Determination of copper-based mineral species by laser induced breakdown spectroscopy and chemometric methods

2019 ◽  
Vol 34 (12) ◽  
pp. 2459-2468 ◽  
Author(s):  
Jonnathan Álvarez ◽  
Marizú Velásquez ◽  
Ashwin Kumar Myakalwar ◽  
Claudio Sandoval ◽  
Rodrigo Fuentes ◽  
...  
Keyword(s):  
Mineral Species ◽  
Laser Induced Breakdown Spectroscopy ◽  
Chemometric Methods ◽  
Direct Identification ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Determination Of Copper

The direct identification of mineral species in raw rocks was performed using laser induced breakdown spectroscopy (LIBS).

Fast Determination of Copper Content in Tobacco (Nicotina tabacum L.) Leaves Using Laser-Induced Breakdown Spectroscopy with Univariate and Multivariate Analysis

2018 ◽  
Vol 61 (3) ◽  
pp. 821-829 ◽  
Author(s):  
Jiyu Peng ◽  
Lanhan Ye ◽  
Tingting Shen ◽  
Fei Liu ◽  
Kunlin Song ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Multivariate Analysis ◽  
Copper Content ◽  
Laser Induced Breakdown Spectroscopy ◽  
Fast Determination ◽  
Tobacco Leaves ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Determination Of Copper

Abstract. Fast and effective measures to determine heavy metals play an important role in ensuring food quality and safety. In this experiment, laser-induced breakdown spectroscopy (LIBS) was used to detect copper content (Cu) in tobacco ( L.) leaves. The experimental parameters for detection, including laser energy, delay time, and camera gate width, were optimized by response surface methodology (RSM). Univariate analysis and multivariate analysis, including partial least squares regression (PLSR) and extreme learning machine (ELM), were used to establish calibration models. In addition, different preprocessing methods were used to eliminate the signal variations and further improve the calibration performance, including baseline correction, background normalization, area normalization, and standard normal variate (SNV) normalization. The results showed that LIBS combined with both univariate and multivariate methods could be used to detect copper content in tobacco leaves. SNV and area normalization were efficient in dealing with signal variations and improving the calibration performance. The ELM model with SNV normalized variables in the spectral region of 324.02 to 325.98 nm achieved the best performance (R2 = 0.9552 and RMSE = 4.8416 mg kg-1 in the testing set). The results provide the first proof-of-principle data for fast determination of copper content in tobacco leaves. Keywords: Copper content, Laser-induced breakdown spectroscopy, Multivariate calibration, Response surface methodology, Tobacco leaves, Univariate calibration.

Mechanization of measurement of laser induced breakdown spectroscopy/ring-oven pre-concentration: determination of copper in cachaça

2016 ◽  
Vol 8 (40) ◽  
pp. 7354-7360 ◽  
Author(s):  
Celio Pasquini ◽  
Benedito B. Farias Filho
Keyword(s):  
Internal Standard ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Concentration Determination ◽  
Concentration Technique ◽  
Ring Oven ◽  
Laser Induced Breakdown ◽  
Sensing Characteristics ◽  
Determination Of Copper

The hyphenation of the micro-analytical sensing characteristics of LIBS with the ring-oven pre-concentration technique is improved through mechanization of the ring measurement and use of lithium as internal standard.

Determination of Ca addition to the wheat flour by using laser-induced breakdown spectroscopy (LIBS)

2016 ◽  
Vol 242 (10) ◽  
pp. 1685-1692 ◽  
Author(s):  
Gonca Bilge ◽  
Banu Sezer ◽  
Kemal Efe Eseller ◽  
Halil Berberoğlu ◽  
Hamit Köksel ◽  
...  
Keyword(s):  
Wheat Flour ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Ca Addition ◽  
Laser Induced Breakdown

Quantitative determination of calcium, magnesium, and zinc in fingernails by laser-induced breakdown spectroscopy

Talanta ◽  
2013 ◽  
Vol 117 ◽  
pp. 55-59 ◽  
Author(s):  
David A. Rusak ◽  
Ann E. Zeleniak ◽  
Jillian L. Obuhosky ◽  
Scott M. Holdren ◽  
Craig A. Noldy
Keyword(s):  
Quantitative Determination ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Calcium Magnesium

Fast determination of calcium concentration in the internal tissues of a single seed using laser-induced breakdown spectroscopy

2016 ◽  
Vol 8 (37) ◽  
pp. 6705-6710 ◽  
Author(s):  
Pengcheng Han ◽  
Daming Dong ◽  
Xiaofan Du ◽  
Leizi Jiao ◽  
Xiande Zhao
Keyword(s):  
High Precision ◽  
Calcium Concentration ◽  
Seed Vigor ◽  
Laser Induced Breakdown Spectroscopy ◽  
Fast Determination ◽  
Breakdown Spectroscopy ◽  
Single Seed ◽  
Small Influence ◽  
Laser Induced Breakdown

Laser-induced breakdown spectroscopy was used for the fast determination of calcium concentration in the internal tissues of a single seed. Compared with conventional methods, LIBS had obvious advantages, such as a little analysis spot, little ablation, high precision, and small influence on the seed vigor.

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