asiri ◽  
Ping Jiang ◽  
...  
Keyword(s):  
Large Scale ◽  
Graphene Nanosheets ◽  
Rapid Preparation ◽  
Water Cleaning ◽  
Highly Effective ◽  
Effective Water
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