scholarly journals Understanding the role of zinc dithiocarbamate complexes as single source precursors to ZnS nanomaterials

2020 ◽  
Vol 2 (2) ◽  
pp. 798-807 ◽  
Author(s):  
Husn-Ubayda Islam ◽  
Anna Roffey ◽  
Nathan Hollingsworth ◽  
Wim Bras ◽  
Gopinathan Sankar ◽  
...  

Heating [Zn(S2CNiBu2)2] in oleylamine affords high aspect ratio nanowires of ZnS and in situ XAS studies of the decomposition of [Zn(S2CNMe2)2] give insight into mechanistic aspects of the molecular transformations.

2019 ◽  
Vol 1 (8) ◽  
pp. 2965-2978 ◽  
Author(s):  
Anna Roffey ◽  
Nathan Hollingsworth ◽  
Husn-Ubayda Islam ◽  
Wim Bras ◽  
Gopinathan Sankar ◽  
...  

Fe(ii) and Fe(iii) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.


2021 ◽  
Vol 5 (7) ◽  
pp. 2055-2064
Author(s):  
Saheli Biswas ◽  
Aniruddha P. Kulkarni ◽  
Daniel Fini ◽  
Sarbjit Giddey ◽  
Sankar Bhattacharya

In situ synthesis of methane in a single-temperature zone SOEC in the absence of any methanation catalyst is a completely electrochemical phenomenon governed by the thermodynamic equilibrium of various reactions.


2021 ◽  
Vol 128 ◽  
pp. 108558
Author(s):  
Yuyue Guo ◽  
Yangfei Hu ◽  
Xiaojiong Luo ◽  
Shudong Lin ◽  
Jiwen Hu ◽  
...  

2010 ◽  
Vol 645-648 ◽  
pp. 271-276 ◽  
Author(s):  
Robert E. Stahlbush ◽  
Rachael L. Myers-Ward ◽  
Brenda L. VanMil ◽  
D. Kurt Gaskill ◽  
Charles R. Eddy

The recently developed technique of UVPL imaging has been used to track the path of basal plane dislocations (BPDs) in SiC epitaxial layers. The glide of BPDs during epitaxial growth has been observed and the role of this glide in forming half-loop arrays has been examined. The ability to track the path of BPDs through the epitaxy has made it possible to develop a BPD reduction process for epitaxy grown on 8° offcut wafers, which uses an in situ growth interrupt and has achieved a BPD reduction of > 98%. The images also provide insight into the strong BPD reduction that typically occurs in epitaxy grown on 4° offcut wafers.


2020 ◽  
Vol 38 (5) ◽  
pp. 053402
Author(s):  
Andrew Simon ◽  
Oscar van der Straten ◽  
Nicholas A. Lanzillo ◽  
Chih-Chao Yang ◽  
Takeshi Nogami ◽  
...  

2019 ◽  
Vol 115 ◽  
pp. 364-373 ◽  
Author(s):  
Yinghua Lin ◽  
Changchun Jiang ◽  
Zhenheng Lin ◽  
Qingtang Chen ◽  
Yongping Lei ◽  
...  

2019 ◽  
Vol 374 (1786) ◽  
pp. 20190083 ◽  
Author(s):  
Marta Sebastián ◽  
Josep M. Gasol

Recent developments in community and single-cell genomic approaches have provided an unprecedented amount of information on the ecology of microbes in the aquatic environment. However, linkages between each specific microbe's identity and their in situ level of activity (be it growth, division or just metabolic activity) are much more scarce. The ultimate goal of marine microbial ecology is to understand how the environment determines the types of different microbes in nature, their function, morphology and cell-to-cell interactions and to do so we should gather three levels of information, the genomic (including identity), the functional (activity or growth), and the morphological, and for as many individual cells as possible. We present a brief overview of methodologies applied to address single-cell activity in marine prokaryotes, together with a discussion of the difficulties in identifying and categorizing activity and growth. We then provide and discuss some examples showing how visualization has been pivotal for challenging established paradigms and for understanding the role of microbes in the environment, unveiling processes and interactions that otherwise would have been overlooked. We conclude by stating that more effort should be directed towards integrating visualization in future approaches if we want to gain a comprehensive insight into how microbes contribute to the functioning of ecosystems. This article is part of a discussion meeting issue ‘Single cell ecology’.


2018 ◽  
Vol 47 (9) ◽  
pp. 2933-2938 ◽  
Author(s):  
G. V. Manohara ◽  
Li Li ◽  
Andrew Whiting ◽  
H. Chris Greenwell

Hybrid layered double hydroxide materials with high aspect ratio have been prepared by slow hydrolysis of metal hydroxides with hydrophobic anions.


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