Fabrication of Fe3O4-based ternary magnetic microsphere catalysts based on supramolecular chemistry and their catalytic performance

2019 ◽  
Vol 43 (22) ◽  
pp. 8482-8491 ◽  
Author(s):  
Yuan Chen ◽  
Wenjie Liu ◽  
Jun Zhou ◽  
Ming Chen
Keyword(s):  
Supramolecular Chemistry ◽  
Self Assembly ◽  
Catalytic Performance ◽  
Magnetic Microsphere ◽  
Assembly Strategy ◽  
Guest Chemistry

In this paper, magnetic catalysts were successfully synthesized using host–guest chemistry and a self-assembly strategy.

scholarly journals Acid-Activated Motion Switching of DB24C8 between Two Discrete Platinum(II) Metallacycles

Molecules ◽  
2021 ◽  
Vol 26 (3) ◽  
pp. 716
Author(s):  
Yi-Xiong Hu ◽  
Gui-Yuan Wu ◽  
Xu-Qing Wang ◽  
Guang-Qiang Yin ◽  
Chang-Wei Zhang ◽  
...  
Keyword(s):  
Supramolecular Chemistry ◽  
Self Assembly ◽  
Molecular Motion ◽  
Stimuli Responsive ◽  
Supramolecular Systems ◽  
Acid Base ◽  
Interlocked Molecules ◽  
Assembly Strategy ◽  
Cooperative Motion ◽  
Recognition Sites

The precise operation of molecular motion for constructing complicated mechanically interlocked molecules has received considerable attention and is still an energetic field of supramolecular chemistry. Herein, we reported the construction of two tris[2]pseudorotaxanes metallacycles with acid–base controllable molecular motion through self-sorting strategy and host–guest interaction. Firstly, two hexagonal Pt(II) metallacycles M1 and M2 decorated with different host–guest recognition sites have been constructed via coordination-driven self-assembly strategy. The binding of metallacycles M1 and M2 with dibenzo-24-crown-8 (DB24C8) to form tris[2]pseudorotaxanes complexes TPRM1 and TPRM2 have been investigated. Furthermore, by taking advantage of the strong binding affinity between the protonated metallacycle M2 and DB24C8, the addition of trifluoroacetic acid (TFA) as a stimulus successfully induces an acid-activated motion switching of DB24C8 between the discrete metallacycles M1 and M2. This research not only affords a highly efficient way to construct stimuli-responsive smart supramolecular systems but also offers prospects for precisely control multicomponent cooperative motion.

Tunable Microstructures of Ultralong Organic Phosphorescence Materials

2021 ◽  
Author(s):  
Kun Liu ◽  
Kaiwei Huang ◽  
Anqi Lv ◽  
Wenpeng Ye ◽  
Yijun Yang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Solution Concentration ◽  
Assembly Strategy ◽  
Considerable Promise ◽  
Organic Phosphor

Three kinds of microstructures of one organic phosphor were perpared based on a solution-concentration-controlled self-assembly strategy. These microstructures show different phosphorescence efficiency, which holds considerable promise for the miniaturized optical...

A colon-targeted podophyllotoxin nanoprodrug: synthesis, characterization, and supramolecular hydrogel formation for the drug combination

2021 ◽  
Vol 9 (14) ◽  
pp. 3200-3209
Author(s):  
Wei Ha ◽  
Xiao-Bo Zhao ◽  
Wei-Hua Zhao ◽  
Jiang-Jiang Tang ◽  
Yan-Ping Shi
Keyword(s):  
Self Assembly ◽  
Drug Combination ◽  
Therapeutic Agents ◽  
Supramolecular Hydrogel ◽  
Assembly Strategy ◽  
Hydrogel Formation

An ingeniously designed podophyllotoxin nanoprodrug was synthesized and offered an effective platform for co-delivery of multiple therapeutic agents for drug combination via the hierarchical self-assembly strategy.

