Pyridyl and pyrimidyl chalcogenolates of coinage metals and their utility as molecular precursors for the preparation of metal chalcogenides

2019 ◽  
Vol 43 (28) ◽  
pp. 11034-11040
Author(s):  
Vimal K. Jain
Keyword(s):  
Metal Chalcogenides ◽  
Molecular Precursors ◽  
Ternary Chalcogenide ◽  
Coinage Metals ◽  
Chalcogenide Materials ◽  
Metallophilic Interactions

Synthesis of and metallophilic interactions in N-heterocyclic chalcogenolates of coinage metals have been described and their utility as molecular precursors for binary and ternary chalcogenide materials has been demonstrated.

scholarly journals Solution-Based Synthesis and Processing of Metal Chalcogenides for Thermoelectric Applications

2019 ◽  
Vol 9 (7) ◽  
pp. 1511 ◽  
Author(s):  
Kwok Wei Shah ◽  
Su-Xi Wang ◽  
Yun Zheng ◽  
Jianwei Xu
Keyword(s):  
Processing Method ◽  
Thermoelectric Generators ◽  
Metal Chalcogenides ◽  
Controllable Synthesis ◽  
Metal Chalcogenide ◽  
High Conversion Efficiency ◽  
Device Development ◽  
Synthesis And Processing ◽  
Chalcogenide Materials ◽  
State Of Art

Metal chalcogenide materials are current mainstream thermoelectric materials with high conversion efficiency. This review provides an overview of the scalable solution-based methods for controllable synthesis of various nanostructured and thin-film metal chalcogenides, as well as their properties for thermoelectric applications. Furthermore, the state-of-art ink-based processing method for fabrication of thermoelectric generators based on metal chalcogenides is briefly introduced. Finally, the perspective on this field with regard to material production and device development is also commented upon.

Organochalcogenolates of Palladium(II) and Platinum(II): Versatile Molecular Precursors for Metal Chalcogenides

2008 ◽  
Vol 183 (4) ◽  
pp. 1003-1008 ◽  
Author(s):  
Vimal K. Jain ◽  
Liladhar B. Kumbhare ◽  
Sandip Dey ◽  
Ninad D. Ghavale
Keyword(s):  
Metal Chalcogenides ◽  
Molecular Precursors

scholarly journals Metal–metal chalcogenide molecular precursors to binary, ternary, and quaternary metal chalcogenide thin films for electronic devices

2016 ◽  
Vol 52 (28) ◽  
pp. 5007-5010 ◽  
Author(s):  
Ruihong Zhang ◽  
Seonghyuk Cho ◽  
Daw Gen Lim ◽  
Xianyi Hu ◽  
Eric A. Stach ◽  
...  
Keyword(s):  
Thin Films ◽  
Primary Amine ◽  
Electronic Devices ◽  
Solvent Mixtures ◽  
Metal Chalcogenides ◽  
Ambient Conditions ◽  
Metal Chalcogenide ◽  
Molecular Precursors ◽  
Metal Metal ◽  
Chalcogenide Thin Films

Bulk metals and metal chalcogenides are found to dissolve in primary amine–dithiol solvent mixtures at ambient conditions.

Synthesis and Properties of Molecular Fragments of Metal Chalcogenides

1992 ◽  
Vol 272 ◽  
Author(s):  
Michael L. Steigerwald
Keyword(s):  
Reverse Micelles ◽  
Metal Chalcogenides ◽  
Molecular Fragments ◽  
Molecular Precursors ◽  
Inorganic Solids ◽  
The Third ◽  
Metal Selenides

ABSTRACTIn this manuscript we describe several approaches to the preparation of molecule-sized fragments of inorganic solids. The first is the arrested precipitation of metal selenides in reverse micelles; the second is the arrested pyrolysis of molecular precursors to II–VI compounds; and the third is the chemical moderation of molecules-to-solids reactions.

A New Dimension in Cyclic Coinage Metal Pyrazolates: Decoration with a Second Ring of Coinage Metals Supported by Inter-ring Metallophilic Interactions

2012 ◽  
Vol 134 (6) ◽  
pp. 2938-2941 ◽  
Author(s):  
Ann Christin Jahnke ◽  
Kevin Pröpper ◽  
Catherine Bronner ◽  
Jörg Teichgräber ◽  
Sebastian Dechert ◽  
...  
Keyword(s):  
Coinage Metal ◽  
Coinage Metals ◽  
Metallophilic Interactions
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