Photoluminescent Cu(i) vs. Ag(i) complexes: slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

2019 ◽  
Vol 48 (26) ◽  
pp. 9765-9775 ◽  
Author(s):  
José M. Carbonell-Vilar ◽  
Elisa Fresta ◽  
Donatella Armentano ◽  
Rubén D. Costa ◽  
Marta Viciano-Chumillas ◽  
...  

Replacement of copper(i) ions by silver(i) improves the solid-state photoluminescence properties.

RSC Advances ◽  
2017 ◽  
Vol 7 (7) ◽  
pp. 4161-4166 ◽  
Author(s):  
Bebeh W. Nuryadin ◽  
Fitri A. Permatasari ◽  
Ade Y. Nuryantini ◽  
Irfana D. Faryuni ◽  
Mikrajuddin Abdullah ◽  
...  

A bright red emission of manganese-doped BCNO (BCNO:Mn) phosphor was firstly synthesized by solid state method.


2015 ◽  
Vol 622 ◽  
pp. 120-123 ◽  
Author(s):  
Amador García-Fuente ◽  
Fanica Cimpoesu ◽  
Harry Ramanantoanina ◽  
Benjamin Herden ◽  
Claude Daul ◽  
...  

2021 ◽  
Vol 139 ◽  
pp. 111259 ◽  
Author(s):  
T Krishnapriya ◽  
Adon Jose ◽  
Twinkle Anna Jose ◽  
A.C. Saritha ◽  
Cyriac Joseph ◽  
...  

2016 ◽  
Vol 12 ◽  
pp. 825-834 ◽  
Author(s):  
Andreea Petronela Diac ◽  
Ana-Maria Ţepeş ◽  
Albert Soran ◽  
Ion Grosu ◽  
Anamaria Terec ◽  
...  

New indeno[1,2-c]pyran-3-ones bearing different substituents at the pyran moiety were synthesized and their photophysical properties were investigated. In solution all compounds were found to be blue emitters and the trans isomers exhibited significantly higher fluorescence quantum yields (relative to 9,10-diphenylanthracene) as compared to the corresponding cis isomers. The solid-state fluorescence spectra revealed an important red shift of λmax due to intermolecular interactions in the lattice, along with an emission-band broadening, as compared to the solution fluorescence spectra.


RSC Advances ◽  
2017 ◽  
Vol 7 (65) ◽  
pp. 41282-41288 ◽  
Author(s):  
Hongwei Xu ◽  
Lili Wang ◽  
Dan Qu ◽  
Zhiyun Si ◽  
Jinsheng Shi

A series of Sr6Ca4(PO4)6F2:Eu2+,Mn2+ phosphors were synthesized by traditional solid state reaction. Through controlling the ratio of Eu2+ and Mn2+, emission colors can be tuned from blue to yellow, including white-light-emitting.


Author(s):  
Rajani A. Bhoyar ◽  
A. C. Nayak

Lanthanide ions are very efficient activators. Due to the presence of shielded 4f shell, the energy levels can be predicted with relative ease. Interaction with the surrounding lattice is minimum and luminescence efficiency is high. For this reason, many important phosphors having various applications have been discovered which use lanthanide activators. For obtaining efficient phosphors, it is important to find a suitable host for lanthanide activators which can accommodate these ions without concentration quenching. The hosts must be transparent to the emitted light. Lanthanides, most commonly occur as trivalent. Thus, hosts constituted by trivalent metals can be suitable. Yttrium compounds have been extensively studied as hosts. Scandium is another trivalent metal. Compared to the yttrium compounds, Scandium compounds have been very scarcely studied as hosts. We are investigating Scandium compounds as luminescence hosts. Synthesis and photoluminescence properties of Sr9 Sc (PO4)7 : Eu3+ and Sr8MgSc(PO4)7:Eu3+ phosphor are described in this work. The phosphors were prepared by solid state reaction. Usually, these phosphors are reduced and results on Eu2+ photoluminescence are reported. However, we have recorded photoluminescence before reduction and thus new results on Eu3+ emission could be obtained.


2015 ◽  
Vol 71 ◽  
pp. 21-24 ◽  
Author(s):  
Qiang Long ◽  
Chuang Wang ◽  
Yanyan Li ◽  
Jianyan Ding ◽  
Xicheng Wang ◽  
...  

2013 ◽  
Vol 684 ◽  
pp. 274-278
Author(s):  
Huang Yu Chen ◽  
Ru Yuan Yang ◽  
Shoou Jinn Chang

A Eu3+ activated YInGe2O7phosphor was synthesized by solid-state reaction and lithium carbonate was added to change the morphology and photoluminescence properties. Scanning electron microscopy showed large particle size and necking shape were obtained as the concentrations of Li+ ions increase. In the PL studies, the excitation spectrum of YInGe2O7:Eu3+ phosphors exhibited a broad band in the UV region centered at about 272 nm attributed to charge transfer state (CTS) band, which has a little shift after Li+ ion was added. As the Li+ ion concentration increased, the photoluminescence intensity of the red emission at 620 nm of Eu3+ ions was enhanced, and the optimized concentration of of added Li+ ion is 0.05. The results showed that addition of Li+ ion allows YInGe2O7:Eu3+ phosphors emitting relatively pure red light.


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