The solvent-free mechanochemical synthesis of mildly oxidized graphene oxide and its application as a novel conductive surfactant

2019 ◽  
Vol 43 (18) ◽  
pp. 7057-7064 ◽  
Author(s):  
Jianhui Chen ◽  
Wufeng Chen ◽  
Dongcheng Song ◽  
Bin Lai ◽  
Yuanyuan Sheng ◽  
...  

A solvent-free mechanochemical synthetic mildly oxidized graphene oxide (MOGO) can act as an electrically conductive surfactant for dispersing nanoparticles.

2015 ◽  
Vol 3 (30) ◽  
pp. 15529-15539 ◽  
Author(s):  
G. Bharath ◽  
Rajesh Madhu ◽  
Shen-Ming Chen ◽  
Vediyappan Veeramani ◽  
D. Mangalaraj ◽  
...  

Large-scale defect-free high quality graphene was synthesized by a mechanochemical process. The surface chemistry and functional properties of the Fe3O4 nanoparticles anchored on graphene were studied for the sensitive detection of nitrite from various water sources.


2019 ◽  
Vol 15 ◽  
pp. 963-970 ◽  
Author(s):  
Sora Park ◽  
Jeung Gon Kim

Mechanochemical polymerization is a rapidly growing area and a number of polymeric materials can now be obtained through green mechanochemical synthesis. In addition to the general merits of mechanochemistry, such as being solvent-free and resulting in high conversions, we herein explore rate acceleration under ball-milling conditions while the conventional solution-state synthesis suffer from low reactivity. The solvent-free mechanochemical polymerization of trimethylene carbonate using the organocatalysts 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) are examined herein. The polymerizations under ball-milling conditions exhibited significant rate enhancements compared to polymerizations in solution. A number of milling parameters were evaluated for the ball-milling polymerization. Temperature increases due to ball collisions and exothermic energy output did not affect the polymerization rate significantly and the initial mixing speed was important for chain-length control. Liquid-assisted grinding was applied for the synthesis of high molecular weight polymers, but it failed to protect the polymer chain from mechanical degradation.


Carbon ◽  
2011 ◽  
Vol 49 (14) ◽  
pp. 4724-4730 ◽  
Author(s):  
Wenjuan Li ◽  
Xiu-Zhi Tang ◽  
Hao-Bin Zhang ◽  
Zhi-Guo Jiang ◽  
Zhong-Zhen Yu ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (20) ◽  
pp. 15070-15076 ◽  
Author(s):  
Linxiang He ◽  
Sie Chin Tjong

Nano silver-decorated reduced graphene oxide (Ag–RGO) sheets were synthesized by simply dissolving graphite oxide and silver nitrate inN,N-dimethylformamide and keeping the suspension at 90 °C for 12 h.


RSC Advances ◽  
2017 ◽  
Vol 7 (36) ◽  
pp. 22045-22053 ◽  
Author(s):  
Neng-Jian Huang ◽  
Jing Zang ◽  
Guo-Dong Zhang ◽  
Li-Zhi Guan ◽  
Shi-Neng Li ◽  
...  

GONR-filled H-t-PDMS nanocomposites were fabricated by using a facile solvent-free process, and the reinforcement efficiency of GONRs at low filler content is superior to those of the other carbon nano-fillers.


CrystEngComm ◽  
2012 ◽  
Vol 14 (8) ◽  
pp. 2950 ◽  
Author(s):  
Ming Wang ◽  
Xueli Cao ◽  
Yunfang Huang ◽  
Chongshen Guo ◽  
Lijun Huang ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Rabindranath Singha ◽  
Aminul Islam ◽  
Pranab Ghosh

AbstractA convenient and efficient solvent-free, facile, one-pot three-component graphene oxide catalysed approach has been described for the synthesis of chromeno-[4,3-b]quinolin-6-one derivatives from 4-hydroxycoumarin with aldehydes and aromatic amines. Graphene oxide (GO) has proved to be a new class of heterogeneous carbocatalyst which could be easily recovered and reused up to 5th run without significant loss of its catalytic activity. A broad scope of substrate applicability is offered and a plausible mechanism is also suggested for this developed protocol.


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