scholarly journals Emerging investigator series: influence of marine emissions and atmospheric processing on individual particle composition of summertime Arctic aerosol over the Bering Strait and Chukchi Sea

2020 ◽  
Vol 22 (5) ◽  
pp. 1201-1213 ◽  
Author(s):  
Rachel M. Kirpes ◽  
Blanca Rodriguez ◽  
Saewung Kim ◽  
Swarup China ◽  
Alexander Laskin ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Chukchi Sea ◽  
Atmospheric Particles ◽  
Individual Particle ◽  
Anthropogenic Sources ◽  
Bering Strait ◽  
Particle Composition ◽  
Atmospheric Processing ◽  
Arctic Aerosol ◽  
Alaskan Arctic

Composition of individual atmospheric particles reveals the influence of marine sources, terrestrial sources, and anthropogenic sources on atmospheric chemistry in the changing Alaskan Arctic.

scholarly journals Clean air in the Anthropocene

2017 ◽  
Vol 200 ◽  
pp. 693-703 ◽  
Author(s):  
Jos Lelieveld
Keyword(s):  
Air Pollution ◽  
Sustainable Development ◽  
Air Quality ◽  
Human Health ◽  
Atmospheric Chemistry ◽  
Clean Energy ◽  
Atmospheric Composition ◽  
Anthropogenic Sources ◽  
Years Of Life Lost ◽  
Clean Air

In atmospheric chemistry, interactions between air pollution, the biosphere and human health, often through reaction mixtures from both natural and anthropogenic sources, are of growing interest. Massive pollution emissions in the Anthropocene have transformed atmospheric composition to the extent that biogeochemical cycles, air quality and climate have changed globally and partly profoundly. It is estimated that mortality attributable to outdoor air pollution amounts to 4.33 million individuals per year, associated with 123 million years of life lost. Worldwide, air pollution is the major environmental risk factor to human health, and strict air quality standards have the potential to strongly reduce morbidity and mortality. Preserving clean air should be considered a human right, and is fundamental to many sustainable development goals of the United Nations, such as good health, climate action, sustainable cities, clean energy, and protecting life on land and in the water. It would be appropriate to adopt “clean air” as a sustainable development goal.

scholarly journals Investigation of water adsorption and hygroscopicity of atmospherically relevant particles using a commercial vapor sorption analyzer

2017 ◽  
Vol 10 (10) ◽  
pp. 3821-3832 ◽  
Author(s):  
Wenjun Gu ◽  
Yongjie Li ◽  
Jianxi Zhu ◽  
Xiaohong Jia ◽  
Qinhao Lin ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Radiative Forcing ◽  
Water Adsorption ◽  
Theoretical Data ◽  
Atmospheric Particles ◽  
Relative Mass ◽  
Nonspherical Particles ◽  
Vapor Sorption ◽  
Hygroscopic Growth ◽  
Dry Conditions

Abstract. Water adsorption and hygroscopicity are among the most important physicochemical properties of aerosol particles, largely determining their impacts on atmospheric chemistry, radiative forcing, and climate. Measurements of water adsorption and hygroscopicity of nonspherical particles under subsaturated conditions are nontrivial because many widely used techniques require the assumption of particle sphericity. In this work we describe a method to directly quantify water adsorption and mass hygroscopic growth of atmospheric particles for temperature in the range of 5–30 °C, using a commercial vapor sorption analyzer. A detailed description of instrumental configuration and experimental procedures, including relative humidity (RH) calibration, is provided first. It is then demonstrated that for (NH4)2SO4 and NaCl, deliquescence relative humidities and mass hygroscopic growth factors measured using this method show good agreements with experimental and/or theoretical data from literature. To illustrate its ability to measure water uptake by particles with low hygroscopicity, we used this instrument to investigate water adsorption by CaSO4 ⋅ 2H2O as a function of RH at 25 °C. The mass hygroscopic growth factor of CaSO4 ⋅ 2H2O at 95 % RH, relative to that under dry conditions (RH  < 1 %), was determined to be (0.450±0.004) % (1σ). In addition, it is shown that this instrument can reliably measure a relative mass change of 0.025 %. Overall, we have demonstrated that this commercial instrument provides a simple, sensitive, and robust method to investigate water adsorption and hygroscopicity of atmospheric particles.

