Aluminum complexes with new non-symmetric ferrocenyl amidine ligands and their application in CO2 transformation into cyclic carbonates

2020 ◽  
Vol 49 (4) ◽  
pp. 1124-1134 ◽  
Author(s):  
Yersica Rios Yepes ◽  
Javier Martínez ◽  
Hiram Rangel Sánchez ◽  
Celso Quintero ◽  
M. Carmen Ortega-Alfaro ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Aluminum Complexes ◽  
Co2 Transformation

A set of alkyl aluminum complexes supported by non-symmetric ferrocenyl amidine ligands were used as catalysts for the preparation of cyclic carbonates from epoxides and carbon dioxide using Bu4NI as a co-catalyst.

Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates

2020 ◽  
Vol 10 (10) ◽  
pp. 3265-3278 ◽  
Author(s):  
Marta Navarro ◽  
Luis F. Sánchez-Barba ◽  
Andrés Garcés ◽  
Juan Fernández-Baeza ◽  
Israel Fernández ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonate ◽  
Carbon Dioxide Fixation ◽  
Cyclic Carbonates ◽  
Carbonate Formation ◽  
Aluminum Complexes

The binuclear aluminum complexes [AlR2(κ2-NN′;κ2-NN′)AlR2] with TBAB/PPNCl behave as excellent systems for cyclic carbonate formation from CO2 with challenging epoxides.

Synthesis of Cyclic Carbonate From Carbon Dioxide and Epoxide Using Amino Acid Ionic Liquid Under 1atm Pressure

2012 ◽  
Vol 65 (4) ◽  
pp. 381 ◽  
Author(s):  
Qing Gong ◽  
Huadong Luo ◽  
Jin Cao ◽  
Yuhan Shang ◽  
Haibo Zhang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Amino Acid ◽  
Atmospheric Pressure ◽  
Cyclic Carbonate ◽  
Cyclic Carbonates ◽  
Metal Component ◽  
Co Catalyst ◽  
Effective Synthesis ◽  
Amino Acid Ionic Liquid

Herein, we report an effective synthesis of cyclic carbonates by cycloaddition of carbon dioxide to epoxide using a modified amino acid ionic liquid as catalyst under 1 atm pressure. With triethylamine as co-catalyst, the catalytic activity of the l-proline based ionic liquid was greatly enhanced, and up to 97 % isolated yield of cyclic carbonate was achieved at 90°C under atmospheric pressure without organic solvent and metal component.

Insights into the Solubility of Carbon Dioxide in Grafted Mesoporous Silica for the Catalytic Synthesis of Cyclic Carbonates by Nanoconfinement

2021 ◽  
Author(s):  
Shahab Boroun ◽  
Abolfazl Alizadeh Sahraei ◽  
Abdol Hadi Mokarizadeh ◽  
Houshang Alamdari ◽  
Frédéric-Georges Fontaine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mesoporous Silica ◽  
Catalytic Synthesis ◽  
Cyclic Carbonates

C3-symmetric zinc complexes as sustainable catalysts for transforming carbon dioxide into mono- and multi-cyclic carbonates

2021 ◽  
Vol 280 ◽  
pp. 119395
Author(s):  
Kanagaraj Naveen ◽  
Hoon Ji ◽  
Tea Soon Kim ◽  
Dongwoo Kim ◽  
Deug-Hee Cho
Keyword(s):  
Carbon Dioxide ◽  
Zinc Complexes ◽  
Cyclic Carbonates

scholarly journals Synthesis of the Multinuclear Cobaloxime Complexes via Click Chemistry as Catalysts for the Formation of Cyclic Carbonates from Carbon Dioxide and Epoxides

2015 ◽  
Vol 127 (9) ◽  
pp. 1665-1674 ◽  
Author(s):  
AHMET KILIC ◽  
ARMAGAN KELES ◽  
EMINE AYTAR ◽  
MUSTAFA DURGUN ◽  
MAHMUT ULUSOY
Keyword(s):  
Carbon Dioxide ◽  
Click Chemistry ◽  
Cyclic Carbonates

ChemInform Abstract: Metal-Promoted Synthesis of Cyclic Carbonates from 1,2-Diols and Carbon Dioxide

ChemInform ◽  
2015 ◽  
Vol 46 (20) ◽  
pp. no-no
Author(s):  
Chun-Xiang Guo ◽  
Ran Ma ◽  
Liang-Nian He
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates
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