New multifunctional 3D porous metal–organic framework with selective gas adsorption, efficient chemical fixation of CO2 and dye adsorption

2019 ◽  
Vol 48 (22) ◽  
pp. 7612-7618 ◽  
Author(s):  
Shan Cheng ◽  
Yunlong Wu ◽  
Jing Jin ◽  
Jiao Liu ◽  
Dan Wu ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Dye Adsorption ◽  
Porous Metal ◽  
Adsorption Behavior ◽  
Chemical Fixation ◽  
Efficient Catalyst ◽  
Metal Organic ◽  
Rapid Adsorption

A new porous Mn(ii)-based MOF was obtained. The studies indicated it exhibits an effective storage capacity for CO2, highly efficient catalyst behavior for epoxides with different substituents and rapid adsorption behavior of different dyes.

A Double-Walled Porous Metal–Organic Framework as a Highly Efficient Catalyst for Chemical Fixation of CO2 with Epoxides

2019 ◽  
Vol 58 (22) ◽  
pp. 15637-15643 ◽  
Author(s):  
Qian-Qian Zhu ◽  
Wen-Wen Zhang ◽  
Han-Wen Zhang ◽  
Ye Yuan ◽  
Rongrong Yuan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Chemical Fixation ◽  
Efficient Catalyst ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

Adsorption behavior of methyl orange onto an aluminum-based metal organic framework, MIL-68(Al)

2017 ◽  
Vol 75 (12) ◽  
pp. 2800-2810 ◽  
Author(s):  
Shi-chuan Wu ◽  
Xia You ◽  
Cao Yang ◽  
Jian-hua Cheng
Keyword(s):  
Methyl Orange ◽  
Adsorption Isotherm ◽  
Electrostatic Interactions ◽  
Metal Organic Framework ◽  
Dye Adsorption ◽  
Adsorption Behavior ◽  
Metal Organic ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Organic Framework

MIL-68(Al), a powdered aluminum-based metal organic framework (MOF), was synthesized and used to explore its adsorption behavior toward methyl orange (MO). The adsorption isotherm, thermodynamics, kinetics, and some key operating factors as well as changes in the material's structure were investigated. The adsorption isotherm conformed to the Langmuir isotherm model and the maximum equilibrium adsorption capacity was 341.30 mg g−1. Thermodynamic data demonstrated that the adsorption process was spontaneous, endothermic and showed positive entropy. For kinetics, the process of MO adsorption onto MIL-68(Al) was more suitably described by a pseudo-second-order model. Electrostatic and hydrogen-bonding interactions contributed to dye adsorption, with electrostatic interactions considered to be the principal binding force between adsorbent and adsorbate. Furthermore, MIL-68(Al) maintained a stable structure after adsorption. From these results, MIL-68(Al) was suggested here to be a stable MOF adsorbent for removing MO from aqueous solution.

A nitro-decorated NbO-type metal–organic framework with a highly selective CO2 uptake and CH4 storage capacity

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
Adsorption Selectivity ◽  
Total Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework ◽  
Ch4 Storage

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.

A lead–porphyrin metal–organic framework: gas adsorption properties and electrocatalytic activity for water oxidation

2016 ◽  
Vol 45 (1) ◽  
pp. 61-65 ◽  
Author(s):  
Fangna Dai ◽  
Weidong Fan ◽  
Jiahui Bi ◽  
Peng Jiang ◽  
Dandan Liu ◽  
...  
Keyword(s):  
Alkaline Solution ◽  
Water Oxidation ◽  
Electrocatalytic Activity ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Organic Framework

A 3D non-interpenetrating porous metal–organic framework shows electrocatalytic activity for water oxidation in alkaline solution.

A Hierarchically Porous Metal-Organic Framework from Semirigid Ligand for Gas Adsorption

2015 ◽  
Vol 34 (2) ◽  
pp. 215-219 ◽  
Author(s):  
Lizhen Liu ◽  
Yingxiang Ye ◽  
Zizhu Yao ◽  
Liuqin Zhang ◽  
Ziyin Li ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Hierarchically Porous ◽  
Metal Organic ◽  
Organic Framework

Selective gas adsorption within a five-connected porous metal–organic framework

2010 ◽  
Vol 20 (19) ◽  
pp. 3984 ◽  
Author(s):  
Ming Xue ◽  
Zhangjing Zhang ◽  
Shengchang Xiang ◽  
Zhao Jin ◽  
Chengdu Liang ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Fabrication of hierarchically porous MIL-88-NH2(Fe): a highly efficient catalyst for the chemical fixation of CO2 under ambient pressure

2019 ◽  
Vol 6 (12) ◽  
pp. 3613-3620 ◽  
Author(s):  
Jintu Francis Kurisingal ◽  
Yadagiri Rachuri ◽  
Yunjang Gu ◽  
Youngson Choe ◽  
Dae-Won Park
Keyword(s):  
Ambient Pressure ◽  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Efficient Catalyst ◽  
Hierarchically Porous ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

A hierarchically micro- and mesoporous MIL-88-NH2 metal organic framework was prepared through an easy template directed methodology.

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