scholarly journals Calcium carbonate saturation in the surface water of the Arctic Ocean: undersaturation in freshwater influenced shelves

2009 ◽  
Vol 6 (11) ◽  
pp. 2421-2431 ◽  
Author(s):  
M. Chierici ◽  
A. Fransson
Keyword(s):  
Calcium Carbonate ◽  
Surface Water ◽  
Cold Water ◽  
Dissolved Inorganic Carbon ◽  
Chukchi Sea ◽  
Total Alkalinity ◽  
The Arctic ◽  
Subsurface Water ◽  
Chukchi Peninsula ◽  
Bering Strait

Abstract. In the summer of 2005, we sampled surface water and measured pH and total alkalinity (AT) underway aboard IB Oden along the Northwest Passage from Cape Farewell (South Greenland) to the Chukchi Sea. We investigated the variability of carbonate system parameters, focusing particularly on carbonate concentration [CO32−] and calcium carbonate saturation states, as related to freshwater addition, biological processes and physical upwelling. Measurements on AT, pH at 15°C, salinity (S) and sea surface temperature (SST), were used to calculate total dissolved inorganic carbon (CT), [CO32−] and the saturation of aragonite (ΩAr) and calcite (ΩCa) in the surface water. The same parameters were measured in the water column of the Bering Strait. Some surface waters in the Canadian Arctic Archipelago (CAA) and on the Mackenzie shelf (MS) were found to be undersaturated with respect to aragonite (ΩAr<1). In these areas, surface water was low in AT and CT (<1500 μmol kg−1) relative to seawater and showed low [CO32−]. The low saturation states were probably due to the likely the effect of dilution due to freshwater addition by sea ice melt (CAA) and river runoff (MS). High AT and CT and low pH, corresponded with the lowest [CO32−], ΩAr and ΩCa, observed near Cape Bathurst and along the South Chukchi Peninsula. This was linked to the physical upwelling of subsurface water with elevated CO2. The highest surface ΩAr and ΩCa of 3.0 and 4.5, respectively, were found on the Chukchi Sea shelf and in the cold water north of Wrangel Island, which is heavily influenced by high CO2 drawdown and lower CT from intense biological production. In the western Bering Strait, the cold and saline Anadyr Current carries water that is enriched in AT and CT from enhanced organic matter remineralization, resulting in the lowest ΩAr (~1.2) of the area.

First year of real-time VOC measurements at the SIRTA facility (Paris region, France): diurnal and seasonal variabilities, impact of lockdowns on air quality

2021 ◽  
Author(s):  
Leïla Simon ◽  
Valérie Gros ◽  
Jean-Eudes Petit ◽  
François Truong ◽  
Roland Sarda-Esteve ◽  
...  
Keyword(s):  
Air Quality ◽  
Atmospheric Chemistry ◽  
Seasonal Variability ◽  
Anthropogenic Sources ◽  
First Year ◽  
Good Representation ◽  
Atmospheric Measurements ◽  
Paris Region ◽  
The Impact

