Efficient oxygen evolution on mesoporous IrOx nanosheets

2019 ◽  
Vol 9 (14) ◽  
pp. 3697-3702 ◽  
Author(s):  
Bo Jiang ◽  
Jeonghun Kim ◽  
Yanna Guo ◽  
Kevin C. W. Wu ◽  
Saad M. Alshehri ◽  
...  

Amorphous iridium oxide (IrOx) is a promising catalyst that has high activity in the oxygen evolution reaction (OER) over a broad range of pH values.

ACS Catalysis ◽  
2021 ◽  
pp. 10043-10057
Author(s):  
Steffen Czioska ◽  
Alexey Boubnov ◽  
Daniel Escalera-López ◽  
Janis Geppert ◽  
Alexandra Zagalskaya ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 657
Author(s):  
Geul Han Kim ◽  
Yoo Sei Park ◽  
Juchan Yang ◽  
Myeong Je Jang ◽  
Jaehoon Jeong ◽  
...  

Developing high performance, highly stable, and low-cost electrodes for the oxygen evolution reaction (OER) is challenging in water electrolysis technology. However, Ir- and Ru-based OER catalysts with high OER efficiency are difficult to commercialize as precious metal-based catalysts. Therefore, the study of OER catalysts, which are replaced by non-precious metals and have high activity and stability, are necessary. In this study, a copper–cobalt oxide nanosheet (CCO) electrode was synthesized by the electrodeposition of copper–cobalt hydroxide (CCOH) on Ni foam followed by annealing. The CCOH was annealed at various temperatures, and the structure changed to that of CCO at temperatures above 250 °C. In addition, it was observed that the nanosheets agglomerated when annealed at 300 °C. The CCO electrode annealed at 250 °C had a high surface area and efficient electron conduction pathways as a result of the direct growth on the Ni foam. Thus, the prepared CCO electrode exhibited enhanced OER activity (1.6 V at 261 mA/cm2) compared to those of CCOH (1.6 V at 144 mA/cm2), Co3O4 (1.6 V at 39 mA/cm2), and commercial IrO2 (1.6 V at 14 mA/cm2) electrodes. The optimized catalyst also showed high activity and stability under high pH conditions, demonstrating its potential as a low cost, highly efficient OER electrode material.


Author(s):  
Takahiro Naito ◽  
Tatsuya Shinagawa ◽  
Takeshi Nishimoto ◽  
Kazuhiro Takanabe

Recent spectroscopic and computational studies concerning the oxygen evolution reaction over iridium oxides are reviewed to provide the state-of-the-art understanding of its reaction mechanism.


2021 ◽  
Vol 143 (38) ◽  
pp. 15616-15623
Author(s):  
Fang Zhao ◽  
Bo Wen ◽  
Wenhan Niu ◽  
Zhu Chen ◽  
Chao Yan ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Jianzhi Wang ◽  
Chen Chen ◽  
Ning Cai ◽  
Miao Wang ◽  
Hui Li ◽  
...  

The development of non-precious metal electrocatalysts with high activity, good durability and low cost to replace precious metal electrocatalysts is highly demanded for oxygen evolution reaction (OER).


Nanoscale ◽  
2019 ◽  
Vol 11 (22) ◽  
pp. 10595-10602 ◽  
Author(s):  
Yu-Feng Qi ◽  
Qian Wang ◽  
Xiu-Guang Wang ◽  
Zheng-Yu Liu ◽  
Xiao-Jun Zhao ◽  
...  

A Co-doped FeNi carbonate hydroxide nanosheet array supported on nickel foam served as an efficient oxygen evolution electrocatalyst with a high activity and excellent stability.


2017 ◽  
Vol 1 (4) ◽  
pp. 780-788 ◽  
Author(s):  
Suoyuan Lian ◽  
Michelle P. Browne ◽  
Carlota Domínguez ◽  
Serban N. Stamatin ◽  
Hugo Nolan ◽  
...  

Solvothermally synthesised MnCO3 leads to template-free formation of highly porous, defect-rich MnO2 with high activity in water oxidation.


2018 ◽  
Vol 54 (39) ◽  
pp. 4987-4990 ◽  
Author(s):  
Jinxiu Zhao ◽  
Xiang Ren ◽  
Qingzhi Han ◽  
Dawei Fan ◽  
Xu Sun ◽  
...  

NiOOH–NiCr2O4/NF shows high activity for the OER in alkaline media, achieving a catalytic current density of 20 mA cm−2 at an overpotential of 271 mV.


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