scholarly journals A triple-triangle cluster derived from a simple tridentate ligand

2019 ◽  
Vol 48 (47) ◽  
pp. 17437-17440
Author(s):  
Takuya Shiga ◽  
Natsumi Okawa ◽  
Hiroki Oshio
Keyword(s):  
Ground State ◽  
Core Structure ◽  
Tridentate Ligand ◽  
Spin Ground State

An iron(iii) complex [Fe7] with a corner-shared triple-triangle core structure shaped like a three-leaf clover has S = 19/2 spin ground state.

DFT Computational Rationalization of an Unusual Spin Ground State in an Mn12 Single-Molecule Magnet with a Low-Symmetry Loop Structure

2005 ◽  
Vol 117 (6) ◽  
pp. 919-923 ◽  
Author(s):  
Dolos Foguet-Albiol ◽  
Ted A. O'Brien ◽  
Wolfgang Wernsdorfer ◽  
Brian Moulton ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ground State ◽  
Loop Structure ◽  
Single Molecule Magnet ◽  
Low Symmetry ◽  
Spin Ground State

Targeted construction of azido-bridged Ni4complexes with decisive effect of µ-1,3-azide torsion on the spin ground state

2006 ◽  
pp. 3458-3465 ◽  
Author(s):  
Serhiy Demeshko ◽  
Guido Leibeling ◽  
Sebastian Dechert ◽  
Franc Meyer
Keyword(s):  
Ground State ◽  
Decisive Effect ◽  
Spin Ground State

Strong Ferromagnetic Interactions in[V8O14(H−2taci)2]: An Unprecedented Large Spin Ground State for a Vanadyl Cluster

2004 ◽  
Vol 43 (26) ◽  
pp. 3436-3439 ◽  
Author(s):  
Kaspar Hegetschweiler ◽  
Bernd Morgenstern ◽  
Jon Zubieta ◽  
Pamela J. Hagrman ◽  
Nicola Lima ◽  
...  
Keyword(s):  
Ground State ◽  
Ferromagnetic Interactions ◽  
Large Spin ◽  
Spin Ground State

Fluorosulfates of palladium

1977 ◽  
Vol 55 (13) ◽  
pp. 2473-2477 ◽  
Author(s):  
K. C. Lee ◽  
F. Aubke
Keyword(s):  
Ground State ◽  
Diffuse Reflectance ◽  
Magnetic Measurements ◽  
Structural Information ◽  
Tridentate Ligand ◽  
Ligand Field ◽  
Polymeric Structure ◽  
Octahedral Environment ◽  
Fluorosulfate Group ◽  
Ligand Field Parameter

The syntheses of Pd(SO3F)2 and Pd(SO3F)3 by the reactions of palladium with BrOSO2F and S2O6F2 are described. Structural information on both compounds is based on infrared, Raman, diffuse reflectance, and electronic mull spectra as well as magnetic measurements from ∼300 to ∼100 K. Palladium bisfluorosulfate is found to have a polymeric structure with the fluorosulfate group acting as a tridentate ligand. As a consequence, an octahedral environment is found for Pd2+ with a 3A2g ground state, a µeff298 value of 3.39 BM and the ligand field parameter Dq = 1177 cm−1 and B = 633 cm−1. Pd(SO3F)3 is best regarded as PdII[PdIV(SO3F)6].

Possibility for an intermediate-spin ground state in the charge-transfer materialSrCoO3

1995 ◽  
Vol 51 (17) ◽  
pp. 11501-11506 ◽  
Author(s):  
R. H. Potze ◽  
G. A. Sawatzky ◽  
M. Abbate
Keyword(s):  
Charge Transfer ◽  
Ground State ◽  
Intermediate Spin ◽  
Spin Ground State

Giant Heterometallic Cu17Mn28Cluster withTdSymmetry and High-Spin Ground State

2007 ◽  
Vol 129 (5) ◽  
pp. 1014-1015 ◽  
Author(s):  
Wen-Guo Wang ◽  
Ai-Ju Zhou ◽  
Wei-Xiong Zhang ◽  
Ming-Liang Tong ◽  
Xiao-Ming Chen ◽  
...  
Keyword(s):  
High Spin ◽  
Ground State ◽  
Spin Ground State

scholarly journals Controlled Synthesis, Characterization and Magnetic Properties of Unsymmetrical Heterodinuclear CuIIMII (M = Co, Mn and Cd) Complexes in Alkoxo Bridged Acyclic Ligand Environment

2020 ◽  
Vol 32 (9) ◽  
pp. 2284-2292
Author(s):  
DIPESH GHOSH
Keyword(s):  
Ground State ◽  
Spectral Studies ◽  
Controlled Synthesis ◽  
Site Specificity ◽  
Magnetic Studies ◽  
X Ray ◽  
X Ray Crystallography ◽  
Synthetic Procedure ◽  
Binucleating Ligands ◽  
Spin Ground State

This work reports the syntheses of heterodinuclear Cu(II)-Co(II), Cu(II)-Mn(II) and Cu(II)-Cd(II) complexes following a convenient single-pot synthetic procedure using the two asymmetric binucleating ligands. Site-specificity offered by one of the ligands' arms towards Cu(I) center has been successfully exploited here, avoiding all sorts of impending scrambling reactions. X-ray crystallography and ESImass spectral studies have been used to prove the exclusivity of these products. Magnetic studies at variable temperatures (4-300 K) have been proved inadequate to assign any spin-ground state for Cu(II)-Co(II) and Cu(II)-Mn(II) compounds.

Phonon scattering by 3d impurities in III-V semiconductors: evidence of a low-spin ground state for V2+in GaAs?

1989 ◽  
Vol 1 (7) ◽  
pp. 1191-1203 ◽  
Author(s):  
N Butler ◽  
L J Challis ◽  
M Sahraoui-Tahar ◽  
B Salce ◽  
W Ulrici
Keyword(s):  
Ground State ◽  
Phonon Scattering ◽  
3D Impurities ◽  
Spin Ground State

A molecular ferromagnet with Tc = 3.3 K and an high spin ground state in trinuclear oxo-centred mixed-valence carboxylates

Polyhedron ◽  
1996 ◽  
Vol 15 (5-6) ◽  
pp. 1041-1044 ◽  
Author(s):  
Zhang Shi-Wei ◽  
Wei Yong-Ge ◽  
Liu Qun ◽  
Shao Mei-Cheng ◽  
Zhou Wen-Sheng
Keyword(s):  
High Spin ◽  
Ground State ◽  
Mixed Valence ◽  
Spin Ground State

Heterometallic Hexanuclear Cluster with anS= 8 Spin Ground State:  MnII{MnII(hfac)2}3{NiII(pao)3}2(hfac-= Hexafluoroacetylacetonate, pao-= Pyridine-2-aldoximate)

2003 ◽  
Vol 42 (15) ◽  
pp. 4501-4503 ◽  
Author(s):  
Hitoshi Miyasaka ◽  
Tomohiro Nezu ◽  
Fumiyasu Iwahori ◽  
Sachie Furukawa ◽  
Kunihisa Sugimoto ◽  
...  
Keyword(s):  
Ground State ◽  
Spin Ground State
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