&lt;p&gt;Volatile Organic Compounds (VOCs) have direct influences on air quality and climate. They also play a key role in atmospheric chemistry, as they are precursors of secondary pollutants, such as ozone (O&lt;sub&gt;3&lt;/sub&gt;) and secondary organic aerosols (SOA).&lt;/p&gt;&lt;p&gt;Long-term datasets of in-situ atmospheric measurements are crucial to characterize the variability of atmospheric chemical composition. Online and continuous measurements of O&lt;sub&gt;3&lt;/sub&gt;, NO&lt;sub&gt;x&lt;/sub&gt; and aerosols have been achieved at the SIRTA-ACTRIS facility (Paris region, France), since 2012. Regarding VOCs, they have been measured there for several years thanks to bi-weekly samplings followed by offline Gas Chromatography analysis. However, this method doesn&amp;#8217;t provide a good representation of the temporal variability of VOC concentrations. To tackle this issue, online VOC measurements using a Proton-Transfer-Reaction Quadrupole Mass-Spectrometer (PTR-Q-MS) have been started in January 2020.&lt;/p&gt;&lt;p&gt;The dataset acquired during the first year of online VOC measurements is analyzed, which gives insights on VOC seasonal variability. The additional long-term datasets obtained from co-located measurements (O&lt;sub&gt;3&lt;/sub&gt;, NO&lt;sub&gt;x&lt;/sub&gt;, aerosol physical and chemical properties, meteorological parameters) are also used for the sake of this study.&lt;/p&gt;&lt;p&gt;Due to Covid-19 pandemic, the year 2020 notably comprised a total lockdown in France in Spring, and a lighter one in Autumn. Therefore, a focus can be made on the impact of these lockdowns on the VOC variability and sources. To this end, the diurnal cycles of VOCs considered markers for anthropogenic sources are carefully investigated. Results notably indicate that markers for traffic and wood burning sources behave quite differently during the Spring lockdown in comparison to the other periods. A source apportionment analysis using positive matrix factorization allows to further document the seasonal variability of VOC sources and the impacts on air quality associated with the lockdown measures.&lt;/p&gt;

Optical properties and molecular diversity of dissolved organic matter in the Bering Strait and Chukchi Sea

2017 ◽  
Vol 144 ◽  
pp. 104-111 ◽  
Author(s):  
Michael Gonsior ◽  
Jenna Luek ◽  
Philippe Schmitt-Kopplin ◽  
Jacqueline M. Grebmeier ◽  
Lee W. Cooper
Keyword(s):  
Organic Matter ◽  
Optical Properties ◽  
Dissolved Organic Matter ◽  
Molecular Diversity ◽  
Chukchi Sea ◽  
Bering Strait

Individual particle analyses of arctic aerosol samples collected during AGASP-III

1993 ◽  
Vol 27 (17-18) ◽  
pp. 2825-2837 ◽  
Author(s):  
Farn Parungo ◽  
Clarence Nagamoto ◽  
Gary Herbert ◽  
Joyce Harris ◽  
Russell Schnell ◽  
...  
Keyword(s):  
Individual Particle ◽  
Arctic Aerosol

scholarly journals A mechanism for biogenic production and emission of MEK from MVK decoupled from isoprene biosynthesis

2019 ◽  
Vol 19 (5) ◽  
pp. 3125-3135 ◽  
Author(s):  
Luca Cappellin ◽  
Francesco Loreto ◽  
Franco Biasioli ◽  
Paolo Pastore ◽  
Karena McKinney
Keyword(s):  
Oxidative Stress ◽  
Heat Stress ◽  
Atmospheric Chemistry ◽  
Plant Transformation ◽  
Anthropogenic Sources ◽  
Methyl Ethyl ◽  
Methyl Vinyl ◽  
Atmosphere Interaction ◽  
A Minor ◽  
Minor Extent

Abstract. Methyl ethyl ketone (MEK) is an important compound in atmospheric chemistry. While attention has been paid mostly to anthropogenic sources of MEK, recently it has been shown that biogenic sources are globally as important as anthropogenic ones. However, the origin of biogenic MEK has yet to be completely elucidated. We present the full mechanism by which within-plant transformation of methyl vinyl ketone (MVK) and, to a minor extent, of 2-butanol and 3-buten-2-ol, is a source of biogenic MEK. Such transformation is observed in red oak for both exogenous MVK, taken up from the atmosphere, and endogenous MVK generated within a plant when it experiences stress (e.g. heat stress). Endogenous MVK emitted by plants is typically explained by within-plant oxidation of isoprene caused by oxidative stress. In this study we show that MVK and MEK emissions caused by heat stress are not related to isoprene in isoprene-emitting plants, implying that the massive carbon investment that plants commit to isoprene production is not explained by a direct antioxidant role. The presented mechanism can be important for inclusion in plant emission and in plant–atmosphere interaction models.

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