20.7% highly reproducible inverted planar perovskite solar cells with enhanced fill factor and eliminated hysteresis

2019 ◽  
Vol 12 (5) ◽  
pp. 1622-1633 ◽  
Author(s):  
Xixia Liu ◽  
Yuanhang Cheng ◽  
Chao Liu ◽  
Tianxiang Zhang ◽  
Nengduo Zhang ◽  
...  

The approach of a hydrophilic group grafted buffer layer (HGGBL) was investigated for perovskite growth to realize highly efficient inverted planar perovskite solar cells with superior reproducibility, negligible hysteresis and improved stability.

Author(s):  
Zhiqin Ying ◽  
Xi Yang ◽  
Jingming Zheng ◽  
Yudong Zhu ◽  
Jingwei Xiu ◽  
...  

A charge-transfer induced BCP:Ag complex is employed as a multifunctional buffer layer for efficient inverted semi-transparent perovskite solar cells.


2018 ◽  
Vol 20 (11) ◽  
pp. 7395-7400 ◽  
Author(s):  
Xuewen Zhang ◽  
Chunjun Liang ◽  
Mengjie Sun ◽  
Huimin Zhang ◽  
Chao Ji ◽  
...  

The fill factor of inverted planar perovskite solar cells was increased when using zirconium acetate as the buffer layer due to its hole-and-ion blocking ability.


2016 ◽  
Vol 4 (20) ◽  
pp. 7903-7913 ◽  
Author(s):  
Chih-Yu Chang ◽  
Yu-Chia Chang ◽  
Wen-Kuan Huang ◽  
Wen-Chi Liao ◽  
Hung Wang ◽  
...  

A promising approach towards highly efficient and stable large-area ITO-free perovskite solar cells is demonstrated by employing thiol-functionalized self-assembled monolayers as interfacial modification layers.


2019 ◽  
Vol 7 (16) ◽  
pp. 9578-9586 ◽  
Author(s):  
Menglin Li ◽  
Xiuwen Xu ◽  
Yuemin Xie ◽  
Ho-Wa Li ◽  
Yuhui Ma ◽  
...  

We demonstrated highly efficient and stable perovskite solar cells based on a NiOx:rGO oxide composite as the hole transport layer.


2021 ◽  
Author(s):  
Shuaifeng Hu ◽  
Kento Otsuka ◽  
Richard Murdey ◽  
Tomoya Nakamura ◽  
Minh Anh Truong ◽  
...  

Abstract Carrier extraction is a key issue which limits the efficiency of perovskite solar cells. In this work, carrier extraction is improved by modifying the perovskite layers with a combination of ethylenediammonium diiodide post-treatment and glycine hydrochloride additive. Ethylenediammonium dications primarily affect the top surface of the perovskite films, while glycinium cations preferentially accumulate at the bottom region. The top and bottom interface modifications improve the crystallinity of the perovskite films and lower the density of electrical traps via surface passivation effects, resulting in long charge carrier lifetimes. The orientated aggregation of the ethylenediammonium and glycinium cations at the charge collection interfaces result in the formation of surface dipoles, which facilitate charge extraction. The performance of the treated solar cell devices also increases. The fill factor rose to 0.82, and the power conversion efficiency reaches 23.6% (23.1% certified). The open circuit voltage reaches 0.91 V, just 0.06 V below the Shockley–Queisser limit. The unencapsulated devices also show improved stability under AM 1.5G, retaining over 80% of the initial efficiency after 200 h continuous operation in inert atmosphere. Our strategy is also successfully applied to centimeter-scale devices, with efficiencies up to 21.0%.


2018 ◽  
Vol 3 (5) ◽  
pp. 717-722 ◽  
Author(s):  
Mohammad Mahdi Tavakoli ◽  
Rouhollah Tavakoli ◽  
Daniel Prochowicz ◽  
Pankaj Yadav ◽  
Michael Saliba

The improvement of the quality of the hole transporting layer (HTL) plays a key role in the fabrication of highly efficient and stable perovskite solar cells (PSCs).


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