Selective catalytic oxidation of benzene to phenol by a vanadium oxide nanorod (Vnr) catalyst in CH3CN using H2O2(aq) and pyrazine-2-carboxylic acid (PCA)

2019 ◽  
Vol 43 (45) ◽  
pp. 17819-17830 ◽  
Author(s):  
Wondemagegn Hailemichael Wanna ◽  
Damodar Janmanchi ◽  
Natarajan Thiyagarajan ◽  
Ravirala Ramu ◽  
Yi-Fang Tsai ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Vanadium Oxide ◽  
Catalytic Oxidation ◽  
Phenol Oxidation ◽  
Highly Active ◽  
Selective Catalytic Oxidation ◽  
Oxidation Of Benzene

A vanadium oxide nanorod (Vnr) catalyst has been synthesized without using surfactants through crystallization, which is highly active for benzene to phenol oxidation.

A nanohybrid self-assembled from exfoliated layered vanadium oxide nanosheets and Keggin Al13 for selective catalytic oxidation of alcohols

2020 ◽  
Vol 49 (8) ◽  
pp. 2559-2569 ◽  
Author(s):  
Shuang Wang ◽  
Shuying Li ◽  
Rui Shi ◽  
Xinyu Zou ◽  
Zhijuan Zhang ◽  
...  
Keyword(s):  
Vanadium Oxide ◽  
Catalytic Oxidation ◽  
Selective Oxidation ◽  
Self Assembly ◽  
The Self ◽  
Selective Catalytic Oxidation ◽  
Oxidation Of Alcohols ◽  
Self Assembled

A porous V2O5–Al13 nanohybrid based on the self-assembly of Keggin Al13 and exfoliated V2O5 nanosheets for selective oxidation of alcohols.

Selective catalytic oxidation of benzene over Cu/Ti/HZSM-5 under low oxygen pressure for one step synthesis of phenol

2016 ◽  
Vol 411 ◽  
pp. 372-376 ◽  
Author(s):  
Atsushi Okemoto ◽  
Yo-hei Tsukano ◽  
Arisa Utsunomiya ◽  
Keita Taniya ◽  
Yuichi Ichihashi ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Oxygen Pressure ◽  
Low Oxygen ◽  
Selective Catalytic Oxidation ◽  
One Step ◽  
Oxidation Of Benzene ◽  
Low Oxygen Pressure

Catalytic oxidation of benzene, toluene and p-xylene over colloidal gold supported on zinc oxide catalyst

2011 ◽  
Vol 12 (10) ◽  
pp. 859-865 ◽  
Author(s):  
Hongjing Wu ◽  
Liuding Wang ◽  
Jiaoqiang Zhang ◽  
Zhongyuan Shen ◽  
Jinghui Zhao
Keyword(s):  
Zinc Oxide ◽  
Catalytic Oxidation ◽  
Colloidal Gold ◽  
Oxide Catalyst ◽  
Benzene Toluene ◽  
Oxidation Of Benzene

scholarly journals Electron donation of non-oxide supports boosts O2 activation on nano-platinum catalysts

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Tao Gan ◽  
Jingxiu Yang ◽  
David Morris ◽  
Xuefeng Chu ◽  
Peng Zhang ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Pt Nanoparticles ◽  
Catalytic Performance ◽  
Nitrogen Vacancy ◽  
Innovative Strategy ◽  
Oxide Supports ◽  
Heterogeneous Catalytic ◽  
Highly Active ◽  
Electron Sink ◽  
Nitrogen Vacancies

AbstractActivation of O2 is a critical step in heterogeneous catalytic oxidation. Here, the concept of increased electron donors induced by nitrogen vacancy is adopted to propose an efficient strategy to develop highly active and stable catalysts for molecular O2 activation. Carbon nitride with nitrogen vacancies is prepared to serve as a support as well as electron sink to construct a synergistic catalyst with Pt nanoparticles. Extensive characterizations combined with the first-principles calculations reveal that nitrogen vacancies with excess electrons could effectively stabilize metallic Pt nanoparticles by strong p-d coupling. The Pt atoms and the dangling carbon atoms surround the vacancy can synergistically donate electrons to the antibonding orbital of the adsorbed O2. This synergistic catalyst shows great enhancement of catalytic performance and durability in toluene oxidation. The introduction of electron-rich non-oxide substrate is an innovative strategy to develop active Pt-based oxidation catalysts, which could be conceivably extended to a variety of metal-based catalysts for catalytic oxidation.

scholarly journals A new highly active La2O3–CuO–MgO catalyst for the synthesis of cumyl peroxide by catalytic oxidation

RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12532-12542
Author(s):  
HanShuang Liu ◽  
KaiJun Wang ◽  
XiaoYan Cao ◽  
JiaXin Su ◽  
Zhenggui Gu
Keyword(s):  
Catalytic Activity ◽  
Catalytic Oxidation ◽  
Highly Active

The La2O3–CuO–MgO catalyst acts on the oxidation of cumene and shows excellent catalytic activity through the coordination of surface and interior.

Gas phase interaction with catalytic oxidation reactions

1972 ◽  
Vol 326 (1565) ◽  
pp. 215-227 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Maleic Anhydride ◽  
Catalytic Oxidation ◽  
Gas Phase ◽  
Major Part ◽  
Oxidation Reactions ◽  
Mixed Gas ◽  
Kinetics Of ◽  
Oxidation Of Benzene ◽  
Homogeneous Decomposition

Studies of the catalytic oxidation of benzene to maleic anhydride and carbon dioxide over vanadia/molybdena catalysts show that the major part of the reaction involves interacting gas and gas-solid processes. The results are consistent with a mechanism in which a benzeneoxygen adduct is formed catalytically, desorbs and then reacts to give maleic anhydride entirely in the gas phase. On the basis of this proposed mechanism, the kinetics of individual reactions have been investigated in some depth. The over-oxidation of maleic anhydride has been found to be not significant under the conditions of reaction. The kinetic relationships governing the homogeneous decomposition of the adduct and the oxidation of the adduct to maleic anhydride and to carbon dioxide have been established. The results show that essentially all of the anhydride originates from mixed gas-solid/gas reaction while substantial amounts of carbon dioxide are produced entirely catalytically.

scholarly journals Study on the NO removal efficiency of the lignite pyrolysis coke catalyst by selective catalytic oxidation method

PLoS ONE ◽  
2017 ◽  
Vol 12 (8) ◽  
pp. e0182424 ◽  
Author(s):  
Lei Zhang ◽  
Xin Wen ◽  
Zhenhua Ma ◽  
Lei Zhang ◽  
Xiangling Sha ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Removal Efficiency ◽  
No Removal ◽  
Oxidation Method ◽  
Selective Catalytic Oxidation ◽  
Pyrolysis Coke
Sign in / Sign up

Export Citation Format

Share Document