3D amorphous NiFe LDH nanosheets electrodeposited on in situ grown NiCoP@NC on nickel foam for remarkably enhanced OER electrocatalytic performance

2020 ◽  
Vol 49 (15) ◽  
pp. 4896-4903 ◽  
Author(s):  
Jianhang Nie ◽  
Min Hong ◽  
Xiaohua Zhang ◽  
Junlin Huang ◽  
Qin Meng ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Nickel Foam ◽  
Electrocatalytic Performance ◽  
Hierarchical Porous

3D amorphous NiFe LDH nanosheets electrodeposited on hierarchical porous and conductive NiCoP@NC/NF in situ grown on nickel foam exhibited outstanding OER catalytic activity and stability.

Catalytic activity of rhodium(I) complexes containing (ω-trimethylsilylalkyl)diphenylphosphines

1980 ◽  
Vol 45 (8) ◽  
pp. 2219-2223 ◽  
Author(s):  
Marie Jakoubková ◽  
Martin Čapka
Keyword(s):  
Catalytic Activity ◽  
Nmr Spectroscopy ◽  
Ir Spectroscopy ◽  
Electron Density ◽  
Phosphorus Atom ◽  
Proton Acceptor ◽  
Trimethylsilyl Group ◽  
Kinetics Of

Kinetics of homogenous hydrogenation of 1-heptene catalysed by rhodium(I) complexes prepared in situ from μ,μ'-dichloro-bis(cyclooctenerhodium) and phosphines of the type RP(C6H5)2 (R = -CH3, -(CH2)nSi(CH3)3; n = 1-4) have been studied. The substitution of the ligands by the trimethylsilyl group was found to increase significantly the catalytic activity of the complexes. The results are discussed in relation to the electron density on the phosphorus atom determined by 31P NMR spectroscopy and to its proton acceptor ability determined by IR spectroscopy.

In situ formation of highly exposed NiPS3 nanosheets on nickel foam as an efficient 3D electrocatalyst for overall water splitting

2021 ◽  
Author(s):  
Liang Fang ◽  
Yanping Xie ◽  
Peiyin Guo ◽  
Jingpei Zhu ◽  
Shuhui Xiao ◽  
...  
Keyword(s):  
Water Splitting ◽  
Nickel Foam ◽  
Chemical Vapor ◽  
Bifunctional Catalyst ◽  
Vapor Transport ◽  
Chemical Vapor Transport ◽  
Overall Water Splitting ◽  
One Step ◽  
Transport Method

Vertical NiPS3 nanosheets in situ grown on conducting nickel foam were fabricated by a facile one-step chemical vapor transport method and used as an efficient bifunctional catalyst for overall water splitting.

On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

2014 ◽  
Vol 3 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Hannes Alex ◽  
Norbert Steinfeldt ◽  
Klaus Jähnisch ◽  
Matthias Bauer ◽  
Sandra Hübner
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
X Ray ◽  
X Ray Scattering ◽  
Oxidation Of Benzyl Alcohol ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

Porous N-doped graphitic carbon assembled one-dimensional hollow structures as high performance electrocatalysts for ORR

RSC Advances ◽  
2016 ◽  
Vol 6 (15) ◽  
pp. 12467-12471 ◽  
Author(s):  
Qiong Luo ◽  
Liyong Chen ◽  
Binhua Duan ◽  
Zhizhi Gu ◽  
Jing Liu ◽  
...  
Keyword(s):  
High Performance ◽  
Graphitic Carbon ◽  
Special Structure ◽  
Dimensional Structure ◽  
Template Method ◽  
One Dimensional ◽  
Sacrificial Template ◽  
Hollow Structures ◽  
Electrocatalytic Performance ◽  
Hierarchical Porous

Hierarchical porous and hollow N-doped graphitic carbon with one-dimensional structure was successfully achieved by a sacrificial template method, and exhibited an enhanced electrocatalytic performance towards ORR due to its special structure.

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