Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

2019 ◽  
Vol 220 ◽  
pp. 133-143 ◽  
Author(s):  
Weiying He ◽  
Pierre Kennepohl
Keyword(s):  
Absorption Spectroscopy ◽  
Experimental Evaluation ◽  
X Ray ◽  
X Ray Absorption

The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.

X-RAY ABSORPTION SPECTROSCOPY STUDY OF Cu-BASED METHANOL CATALYSTS. 2. REDUCED STATE

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-237-C8-242 ◽  
Author(s):  
B. S. CLAUSEN ◽  
B. LENGELER ◽  
B. S. RASMUSSEN ◽  
W. NIEMANN ◽  
H. TOPSØE
Keyword(s):  
Absorption Spectroscopy ◽  
Spectroscopy Study ◽  
X Ray ◽  
X Ray Absorption ◽  
Reduced State

GAS PHASE X-RAY ABSORPTION SPECTROSCOPY WITH AN ELECTRON YIELD DETECTOR

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-149-C8-151
Author(s):  
F. W. LYTLE ◽  
R. B. GREEGOR ◽  
G. H. VIA ◽  
J. M. BROWN ◽  
G. MEITZNER
Keyword(s):  
Gas Phase ◽  
Absorption Spectroscopy ◽  
X Ray ◽  
Electron Yield ◽  
X Ray Absorption

THE FORMATION, STRUCTURE AND DISSOLUTION OF THE FERRITIN IRON CORE STUDIED BY X-RAY ABSORPTION SPECTROSCOPY

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-1155-C8-1157
Author(s):  
E. C. THEIL ◽  
D. E. SAYERS ◽  
C. Y. YANG ◽  
A. FONTAINE ◽  
E. DARTYGE
Keyword(s):  
Absorption Spectroscopy ◽  
Iron Core ◽  
X Ray ◽  
Ferritin Iron ◽  
X Ray Absorption

STOPPED-FLOW X-RAY ABSORPTION SPECTROSCOPY IN DISPERSIVE MODE

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-555-C8-561 ◽  
Author(s):  
S. SAIGO ◽  
H. OYANAGI ◽  
T. MATSUSHITA ◽  
H. HASHIMOTO ◽  
N. YOSHIDA ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Stopped Flow ◽  
X Ray ◽  
X Ray Absorption

Application of In Situ X-ray Absorption Spectroscopy to Study Dilute Chromium Ions in a Molten Chloride Salt

2019 ◽  
Author(s):  
Jisue Moon ◽  
Carter Abney ◽  
Dmitriy Dolzhnikov ◽  
James M. Kurley ◽  
Kevin A. Beyer ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Local Structure ◽  
Chloride Salt ◽  
X Ray ◽  
Molten Chloride ◽  
Stable Species ◽  
Higher Temperature ◽  
Cr Concentration ◽  
X Ray Absorption

The local structure of dilute CrCl<sub>3</sub> in a molten MgCl<sub>2</sub>:KCl salt was investigated by <i>in situ</i> x-ray absorption spectroscopy (XAS) at temperatures from room temperature to 800<sup>o</sup>C. This constitutes the first experiment where dilute Cr speciation is explored in a molten chloride salt, ostensibly due to the compounding challenges arising from a low Cr concentration in a matrix of heavy absorbers at extreme temperatures. CrCl<sub>3</sub> was confirmed to be the stable species between 200 and 500<sup>o</sup>C, while mobility of metal ions at higher temperature (>700<sup>o</sup>C) prevented confirmation of the local structure.

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