Reaction condition controlled nickel(ii)-catalyzed C–C cross-coupling of alcohols

2019 ◽  
Vol 17 (14) ◽  
pp. 3567-3574 ◽  
Author(s):  
Meng-Juan Zhang ◽  
Hong-Xi Li ◽  
David J. Young ◽  
Hai-Yan Li ◽  
Jian-Ping Lang
Keyword(s):  
Cross Coupling ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Unsaturated Ketones ◽  
Reaction Condition

Nickel(ii)-catalyzed C–C cross-coupling of secondary and primary alcohols selectively produced β-alkylated secondary alcohols, α-alkylated ketones and α,β-unsaturated ketones.

scholarly journals Manganese(I)-Catalyzed Cross-Coupling of Ketones and Secondary Alcohols with Primary Alcohols

ACS Omega ◽  
2019 ◽  
Vol 4 (6) ◽  
pp. 10741-10754 ◽  
Author(s):  
Suhas Shahaji Gawali ◽  
Biplab Keshari Pandia ◽  
Souvik Pal ◽  
Chidambaram Gunanathan
Keyword(s):  
Cross Coupling ◽  
Secondary Alcohols ◽  
Primary Alcohols

Iridium–CNP complex catalyzed cross-coupling of primary alcohols and secondary alcohols by a borrowing hydrogen strategy

RSC Advances ◽  
2014 ◽  
Vol 4 (81) ◽  
pp. 42924-42929 ◽  
Author(s):  
Dawei Wang ◽  
Keyan Zhao ◽  
Xin Yu ◽  
Hongyan Miao ◽  
Yuqiang Ding
Keyword(s):  
Cross Coupling ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Borrowing Hydrogen

ChemInform Abstract: Iridium-CNP Complex Catalyzed Cross-Coupling of Primary Alcohols and Secondary Alcohols by a Borrowing Hydrogen Strategy.

ChemInform ◽  
2015 ◽  
Vol 46 (13) ◽  
pp. no-no
Author(s):  
Dawei Wang ◽  
Keyan Zhao ◽  
Xin Yu ◽  
Hongyan Miao ◽  
Yuqiang Ding
Keyword(s):  
Cross Coupling ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Borrowing Hydrogen

Revisiting Sodium Hypochlorite Pentahydrate (NaOCl·5H2O) for the Oxidation of Alcohols in Acetonitrile without Nitroxyl Radicals

Synlett ◽  
2018 ◽  
Vol 29 (18) ◽  
pp. 2404-2407 ◽  
Author(s):  
Tsunehisa Hirashita ◽  
Yuto Sugihara ◽  
Shota Ishikawa ◽  
Yohei Naito ◽  
Yuta Matsukawa ◽  
...  
Keyword(s):  
Sodium Hypochlorite ◽  
Nitroxyl Radicals ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Oxidation Of Alcohols

Sodium hypochlorite pentahydrate (NaOCl·5H2O) is capable of oxidizing alcohols in acetonitrile at 20 °C without the use of catalysts. The oxidation is selective to allylic, benzylic, and secondary alcohols. ­Aliphatic primary alcohols are not oxidized.

Ruthenium Pincer-Catalyzed Cross-Dehydrogenative Coupling of Primary Alcohols with Secondary Alcohols under Neutral Conditions

2012 ◽  
Vol 354 (13) ◽  
pp. 2403-2406 ◽  
Author(s):  
Dipankar Srimani ◽  
Ekambaram Balaraman ◽  
Boopathy Gnanaprakasam ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Dehydrogenative Coupling ◽  
Neutral Conditions

scholarly journals Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 231
Author(s):  
Yao Cui ◽  
Jixian Wang ◽  
Lei Yu ◽  
Ying Xu ◽  
David J. Young ◽  
...  
Keyword(s):  
Functional Group ◽  
Catalytic Efficiency ◽  
Organic Polymer ◽  
Pincer Ligands ◽  
High Catalytic Activity ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Solid Supports ◽  
Porous Organic Polymer ◽  
Heterogeneous And Homogeneous Catalysis

Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl3) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling of secondary and primary alcohols to give β-alkylated secondary alcohols. This catalyst demonstrated excellent durability during successive recycling without leaching of Ru which is ascribed to the strong binding of the pincer ligands to the metal ions.

Aerobic oxidation of primary alcohols in the presence of activated secondary alcohols

2005 ◽  
Vol 46 (5) ◽  
pp. 783-786 ◽  
Author(s):  
Hiromichi Egami ◽  
Hideki Shimizu ◽  
Tsutomu Katsuki
Keyword(s):  
Aerobic Oxidation ◽  
Secondary Alcohols ◽  
Primary Alcohols

Ti(OiPr)4-Enabled Dual Photoredox and Nickel-Catalyzed Arylation and Alkenylation of Cyclopropanols

2021 ◽  
Author(s):  
Nastassia A. Varabyeva ◽  
Maryia V. Barysevich ◽  
Yauhen Aniskevich ◽  
Alaksiej Hurski
Keyword(s):  
Cross Coupling ◽  
Unsaturated Ketones

<p>In this article, we report an application of cyclopropanols as coupling partners in the dual photoredox/nickel catalyzed reaction with aryl and vinyl bromides. We found that this cross-coupling proceeds smoothly in the presence of Ti(OiPr)<sub>4</sub> as an additive to provide β-aryl or γ,δ-unsaturated ketones. </p>

One Pot Tandem Dual C=C and C=O Bond Reductions in β-Alkylation of Secondary Alcohols with Primary Alcohols by Ruthenium Complexes of Amido and Picolyl Functionalized N-Heterocyclic Carbenes

2021 ◽  
Author(s):  
A. P. Prakasham ◽  
Sabyasachi Ta ◽  
Shreyata Dey ◽  
Prasenjit Ghosh
Keyword(s):  
Ruthenium Complexes ◽  
Heterocyclic Carbenes ◽  
Secondary Alcohols ◽  
Coupling Reactions ◽  
Primary Alcohols ◽  
One Pot ◽  
The One ◽  
Alcohol Alcohol

Two different class of ruthenium complexes, namely, [1-mesityl-3-(2,6-Me2-phenylacetamido)-imidazol-2-ylidene]Ru(p-cymene)Cl (1c) and {[1-(pyridin-2-ylmethyl)-3-(2,6-Me2-phenyl)-imidazol-2-ylidene]Ru(p-cymene)Cl}Cl (2c), successfully carried out the one-pot tandem alcohol-alcohol coupling reactions of a variety of secondary and primary alcohols, in...

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