Fluorine and tin co-doping synergistically improves the photoelectrochemical water oxidation performance of TiO2 nanorod arrays by enhancing the ultraviolet light conversion efficiency

2019 ◽  
Vol 48 (32) ◽  
pp. 12096-12104 ◽  
Author(s):  
Tong Wu ◽  
Changlong Chen ◽  
Yuling Wei ◽  
Ranran Lu ◽  
Leshuang Wang ◽  
...  

Fluorine and tin co-doping changes the electronic structure of rutile TiO2 nanorod arrays, leading to much-enhanced UV light conversion efficiency and significantly improved photoelectrochemical water oxidation performance.

Nanoscale ◽  
2018 ◽  
Vol 10 (41) ◽  
pp. 19367-19374 ◽  
Author(s):  
Shiman He ◽  
Yuying Meng ◽  
Qili Wu ◽  
Jingling Yang ◽  
Senchuan Huang ◽  
...  

Ta-doped porous TiO2 nanorod arrays on a Ta substrate are synthesized and used as a photoanode for photoelectrochemical water oxidation. The Ta substrate provides Ta dopants and also plays a vital role in the formation of nanopores in the nanorods.


2019 ◽  
Vol 465 ◽  
pp. 192-200 ◽  
Author(s):  
Baoshun Liu ◽  
Jingjing Yang ◽  
Jiangyan Wang ◽  
Xiujian Zhao ◽  
Kazuya Nakata

Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 983 ◽  
Author(s):  
Shiman He ◽  
Yuying Meng ◽  
Yangfei Cao ◽  
Senchuan Huang ◽  
Jingling Yang ◽  
...  

TiO2 is one of the most attractive semiconductors for use as a photoanode for photoelectrochemical (PEC) water oxidation. However, the large-scale application of TiO2 photoanodes is restricted due to a short hole diffusion length and low electron mobility, which can be addressed by metal doping and surface decorating. In this paper we report the successful synthesis of hierarchical Ta doped TiO2 nanorod arrays, with nanoparticles on the top (Ta:TiO2), on F-doped tin oxide (FTO) glass by a hydrothermal method, and its application as photoanodes for photoelectrochemical water oxidation. It has been found that the incorporation of Ta5+ in the TiO2 lattice can decrease the diameter of surface TiO2 nanoparticles. Ta:TiO2-140, obtained with a moderate Ta concentration, yields a photocurrent of ∼1.36 mA cm−2 at 1.23 V vs. a reversible hydrogen electrode (RHE) under FTO side illumination. The large photocurrent is attributed to the large interface area of the surface TiO2 nanoparticles and the good electron conductivity due to Ta doping. Besides, the electron trap-free model illustrates that Ta:TiO2 affords higher transport speed and lower electron resistance when under FTO side illumination.


Author(s):  
Anna A. Wilson ◽  
Sacha Corby ◽  
Laia Francàs ◽  
James R. Durrant ◽  
Andreas Kafizas

PdO nanoparticles grown on the surface of nanostructured WO3 photoanodes dramatically increase the faradaic efficiency of water oxidation from 52% to 92%, whilst also enhancing photocurrent generation and electron extraction rates.


2017 ◽  
Vol 53 (30) ◽  
pp. 4278-4281 ◽  
Author(s):  
Pravin S. Shinde ◽  
Su Yong Lee ◽  
Jungho Ryu ◽  
Sun Hee Choi ◽  
Jum Suk Jang

We report CTAB-mediated synthesis of internally porous Au-embedded hematite photoanode with enhanced photoelectrochemical water oxidation performance.


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