Chemoselective photocatalytic oxidation of alcohols to aldehydes and ketones by nitromethane on titanium dioxide under violet 400 nm LED light irradiation

2020 ◽  
Vol 18 (12) ◽  
pp. 2326-2330 ◽  
Author(s):  
Azam Rahimi Niaraki ◽  
Mohammad Reza Saraee ◽  
Foad Kazemi ◽  
Babak Kaboudin
Keyword(s):  
Titanium Dioxide ◽  
Photocatalytic Oxidation ◽  
Electron Acceptors ◽  
Light Irradiation ◽  
Led Light ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones ◽  
First Time ◽  
Led Irradiation

In this study, for the first time, nitroalkanes, especially nitromethane, have been used as electron acceptors for the highly chemoselective oxidation of alcohols in the presence of a TiO2 photocatalyst under 400 nm LED irradiation.

Photocatalytic Oxidation of NOx under Visible LED Light Irradiation over Nitrogen-Doped Titania Particles with Iron or Platinum Loading

2008 ◽  
Vol 112 (32) ◽  
pp. 12425-12431 ◽  
Author(s):  
Shu Yin ◽  
Bin Liu ◽  
Peilin Zhang ◽  
Takeshi Morikawa ◽  
Ken-ichi Yamanaka ◽  
...  
Keyword(s):  
Photocatalytic Oxidation ◽  
Light Irradiation ◽  
Led Light ◽  
Nitrogen Doped ◽  
Doped Titania ◽  
Platinum Loading

Macroporous TiO2encapsulated Au@Pd bimetal nanoparticles for the photocatalytic oxidation of alcohols in water under visible-light

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 107233-107238 ◽  
Author(s):  
Xiaohui Wang ◽  
Dahu Baiyila ◽  
Xiaotian Li
Keyword(s):  
Catalytic Activity ◽  
Visible Light ◽  
Ambient Temperature ◽  
Visible Light Irradiation ◽  
Photocatalytic Oxidation ◽  
Aerobic Oxidation ◽  
Light Irradiation ◽  
Oxidizing Agent ◽  
Oxidation Of Alcohols

A novel macroporous photocatalyst Au@Pd@TiO2has been reported and showed excellent catalytic activity and stability in the aerobic oxidation of alcohols in water at ambient temperature when using air as the oxidizing agent under visible light irradiation.

Visible-light-driven photocatalytic bacterial inactivation and the mechanism of zinc oxysulfide under LED light irradiation

2016 ◽  
Vol 4 (3) ◽  
pp. 1052-1059 ◽  
Author(s):  
Dan Wu ◽  
Wei Wang ◽  
Tsz Wai Ng ◽  
Guocheng Huang ◽  
Dehua Xia ◽  
...  
Keyword(s):  
Escherichia Coli ◽  
Visible Light ◽  
Light Irradiation ◽  
Bacterial Inactivation ◽  
Led Light ◽  
Visible Light Driven ◽  
Zinc Oxysulfide ◽  
K 12 ◽  
First Time

Zinc oxysulfide (ZnO0.6S0.4) nanoparticles were prepared and used as an effective visible-light-driven (VLD) photocatalyst for the inactivation of Escherichia coli K-12 for the first time.

scholarly journals Synthesis of carbon self-doped titanium dioxide and its activity in the photocatalytic oxidation of styrene under visible light irradiation

2019 ◽  
Vol 15 (2) ◽  
pp. 291-297 ◽  
Author(s):  
Siti Hajar Alias ◽  
Nurul Najidah Mohamed ◽  
Leaw Wai Loon ◽  
Sheela Chandren
Keyword(s):  
Titanium Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Photoelectron Spectroscopy ◽  
Photocatalytic Oxidation ◽  
Styrene Oxide ◽  
Light Irradiation ◽  
Tio2 Photocatalysts ◽  
X Ray ◽  
Doped Titanium Dioxide

Carbon self-doped titanium dioxide (C/TiO2) photocatalyst was synthesized by a simple sol-gel method using titanium isopropoxide as both the titanium precursor and carbon source. The effects of calcination temperatures in the range of 300 to 700 °C to the structure and physicochemical properties of the C/TiO2 were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) coupled with energy dispersive X-ray (EDX), Fourier transform infrared (FTIR) spectroscopy, UV-visible diffuse reflectance (UV-Vis DR) spectroscopy, photoluminescence spectroscopy, N2 adsorption-desorption and X-ray photoelectron spectroscopy (XPS). XPS results proved the presence of self-doped carbon at the interstitial and substitutional lattice of TiO2. The C/TiO2 calcined at 300 and 400 °C (C/TiO2-300 and C/TiO2-400, respectively) showed mesoporous characteristic and large surface area of about 100 m2 g-1. The C/TiO2 photocatalysts were then tested in the photo-oxidation of styrene under visible light irradiation with aqueous hydrogen peroxide as the oxidizing agent. The C/TiO2 photocatalysts were successfully activated under the irradiation of visible light, where C/TiO2-300 and C/TiO2-400 showed the highest total concentration of products (benzaldehyde and styrene oxide) at 1.1 mmol and 1.0 mmol, respectively.For video presentation, kindly please visit this link:

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