A new and different insight into the promotion mechanisms of Ga for the hydrogenation of carbon dioxide to methanol over a Ga-doped Ni(211) bimetallic catalyst

Nanoscale ◽  
2019 ◽  
Vol 11 (20) ◽  
pp. 9969-9979 ◽  
Author(s):  
Qingli Tang ◽  
Wenchao Ji ◽  
Christopher K. Russell ◽  
Yulong Zhang ◽  
Maohong Fan ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Bimetallic Catalyst ◽  
The Future ◽  
Hydrogenation Of Carbon Dioxide ◽  
Insight Into ◽  
Hydrogenation Of Co

The hydrogenation of CO2 to CH3OH is one of the most promising technologies for the utilization of captured CO2 in the future.

scholarly journals Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium–Triphos catalyst: from mechanistic investigations to multiphase catalysis

2015 ◽  
Vol 6 (1) ◽  
pp. 693-704 ◽  
Author(s):  
Sebastian Wesselbaum ◽  
Verena Moha ◽  
Markus Meuresch ◽  
Sandra Brosinski ◽  
Katharina M. Thenert ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mechanistic Investigations ◽  
Organometallic Catalyst ◽  
First Time ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

The hydrogenation of CO2 to methanol using a recyclable molecular organometallic catalyst in the absence of an alcohol additive is demonstrated for the first time.

A phenanthroline-based porous organic polymer for the iridium-catalyzed hydrogenation of carbon dioxide to formate

2019 ◽  
Vol 7 (23) ◽  
pp. 14019-14026 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Sungho Yoon
Keyword(s):  
Carbon Dioxide ◽  
Functional Groups ◽  
Single Site ◽  
Organic Polymer ◽  
Selective Catalyst ◽  
Porous Organic Polymer ◽  
Highly Active ◽  
First Time ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

A novel phenanthroline-functionalized porous organic polymer (phen-POP) has been designed, and prepared for the first time without other reactive functional groups in the polymer skeleton. Post-synthetic metalation of phen-POP with IrCl3 afforded a single-site, highly active and selective catalyst for the hydrogenation of CO2 to formate.

Bio-inspired computational design of iron catalysts for the hydrogenation of carbon dioxide

2015 ◽  
Vol 51 (66) ◽  
pp. 13098-13101 ◽  
Author(s):  
Xinzheng Yang
Keyword(s):  
Carbon Dioxide ◽  
Active Center ◽  
Computational Design ◽  
Iron Complex ◽  
Iron Catalysts ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

A computationally designed aliphatic PNP iron complex as a mimic of the active center of [Fe]-hydrogenase for the hydrogenation of CO2.

scholarly journals Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine–diphosphine ligands

2015 ◽  
Vol 6 (5) ◽  
pp. 2928-2931 ◽  
Author(s):  
Chong Liu ◽  
Jian-Hua Xie ◽  
Gui-Long Tian ◽  
Wei Li ◽  
Qi-Lin Zhou
Keyword(s):  
Carbon Dioxide ◽  
Diphosphine Ligands ◽  
Diphosphine Ligand ◽  
Highly Efficient ◽  
Iridium Catalyst ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

A new iridium catalyst containing an imine–diphosphine ligand was developed for the hydrogenation of CO2 to formate.

scholarly journals Colloidal Cu/ZnO catalysts for the hydrogenation of carbon dioxide to methanol: investigating catalyst preparation and ligand effects

2017 ◽  
Vol 7 (17) ◽  
pp. 3842-3850 ◽  
Author(s):  
Sebastian D. Pike ◽  
Andrés García-Trenco ◽  
Edward R. White ◽  
Alice H. M. Leung ◽  
Jonathan Weiner ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Preparation Method ◽  
Catalyst Preparation ◽  
Ligand Effects ◽  
Highly Active ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

This paper reports on the influences of the catalyst preparation method and ligand effects for a series of highly active Cu/ZnO colloidal catalysts for the hydrogenation of CO2 to methanol.

Transfer hydrogenation of carbon dioxide and bicarbonate from glycerol under aqueous conditions

2018 ◽  
Vol 54 (48) ◽  
pp. 6184-6187 ◽  
Author(s):  
Jacob M. Heltzel ◽  
Matthew Finn ◽  
Diana Ainembabazi ◽  
Kai Wang ◽  
Adelina M. Voutchkova-Kostal
Keyword(s):  
Carbon Dioxide ◽  
Lactic Acid ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Waste Streams ◽  
Catalytic Transfer ◽  
Aqueous Conditions ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

Catalytic transfer hydrogenation of CO2 from glycerol to afford formic and lactic acid is an attractive path to valorizing two waste streams. The process is significantly more thermodynamically favorable than direct CO2 hydrogenation.

A mechanistic study and computational prediction of iron, cobalt and manganese cyclopentadienone complexes for hydrogenation of carbon dioxide

2016 ◽  
Vol 52 (84) ◽  
pp. 12422-12425 ◽  
Author(s):  
Hongyu Ge ◽  
Xiangyang Chen ◽  
Xinzheng Yang
Keyword(s):  
Carbon Dioxide ◽  
Computational Prediction ◽  
Mechanistic Study ◽  
Iron Cobalt ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

A series of cobalt and manganese cyclopentadienone complexes are proposed and examined computationally as promising catalysts for hydrogenation of CO2.

Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes — Effect of gas pressure and additives on rate in the liquid phase

2001 ◽  
Vol 79 (5-6) ◽  
pp. 719-724
Author(s):  
Colin A Thomas ◽  
R Jason Bonilla ◽  
Yong Huang ◽  
Philip G Jessop
Keyword(s):  
Carbon Dioxide ◽  
Formic Acid ◽  
Reaction Medium ◽  
Phase Behaviour ◽  
Kinetic Measurements ◽  
Insertion Mechanism ◽  
Acid Catalyzed ◽  
Gas Expansion ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

Kinetic and mechanistic studies of CO2 hydrogenation were performed in liquid triethylamine and at subcritical CO2 pressures to avoid complications from phase behaviour that are observed under supercritical conditions. Kinetic measurements of the hydrogenation of CO2 to formic acid, catalyzed by RuCl(O2CMe)(PMe3)4, support a CO2 insertion mechanism. The reaction is first-order in both H2 and CO2 under most conditions. The rate is strongly dependent on the choice of additive, with methanol giving the greatest rates. Because only trace amounts of methanol are needed, the effect of the additive is believed to involve direct interactions with the catalyst rather than changes in the physical properties of the reaction medium. The optimized rates exceed 3500 h–1. Addition of an inert gas affects the rate of the reaction, probably via the phenomenon of gas expansion of the liquid phase.Key words: carbon dioxide, homogeneous catalysis, hydrogenation, formic acid, expanded liquids.

scholarly journals Ruthenium Inserted Hydrotalcite (Ru-HT) Heterogeneous Catalyst for the Kinetic Studies of Selective Hydrogenation of Carbon Dioxide to Formic Acid

2021 ◽  
Author(s):  
Minaxi S. Maru ◽  
Sanwala Ram ◽  
Noorul Hasan Khan ◽  
Ram Sambhar Shukla
Keyword(s):  
Carbon Dioxide ◽  
Formic Acid ◽  
Heterogeneous Catalyst ◽  
Selective Hydrogenation ◽  
Kinetic Studies ◽  
Turnover Number ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

The kinetic studies have been done for the base-free hydrogenation of CO2 to formic acid using heterogeneous ruthenium inserted hydrotalcite (Ru-HT) catalyst. An impressive Turnover Number (TON = 11389) was...

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