Lewis acidic alkaline earth metal complexes with a perfluorinated diphenylamide ligand

2019 ◽  
Vol 48 (20) ◽  
pp. 6757-6766 ◽  
Author(s):  
Christian A. Fischer ◽  
Andreas Rösch ◽  
Holger Elsen ◽  
Gerd Ballmann ◽  
Michael Wiesinger ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Lewis Acid ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Chemistry

Alkaline earth metal chemistry with the anion [N(C6F5)2]− has been explored. Complexes are stabilized by metal⋯F interactions. Mg[N(C6F5)2]2 is a stronger Lewis acid than B(C6F5)3.

C–H and C–F coordination of arenes in neutral alkaline earth metal complexes

2021 ◽  
Author(s):  
Jacob S. McMullen ◽  
Alison J. Edwards ◽  
Jamie Hicks
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Calcium Complexes ◽  
Group 2 ◽  
Rare Group

A series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feaure rare group 2 metal···aromatic...

Alkali and alkaline-earth metal complexes of different nuclearities with azamacrocyclic pendant-arms ligands

2009 ◽  
Vol 362 (9) ◽  
pp. 3351-3356 ◽  
Author(s):  
Luis Botana ◽  
Rufina Bastida ◽  
Alejandro Macías ◽  
Paulo Pérez-Lourido ◽  
Laura Valencia
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Pendant Arms

Highly Lewis acidic cationic alkaline earth metal complexes

2018 ◽  
Vol 54 (63) ◽  
pp. 8685-8688 ◽  
Author(s):  
Jürgen Pahl ◽  
Steffen Brand ◽  
Holger Elsen ◽  
Sjoerd Harder
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal

“Naked” cationic β-diketiminate Mg and Ca complexes possess high Lewis acidities and bind strongly to neutral benzene or alkyne ligands.

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