POP-Pd(ii) catalyzed easy and safe in situ carbonylation towards the synthesis of α-ketoamides from secondary cyclic amines utilizing CHCl3 as a carbon monoxide surrogate

2020 ◽  
Vol 44 (5) ◽  
pp. 1979-1987 ◽  
Author(s):  
Sk Safikul Islam ◽  
Sk Riyajuddin ◽  
Rostam Ali Molla ◽  
Nasima Yasmin ◽  
Kaushik Ghosh ◽  
...  

POP-palladium(ii) was synthesized for the in situ carbonylation of aryl iodides and secondary cyclic amine to the respective α-ketoamides.

Author(s):  
Thulani M. Nyathi ◽  
Mohamed I. Fadlalla ◽  
Nico Fischer ◽  
Andrew P.E. York ◽  
Ezra J. Olivier ◽  
...  

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Lian Wang ◽  
Juncheng Zhou ◽  
Yuhao Chen ◽  
Liu Xiao ◽  
Guojia Huang ◽  
...  

Abstract An intensity modulated fiber-optic carbon monoxide (CO) sensor by integrating in-situ solvothermal-growth Ag/Co-MOF sensing film is fabricated and evaluated. The Michelson interference sensing structure is composed of single-mode fiber (SMF), enlarged taper, thin-core fiber (TCF), and Ag film as the reflector. Ag/Co-MOF was coated on the cladding of the TCF as the sensing material, and the enlarged taper is located between TCF and SMF as the coupler. The structure, morphology, compositions and thermal stability of the Ag/Co-MOF sensing film were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), etc. The sensitivity of the sensor is 0.04515 dB/ppm, and the fitting parameter of the CO concentration is 0.99876. In addition, the sensor has the advantages of good selectivity, good signal and temperature stability, and it has potential application in trace CO detection.


ChemInform ◽  
2003 ◽  
Vol 34 (24) ◽  
Author(s):  
Sandro Cacchi ◽  
Giancarlo Fabrizi ◽  
Federica Gavazza ◽  
Antonella Goggiamani

2021 ◽  
Vol 62 (1) ◽  
pp. 160-171
Author(s):  
A. M. Kremneva ◽  
A. V. Fedorov ◽  
A. A. Saraev ◽  
O. A. Bulavchenko ◽  
V. A. Yakovlev ◽  
...  

Carbon ◽  
2020 ◽  
Vol 158 ◽  
pp. 110-120
Author(s):  
Junsung Hong ◽  
Youngjin Ko ◽  
Kwang-Yeon Cho ◽  
Dong-Geun Shin ◽  
Prabhakar Singh ◽  
...  

2020 ◽  
Vol 59 (41) ◽  
pp. 17887-17896 ◽  
Author(s):  
Philip Boehm ◽  
Sven Roediger ◽  
Alessandro Bismuto ◽  
Bill Morandi

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