Ultra-high adsorption of tetracycline antibiotics on garlic skin-derived porous biomass carbon with high surface area

2020 ◽  
Vol 44 (3) ◽  
pp. 1097-1106 ◽  
Author(s):  
Shujian Liu ◽  
Mingdi Pan ◽  
Zhongmin Feng ◽  
Yangchun Qin ◽  
Yun Wang ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Water Environment ◽  
High Specific Surface Area ◽  
Adsorption Properties ◽  
Porous Carbon Material ◽  
Biomass Carbon ◽  
High Adsorption ◽  
Tetracycline Antibiotics

A porous carbon material with ultra-high specific surface area was prepared from waste garlic skin, and exhibited excellent adsorption properties to TCs in a water environment.

scholarly journals Effective Poly (Cyclotriphosphazene-Co-4,4′-Sulfonyldiphenol)@rGO Sheets for Tetracycline Adsorption: Fabrication, Characterization, Adsorption Kinetics and Thermodynamics

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1540
Author(s):  
Muhammad Ahmad ◽  
Tehseen Nawaz ◽  
Mohammad Mujahid Alam ◽  
Yasir Abbas ◽  
Shafqat Ali ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
High Adsorption ◽  
Clean Environment ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
High Adsorption Capacity ◽  
Adsorption Equilibrium Data

The development of excellent drug adsorbents and clarifying the interaction mechanisms between adsorbents and adsorbates are greatly desired for a clean environment. Herein, we report that a reduced graphene oxide modified sheeted polyphosphazene (rGO/poly (cyclotriphosphazene-co-4,4′-sulfonyldiphenol)) defined as PZS on rGO was used to remove the tetracycline (TC) drug from an aqueous solution. Compared to PZS microspheres, the adsorption capacity of sheeted PZS@rGO exhibited a high adsorption capacity of 496 mg/g. The adsorption equilibrium data well obeyed the Langmuir isotherm model, and the kinetics isotherm was fitted to the pseudo-second-order model. Thermodynamic analysis showed that the adsorption of TC was an exothermic, spontaneous process. Furthermore, we highlighted the importance of the surface modification of PZS by the introduction of rGO, which tremendously increased the surface area necessary for high adsorption. Along with high surface area, electrostatic attractions, H-bonding, π-π stacking and Lewis acid-base interactions were involved in the high adsorption capacity of PZS@rGO. Furthermore, we also proposed the mechanism of TC adsorption via PZS@rGO.

Facile Synthesis of Nanoporous Carbons with High Surface Area and Their CO2 Adsorption Properties

2015 ◽  
Vol 44 (7) ◽  
pp. 1004-1006
Author(s):  
Takahito Mitome ◽  
Yoshiaki Uchida ◽  
Norikazu Nishiyama
Keyword(s):  
Surface Area ◽  
Co2 Adsorption ◽  
High Surface ◽  
High Surface Area ◽  
Adsorption Properties ◽  
Facile Synthesis ◽  
Nanoporous Carbons

Facile and large-scale synthesis of poly(m-phenylenediamine) nanobelts with high surface area and superior dye adsorption ability

RSC Advances ◽  
2014 ◽  
Vol 4 (85) ◽  
pp. 45244-45250 ◽  
Author(s):  
Yun Meng ◽  
Liyuan Zhang ◽  
Liyuan Chai ◽  
Wanting Yu ◽  
Ting Wang ◽  
...  
Keyword(s):  
Surface Area ◽  
Large Scale ◽  
High Surface ◽  
High Surface Area ◽  
Dye Adsorption ◽  
High Adsorption ◽  
Adsorption Ability ◽  
Adsorption Performance ◽  
Large Scale Synthesis

PmPD nanobelts with high adsorption performance have been synthesized by using CTAP as oxidants.

Morphology dependent adsorption of methylene blue on trititanate nanoplates and nanotubes prepared by the hydrothermal treatment of TiO2

2016 ◽  
Vol 75 (2) ◽  
pp. 350-357
Author(s):  
Graham Dawson ◽  
Wei Chen ◽  
Luhua Lu ◽  
Kai Dai
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Pore Volume ◽  
Hydrothermal Reaction ◽  
Low Cost ◽  
High Surface ◽  
High Surface Area ◽  
High Capacity ◽  
Adsorption Properties

The adsorption properties of two nanomorphologies of trititanate, nanotubes (TiNT) and plates (TiNP), prepared by the hydrothermal reaction of concentrated NaOH with different phases of TiO2, were examined. It was found that the capacity for both morphologies towards methylene blue (MB), an ideal pollutant, was extremely high, with the TiNP having a capacity of 130 mg/g, higher than the TiNT, whose capacity was 120 mg/g at 10 mg/L MB concentration. At capacity, the well-dispersed powders deposit on the floor of the reaction vessel. The two morphologies had very different structural and adsorption properties. TiNT with high surface area and pore volume exhibited exothermic monolayer adsorption of MB. TiNP with low surface area and pore volume yielded a higher adsorption capacity through endothermic multilayer adsorption governed by pore diffusion. TiNP exhibited a higher negative surface charge of −23 mV, compared to −12 mV for TiNT. The adsorption process appears to be an electrostatic interaction, with the cationic dye attracted more strongly to the nanoplates, resulting in a higher adsorption capacity and different adsorption modes. We believe this simple, low cost production of high capacity nanostructured adsorbent material has potential uses in wastewater treatment.

