scholarly journals Efficient transformation of CO2 to cyclic carbonates using bifunctional protic ionic liquids under mild conditions

2019 ◽  
Vol 21 (12) ◽  
pp. 3456-3463 ◽  
Author(s):  
Xianglei Meng ◽  
Zhaoyang Ju ◽  
Suojiang Zhang ◽  
Xiaodong Liang ◽  
Nicolas von Solms ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
High Activity ◽  
Cyclic Carbonates ◽  
Protic Ionic Liquids ◽  
Mild Conditions ◽  
Efficient Transformation ◽  
Mild Temperature

Bifunctional protic ionic liquids were prepared and they showed high activity for conversion of CO2 with epoxides at mild temperature (30–50 °C) and 1 bar CO2.

scholarly journals Correction: Efficient transformation of CO2 to cyclic carbonates using bifunctional protic ionic liquids under mild conditions

2021 ◽  
Author(s):  
Xianglei Meng ◽  
Zhaoyang Ju ◽  
Suojiang Zhang ◽  
Xiaodong Liang ◽  
Nicolas von Solms ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Cyclic Carbonates ◽  
Protic Ionic Liquids ◽  
Mild Conditions ◽  
Efficient Transformation

Correction for ‘Efficient transformation of CO2 to cyclic carbonates using bifunctional protic ionic liquids under mild conditions’ by Xianglei Meng et al., Green Chem., 2019, 21, 3456–3463, DOI: 10.1039/C9GC01165J.

scholarly journals Efficient and Reusable Iron Catalyst to Convert CO2 into Valuable Cyclic Carbonates

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1089
Author(s):  
Ana P. C. Ribeiro ◽  
Peter Goodrich ◽  
Luísa M. D. R. S. Martins
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Catalytic Effect ◽  
Iron Catalyst ◽  
Cyclic Carbonate ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
First Time

The production of cyclic carbonates from CO2 cycloaddition to epoxides, using the C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz = 1H-pyrazol-1-yl) as a catalyst, is achieved in excellent yields (up to 98%) in a tailor-made ionic liquid (IL) medium under mild conditions (80 °C; 1–8 bar). A favorable synergistic catalytic effect was found in the [FeCl2{κ3-HC(pz)3}]/IL system. Notably, in addition to exhibiting remarkable activity, the catalyst is stable during ten consecutive cycles, the first decrease (11%) on the cyclic carbonate yield being observed during the 11th cycle. The use of C-scorpionate complexes in ionic liquids to afford cyclic carbonates is presented herein for the first time.

Design of Novel Poly(ionic liquids) for the Conversion of CO2 to Cyclic Carbonates under Mild Conditions without Solvent

2019 ◽  
Vol 7 (10) ◽  
pp. 9489-9497 ◽  
Author(s):  
Hongbing Song ◽  
Yongjie Wang ◽  
Meng Xiao ◽  
Lei Liu ◽  
Yule Liu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Cyclic Carbonates ◽  
Mild Conditions

Fluoro-functionalized polymeric ionic liquids: highly efficient catalysts for CO2cycloaddition to cyclic carbonates under mild conditions

2014 ◽  
Vol 16 (8) ◽  
pp. 3724 ◽  
Author(s):  
Zhen-Zhen Yang ◽  
Yanfei Zhao ◽  
Guipeng Ji ◽  
Hongye Zhang ◽  
Bo Yu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Cyclic Carbonates ◽  
Polymeric Ionic Liquids ◽  
Mild Conditions ◽  
Highly Efficient

Integrated, one-pot carbon capture and utilisation using porous ionic liquids

2021 ◽  
Author(s):  
Yujiao zhou ◽  
Jocasta Avila ◽  
Nicolas Berthet ◽  
Solene Legrand ◽  
Catherine Santini ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
High Activity ◽  
Carbon Capture ◽  
Cyclic Carbonates ◽  
One Pot

Porous ionic liquids combining alkylphosphonium halides with ZIF–8 absorb large amounts of carbon dioxide that can be catalytically coupled with epoxides to form cyclic carbonates. High activity and selectivity under...

DFT Study on the Chemical Absorption Mechanism of CO2 in Diamino Protic Ionic Liquids

2021 ◽  
Vol 125 (5) ◽  
pp. 1416-1428
Author(s):  
Jing Ma ◽  
Yutong Wang ◽  
Xueqing Yang ◽  
Mingxuan Zhu ◽  
Baohe Wang
Keyword(s):  
Ionic Liquids ◽  
Dft Study ◽  
Protic Ionic Liquids ◽  
Absorption Mechanism ◽  
Chemical Absorption

scholarly journals The Synthesis of Poly(Vinyl Alcohol) Grafted with Fluorinated Protic Ionic Liquids Containing Sulfo Functional Groups

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4158
Author(s):  
Patrycja Glińska ◽  
Andrzej Wolan ◽  
Wojciech Kujawski ◽  
Edyta Rynkowska ◽  
Joanna Kujawa
Keyword(s):  
Ionic Liquids ◽  
Vinyl Alcohol ◽  
Proton Exchange ◽  
Polymer Materials ◽  
Polymerization Reaction ◽  
Poly Vinyl Alcohol ◽  
Hydroxyl Groups ◽  
Protic Ionic Liquids ◽  
Synthesis Route ◽  
Sulfo Groups

There has been an ongoing need to develop polymer materials with increased performance as proton exchange membranes (PEMs) for middle- and high-temperature fuel cells. Poly(vinyl alcohol) (PVA) is a highly hydrophilic and chemically stable polymer bearing hydroxyl groups, which can be further altered. Protic ionic liquids (proticILs) have been found to be an effective modifying polymer agent used as a proton carrier providing PEMs’ desirable proton conductivity at high temperatures and under anhydrous conditions. In this study, the novel synthesis route of PVA grafted with fluorinated protic ionic liquids bearing sulfo groups (–SO3H) was elaborated. The polymer functionalization with fluorinated proticILs was achieved by the following approaches: (i) the PVA acylation and subsequent reaction with fluorinated sultones and (ii) free-radical polymerization reaction of vinyl acetate derivatives modified with 1-methylimidazole and sultones. These modifications resulted in the PVA being chemically modified with ionic liquids of protic character. The successfully grafted PVA has been characterized using 1H, 19F, and 13C-NMR and FTIR-ATR. The presented synthesis route is a novel approach to PVA functionalization with imidazole-based fluorinated ionic liquids with sulfo groups.

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