Green synthesis of mesoporous MnNbOx oxide by a liquid induced self-assembly strategy for low-temperature removal of NOx

2019 ◽  
Vol 55 (100) ◽  
pp. 15073-15076 ◽  
Author(s):  
Huifang Cheng ◽  
Guodong Feng ◽  
Zhenzhen Yang ◽  
Tao Wang ◽  
Francis Okejiri ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Low Temperature ◽  
Green Synthesis ◽  
Self Assembly ◽  
Assembly Strategy ◽  
Highly Porous

A highly porous MnNbOx with excellent low-temperature NOx reduction was fabricated by a facile, sustainable ionic liquid induced self-assembly strategy.

An interfacial self-assembly strategy to fabricate graphitic hollow porous carbon spheres for supercapacitor electrodes

Carbon ◽  
2021 ◽  
Vol 182 ◽  
pp. 860
Author(s):  
Xiao-hua Zhang ◽  
Xin-yu Gan ◽  
Bao-sheng Liu ◽  
Xiao-yan Yan ◽  
Xin-xin Zhao
Keyword(s):  
Porous Carbon ◽  
Self Assembly ◽  
Carbon Spheres ◽  
Assembly Strategy ◽  
Porous Carbon Spheres

Effect of Preparation Methods of HPW/SiO2 Mesoporous Composites on its Catalytic Performance in Fuel Oils Desulfurization

2010 ◽  
Vol 148-149 ◽  
pp. 924-928
Author(s):  
Xue Min Yan ◽  
Yuan Zhu Mi
Keyword(s):  
Catalytic Activity ◽  
Self Assembly ◽  
Electrostatic Force ◽  
Oxidative Desulfurization ◽  
Strong Acid ◽  
Catalytic Performance ◽  
Synthesis Mechanism ◽  
Base Interaction ◽  
Preparation Methods ◽  
Oh Groups

Two kinds of mesoporous HPW/SiO2 composites, which have been synthesized respectively by the amino-functionalized (AF) method and evaporation-induced self-assembly (EISA) method, have been used as catalysts in the oxidative desulfurization process of dibenzothiophene(DBT). The catalytic performance results show that the catalyst synthesized by EISA method holds higher catalytic activity than that synthesized by the AF method. The difference of catalytic activity can be attributed to the different synthesis mechanism of two kinds of composites. In the AF method, the bonding force between HPW and SiO2 is strong acid-base interaction, which damages the Keggin structure. Whereas in the EISA process, electrostatic force and hydrogen bonds between W=O groups and Si-OH groups are main bonding forces. The hydrogen bond holds the electron-withdrawing effect, which increases the activity of nonbonding W=O groups in HPW and then results in the enhancement of the catalytic activity.

Nanostructuring of diamond films using self-assembled nanoparticles

Open Physics ◽  
2009 ◽  
Vol 7 (2) ◽  
Author(s):  
Oleg Babchenko ◽  
Alexander Kromka ◽  
Karel Hruska ◽  
Miroslav Michalka ◽  
Jiri Potmesil ◽  
...  
Keyword(s):  
Plasma Etching ◽  
Self Assembly ◽  
Diamond Films ◽  
Diamond Powder ◽  
Gas Mixture ◽  
Assembly Strategy ◽  
Nano Structures ◽  
Mask Type ◽  
Different Types ◽  
Nano Rods

AbstractWe report the use of gold, nickel and diamond nanoparticles as a masking material for realization of diamond nano-structures by applying the dry plasma etching process. Applying low power plasma (100 W) in a gas mixture of CF4/O2 for 5 minutes results in a formation of three different types of diamond nanostructures, depending on the mask type material and particle size. Using of the Ni mask results in realization of diamond nano-rods, applying of the Au mask brings cauliflower-like structures, and using the diamond powder allows the production of irregular nano-structures. The main advance of the presented etching procedure is use of a self-assembly strategy where no lithographic steps are implemented.

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