Photochemical or electrochemical bond breaking – exploring the chemistry of (μ2-alkyne)Co2(CO)6 complexes using time-resolved infrared spectroscopy, spectro-electrochemical and density functional methods

2019 ◽  
Vol 48 (39) ◽  
pp. 14642-14652
Author(s):  
Jennifer C. Manton ◽  
Florian J. R. Cerpentier ◽  
Emma C. Harvey ◽  
Ian P. Clark ◽  
Gregory M. Greetham ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
High Spin ◽  
Density Functional ◽  
Bond Breaking ◽  
Time Resolved ◽  
Density Functional Methods ◽  
Functional Methods ◽  
Time Resolved Infrared Spectroscopy

The photoassisted Pauson–Khand reaction involves the formation of a high-spin diradical species and not CO loss as previously thought.

The triplet state of a platinum acetylide chromophore examined by time-resolved infrared spectroscopy and density functional theory

2004 ◽  
Vol 400 (1-3) ◽  
pp. 239-244 ◽  
Author(s):  
Thomas M. Cooper ◽  
Jean-Philippe Blaudeau ◽  
Benjamin C. Hall ◽  
Joy E. Rogers ◽  
Daniel G. McLean ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Infrared Spectroscopy ◽  
Triplet State ◽  
Density Functional ◽  
Functional Theory ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy

scholarly journals Picosecond time-resolved infrared spectroscopy of rhodium and iridium azides

2014 ◽  
Vol 43 (47) ◽  
pp. 17694-17702 ◽  
Author(s):  
Peter Portius ◽  
Anthony J. H. M. Meijer ◽  
Michael Towrie ◽  
Benjamin F. Crozier ◽  
Ingrid Schiager
Keyword(s):  
Density Functional Theory ◽  
Infrared Spectroscopy ◽  
Transition Metal ◽  
Density Functional ◽  
Laser Excitation ◽  
Functional Theory ◽  
Time Resolved ◽  
Photochemical Processes ◽  
Time Resolved Infrared Spectroscopy

Ultrafast photochemical processes induced in the transition metal azido complexes Rh(Cp*)(N3)2(PPh3) and Ir(Cp*)(N3)2(PPh3) upon laser excitation at 266 nm and 400 nm were elucidated by picosecond time-resolved infrared spectroscopy and density functional theory.

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