CoII immobilized on an aminated magnetic metal–organic framework catalyzed C–N and C–S bond forming reactions: a journey for the mild and efficient synthesis of arylamines and arylsulfides

2019 ◽  
Vol 43 (39) ◽  
pp. 15525-15538 ◽  
Author(s):  
Arezou Mohammadinezhad ◽  
Batool Akhlaghinia
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Efficient Synthesis ◽  
Bond Forming ◽  
Cross Coupling Reactions ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Organic Framework

The catalytic activity of Fe3O4@AMCA-MIL53(Al)-NH2-CoII NPs as a novel and inexpensive catalyst was investigated in the C–N and C–S cross coupling reactions.

Palladium nanoparticles encapsulated inside the pores of a metal–organic framework as a highly active catalyst for carbon–carbon cross-coupling

RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54487-54493 ◽  
Author(s):  
Ningzhao Shang ◽  
Shutao Gao ◽  
Xin Zhou ◽  
Cheng Feng ◽  
Zhi Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Palladium nanoparticles were successfully encapsulated in the cages of MIL-101, which exhibited high catalytic activity toward the C–C coupling reactions.

scholarly journals Heterogeneous Metal–Organic Framework Catalysts for Suzuki-Miyaura Cross Coupling in the Pharma Industry

2021 ◽  
Vol 75 (11) ◽  
pp. 972-978
Author(s):  
Daniele Cartagenova ◽  
Stephan Bachmann ◽  
Jeroen A. Van Bokhoven ◽  
Kurt Püntener ◽  
Marco Ranocchiari
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
Critical Parameters ◽  
Coupling Reactions ◽  
Present Contribution ◽  
Heterogeneous Catalytic ◽  
Cross Coupling Reactions ◽  
Metal Organic ◽  
Organic Framework

The synthesis of drug substances (DS) requires the continuous effort of the pharma industry to ensure high sustainability standards. The Suzuki-Miyaura cross coupling is a fundamental C–C bond-forming reaction to produce complex DS intermediates. The present contribution points out the way in which the synthesis of DS intermediates by C–C cross coupling can be economically competitive, while minimizing waste by selecting the appropriate heterogeneous catalyst. By comparing homogeneous, immobilized heterogeneous catalysts on silica and metal–organic framework (MOF) catalysts, while considering the perspectives of academia and industry, the critical parameters for a successful industrial application of heterogeneous catalytic Suzuki-Miyaura cross coupling reactions were identified. Heterogeneous catalysts, such as MOFs, may provide a complementary platform for reducing waste and the costs of production related to such transformations.

Design and synthesis of a new magnetic metal organic framework as a versatile platform for immobilization of acidic catalysts and CO2 fixation reaction

2021 ◽  
Author(s):  
Faezeh Taghavi ◽  
Amir Khojastehnezhad ◽  
Reza Khalifeh ◽  
Maryam Rajabzadeh ◽  
Fahimeh Rezaei ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
Chemical Fixation ◽  
Design And Synthesis ◽  
Acidic Catalysts ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Fixation Reaction ◽  
Organic Framework

The first report of the use of an acidic magnetic metal organic framework for the chemical fixation of CO2 as an environmentally friendly reaction.

scholarly journals Enhancement of Thermostability of Aspergillus flavus Urate Oxidase by Immobilization on the Ni-Based Magnetic Metal–Organic Framework

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1759
Author(s):  
Neda Motamedi ◽  
Mahmood Barani ◽  
Azadeh Lohrasbi-Nejad ◽  
Mojtaba Mortazavi ◽  
Ali Riahi-Medvar ◽  
...  
Keyword(s):  
Aspergillus Flavus ◽  
Metal Organic Framework ◽  
Urate Oxidase ◽  
Significant Activity ◽  
Original Activity ◽  
Long Term Stability ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Almost All ◽  
Organic Framework

The improvement in the enzyme activity of Aspergillus flavus urate oxidase (Uox) was attained by immobilizing it on the surface of a Ni-based magnetic metal–organic framework (NimMOF) nanomaterial; physicochemical properties of NimMOF and its application as an enzyme stabilizing support were evaluated, which revealed a significant improvement in its stability upon immobilization on NimMOF (Uox@NimMOF). It was affirmed that while the free Uox enzyme lost almost all of its activity at ~40–45 °C, the immobilized Uox@NimMOF retained around 60% of its original activity, even retaining significant activity at 70 °C. The activation energy (Ea) of the enzyme was calculated to be ~58.81 kJ mol−1 after stabilization, which is approximately half of the naked Uox enzyme. Furthermore, the external spectroscopy showed that the MOF nanomaterials can be coated by hydrophobic areas of the Uox enzyme, and the immobilized enzyme was active over a broad range of pH and temperatures, which bodes well for the thermal and long-term stability of the immobilized Uox on NimMOF.

Removal of lead ions from aqueous solution using new magnetic metal-organic framework

2021 ◽  
pp. 1-30
Author(s):  
Homeira Nasiri ◽  
Farshad Yazdani ◽  
Jalal Zeinali ◽  
Hamid Reza Mortaheb
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Framework ◽  
Lead Ions ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Organic Framework
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