Mechanistic insights into artificial metalloenzymes towards imine reduction

2019 ◽  
Vol 21 (42) ◽  
pp. 23408-23417 ◽  
Author(s):  
Haisong Feng ◽  
Xuan Guo ◽  
Hui Zhang ◽  
Lifang Chen ◽  
Pan Yin ◽  
...  
Keyword(s):  
Anchoring Effect ◽  
Artificial Metalloenzymes ◽  
Imine Reduction

The anchoring effect of artificial metalloenzymes determines the chirality of the product of imine reduction.

Enantioselective imine reduction catalyzed by imine reductases and artificial metalloenzymes

2014 ◽  
Vol 12 (19) ◽  
pp. 2989-2992 ◽  
Author(s):  
Daniela Gamenara ◽  
Pablo Domínguez de María
Keyword(s):  
Organic Synthesis ◽  
Chiral Amines ◽  
Enantioselective Reduction ◽  
Artificial Metalloenzymes ◽  
Imine Reduction

Adding value to organic synthesis. Novel imine reductases enable the enantioselective reduction of imines to afford chiral amines. Likewise, novel bioinspired artificial metalloenzymes can perform the same reaction as well. Remarkable recent examples are herein discussed.

The Anchoring Effect in Performance Appraisals

2005 ◽  
Author(s):  
Gary P. Latham ◽  
Marie-Helene Budworth
Keyword(s):  
Performance Appraisals ◽  
Anchoring Effect

scholarly journals Mechanistic insight into B(C6F5)3 catalyzed imine reduction with PhSiH3 under stoichiometric water conditions

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 20961-20969
Author(s):  
Yunqing He ◽  
Wanli Nie ◽  
Ying Xue ◽  
Qishan Hu
Keyword(s):  
Mechanistic Insight ◽  
Excess Water ◽  
Water Conditions ◽  
Imine Reduction ◽  
Water Amount ◽  
Insight Into

Hydrosilylation or amination products? It depends on water amount and nucleophiles like excess water or produced/added amines.

Engineering Artificial Metalloenzymes

2021 ◽  
pp. 177-205
Author(s):  
Kevin A. Harnden ◽  
Yajie Wang ◽  
Lam Vo ◽  
Huimin Zhao ◽  
Yi Lu
Keyword(s):  
Artificial Metalloenzymes

scholarly journals In Vivo Assembly of Artificial Metalloenzymes and Application in Whole‐Cell Biocatalysis**

2021 ◽  
Author(s):  
Shreyans Chordia ◽  
Siddarth Narasimhan ◽  
Alessandra Lucini Paioni ◽  
Marc Baldus ◽  
Gerard Roelfes
Keyword(s):  
Whole Cell ◽  
Whole Cell Biocatalysis ◽  
Artificial Metalloenzymes

scholarly journals Artificial imine reductases: developments and future directions

2020 ◽  
Vol 1 (5) ◽  
pp. 369-378
Author(s):  
Rosalind L. Booth ◽  
Gideon Grogan ◽  
Keith S. Wilson ◽  
Anne-Kathrin Duhme-Klair
Keyword(s):  
Future Research ◽  
Future Directions ◽  
Artificial Metalloenzymes

This review surveys the development of this class of artificial metalloenzymes and provides a perspective on existing and future research in the area.

scholarly journals Editorial: Advances in the Development of Artificial Metalloenzymes

2019 ◽  
Vol 7 ◽  
Author(s):  
Tatjana N. Parac-Vogt ◽  
Andrea Erxleben ◽  
Gerhard Schenk ◽  
Rajeev Prabhakar
Keyword(s):  
Artificial Metalloenzymes
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