Modification of the adsorption properties of high surface area graphites by oxygen functional groups

Carbon ◽  
2008 ◽  
Vol 46 (15) ◽  
pp. 2096-2106 ◽  
Author(s):  
Montserrat R. Cuervo ◽  
Esther Asedegbega-Nieto ◽  
Eva Díaz ◽  
Salvador Ordóñez ◽  
Aurelio Vega ◽  
...  
Keyword(s):  
Surface Area ◽  
Functional Groups ◽  
High Surface ◽  
High Surface Area ◽  
Adsorption Properties ◽  
Oxygen Functional Groups

scholarly journals Synthesis and characterization of porous silica and polyaniline-porous silica composite materials with high surface area

2014 ◽  
Vol 49 (1) ◽  
pp. 1-8
Author(s):  
US Akhtar ◽  
MK Hossain ◽  
MS Miran ◽  
MYA Mollah
Keyword(s):  
Electron Microscopy ◽  
Pore Size ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Porous Silica ◽  
Nitrogen Adsorption ◽  
High Specific Surface Area ◽  
Molar Ratio ◽  
Cylindrical Pore

Porous silica materials were synthesized from tetraethyl orthosilicate (TEOS) using Pluronic P123 (non-ionic triblock copolymer, EO20PO70O20) as template under acidic conditions which was then used to prepare polyaniline (PAni) and porous silica composites (PAnisilica) at a fixed molar ratio. These materials were characterized by nitrogen adsorption-desorption isotherm measured by Barrett-Joyner- Halenda (BJH) method and pore size distribution from desorption branch and surface area measured by the Brunauer-Emmett-Teller (BET) method, scanning electron microscopy (SEM), transmission electron microscopy (TEM), TEM-energy dispersive X-ray (EDX) and Fourier transform infrared (FT-IR) spectroscopy. The composite maintains its structure even after the polymerization and the polymer is dispersed on the inorganic matrix. The rod-like porous silica was about 1?m to 1.5 ?m long and on an average the diameter was in the range of 300- 500 nm. The SEM and TEM images show well ordered 2d hexagonal pore, high specific surface area (850 m2g-1) and uniform pore size of ca. 6.5 nm in diameter. After incorporation of PAni inside the silica pore, framework of porous silica did not collapse and the surface area of the composite was as high as 434 m2g-1 which was 5.5 time higher than our previous report of 78.3 m2g-1. Due to shrinkage of the framework during the incorporation of aniline inside the silica, the pore diameter slightly increase to 7.5 nm but still showing Type IV isotherm and typical hysteresis loop H1 implying a uniform cylindrical pore geometry. DOI: http://dx.doi.org/10.3329/bjsir.v49i1.18847 Bangladesh J. Sci. Ind. Res. 49(1), 1-8, 2014

scholarly journals Rice Husk-Derived High Surface Area Nanoporous Carbon Materials with Excellent Iodine and Methylene Blue Adsorption Properties

2019 ◽  
Vol 5 (1) ◽  
pp. 10 ◽  
Author(s):  
Lok Shrestha ◽  
Mamata Thapa ◽  
Rekha Shrestha ◽  
Subrata Maji ◽  
Raja Pradhananga ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Surface Area ◽  
Rice Husk ◽  
Carbon Materials ◽  
High Surface ◽  
High Surface Area ◽  
Nanoporous Carbon ◽  
Adsorption Properties ◽  
Methylene Blue Adsorption ◽  
Nanoporous Carbon Materials

Iodine and methylene blue adsorption properties of the high surface area nanoporous carbon materials derived from agro-waste and rice husk is reported. Rice husk was pre-carbonized at 300 °C in air followed by leaching out the silica nanoparticles by extraction with sodium hydroxide solution. The silica-free rice husk char was mixed with chemical activating agents sodium hydroxide (NaOH), zinc chloride (ZnCl2), and potassium hydroxide (KOH) separately at a mixing ratio of 1:1 (wt%) and carbonized at 900 °C under a constant flow of nitrogen. The prepared carbon materials were characterized by scanning electron microscopy (SEM), Fourier transformed-infrared spectroscopy (FT-IR), powder X-ray diffraction (pXRD), and Raman scattering. Due to the presence of bimodal micro- and mesopore structures, KOH activated samples showed high specific surface area ca. 2342 m2/g and large pore volume ca. 2.94 cm3/g. Oxygenated surface functional groups (hydroxyl, carbonyl, and carboxyl) were commonly observed in all of the samples and were essentially non-crystalline porous particle size of different sizes (<200 μm). Adsorption study revealed that KOH activated samples could be excellent material for the iodine and methylene blue adsorption from aqueous phase. Iodine and methylene blue number were ca. 1726 mg/g and 608 mg/g, respectively. The observed excellent iodine and methylene blue adsorption properties can be attributed to the well-developed micro- and mesopore structure in the carbon material. This study demonstrates that the agricultural waste, rice husk, and derived nanoporous carbon materials would be excellent adsorbent materials in water purifications.

Hierarchical flowerlike magnesium oxide hollow spheres with extremely high surface area for adsorption and catalysis

2016 ◽  
Vol 4 (2) ◽  
pp. 400-406 ◽  
Author(s):  
Shuliang Yang ◽  
Peipei Huang ◽  
Li Peng ◽  
Changyan Cao ◽  
Yanan Zhu ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Surface Area ◽  
Magnesium Oxide ◽  
Heavy Metal Ions ◽  
Catalytic Properties ◽  
Condensation Reaction ◽  
High Surface ◽  
Hollow Spheres ◽  
High Surface Area ◽  
Adsorption Properties

3D hierarchical flowerlike MgO hollow spheres with extremely high surface area showed excellent adsorption properties for heavy metal ions and catalytic properties for the Claisen–Schmidt condensation reaction.

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