A new practical isobaric interference correction model for the in situ Hf isotopic analysis using laser ablation-multi-collector-ICP-mass spectrometry of zircons with high Yb/Hf ratios

2019 ◽  
Vol 34 (6) ◽  
pp. 1223-1232 ◽  
Author(s):  
Hai-Ou Gu ◽  
He Sun ◽  
Fangyue Wang ◽  
Can Ge ◽  
Taofa Zhou
Keyword(s):  
Mass Spectrometry ◽  
Laser Ablation ◽  
Isotopic Analysis ◽  
Correction Model ◽  
Isobaric Interference ◽  
Interference Correction ◽  
Icp Ms ◽  
Icp Mass Spectrometry

An isobaric interference correction model was proposed for the in situ Hf isotopic analysis of zircons with high Yb/Hf ratios using LA-MC-ICP-MS.

Laser ablation-tandem ICP-mass spectrometry (LA-ICP-MS/MS) for direct Sr isotopic analysis of solid samples with high Rb/Sr ratios

2016 ◽  
Vol 31 (2) ◽  
pp. 464-472 ◽  
Author(s):  
Eduardo Bolea-Fernandez ◽  
Stijn J. M. Van Malderen ◽  
Lieve Balcaen ◽  
Martín Resano ◽  
Frank Vanhaecke
Keyword(s):  
Mass Spectrometry ◽  
Laser Ablation ◽  
Isotopic Analysis ◽  
Solid Samples ◽  
Icp Ms ◽  
Icp Mass Spectrometry

The combination of laser ablation and tandem ICP-mass spectrometry (LA-ICP-MS/MS) allows for successful Sr isotopic analysis of solid samples with high Rb/Sr ratios.

Evaluation of Laser Ablation in Liquid (LAL) technique as a new sampling technique for elemental and isotopic analysis using ICP-mass spectrometry

2011 ◽  
Vol 26 (7) ◽  
pp. 1393 ◽  
Author(s):  
Satoki Okabayashi ◽  
Takaomi D. Yokoyama ◽  
Yoshiaki Kon ◽  
Shinji Yamamoto ◽  
Tetsuya Yokoyama ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Laser Ablation ◽  
Sampling Technique ◽  
Isotopic Analysis ◽  
Laser Ablation In Liquid ◽  
Icp Mass Spectrometry

High-precision isotopic analysis of Cu in blood serum via multi-collector ICP-mass spectrometry for clinical investigation: steps towards improved robustness and higher sample throughput

2017 ◽  
Vol 32 (3) ◽  
pp. 597-608 ◽  
Author(s):  
Sara Lauwens ◽  
Marta Costas-Rodríguez ◽  
Hans Van Vlierberghe ◽  
Frank Vanhaecke
Keyword(s):  
Mass Spectrometry ◽  
Isotopic Composition ◽  
Blood Serum ◽  
Diurnal Variation ◽  
Clinical Investigation ◽  
Isotopic Analysis ◽  
Clinical Context ◽  
Sample Throughput ◽  
Icp Ms ◽  
Icp Mass Spectrometry

A procedure for Cu isolation from serum prior to MC-ICP-MS measurements was developed and applied in a clinical context. The serum Cu isotopic composition does not show diurnal variation.

scholarly journals Accurate analysis of Fe isotopes in Fe- dominated minerals by excimer laser ablation MC-ICP-MS on wet plasma conditions

2021 ◽  
Vol 42 (5) ◽  
Author(s):  
Honglin Yuan
Keyword(s):  
Water Vapor ◽  
Laser Ablation ◽  
Matrix Effect ◽  
Laser Fluence ◽  
Pulse Repetition Rate ◽  
Isotopic Analysis ◽  
Spot Size ◽  
Nitrogen Gas ◽  
Icp Ms

The Fe isotope ratios can be a useful tracer of geochemistry, biogeochemistry, and the environmental redox state. In this study, we investigated the feasibility of Fe isotopic analysis in Fe-dominated minerals by 193 nm excimer ns laser ablation combined with Nu Plasma 1700 high resolution MC-ICP-MS without matrix-match calibration. Several important instrument parameters were investigated, such as the effect of the addition of nitrogen gas and water vapor, the effects of analytical parameters such as ablation mode, laser fluence, pulse repetition rate, spot size on Fe isotopic mass bias during analysis were investigated as well. The results showed that the effects of ablation mode, spot size, laser pulse repetition rate, and line scan speed can be neglected, while laser fluence and matrix effects had significant influence on the Fe isotopic mass bias at dry plasma condition. These problems can be minimized using consistent lower fluence (1.5‒3.5 J·cm-2), as well as the wet plasma conditions can significantly reduce the matrix effect in Fe isotopic analysis. Fortunately, with the water vapor and nitrogen gas addition after the ablation cell, an accurate and precise Fe isotope in pyrite, manganite, hematite, and chalcopyrite analysis by ns-LA-MC-ICP-MS can be achieved with non-matrix-matched calibration. The obtained accuracy and reproducibility of the in situ determinations of δ56FeIRMM-014 were both better than ± 0.10‰ (2 SD). This study indicated that there was a serious matrix effect in the Fe isotopic analysis of Fe-dominated minerals by ns- LA-MC-ICP-MS, and nitrogen gas mixed with water vapor-assisted ns- LA-MC-ICP-MS were an appealing option for the in situ Fe isotope analysis of Fe-dominated minerals with non-matrix-matched calibration.

Determination of Zr isotopic ratios in zircons using laser-ablation multiple-collector inductively coupled-plasma mass-spectrometry

2019 ◽  
Vol 34 (9) ◽  
pp. 1800-1809 ◽  
Author(s):  
Wen Zhang ◽  
Zaicong Wang ◽  
Frédéric Moynier ◽  
Edward Inglis ◽  
Shengyu Tian ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Laser Ablation ◽  
Inductively Coupled Plasma ◽  
Isotopic Ratios ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Isotope Variation

An in situ Zr isotopic analytical method for zircons was developed using LA-MC-ICP-MS to reveal the Zr stable isotope variation in the complex mineral crystallization history.

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