Bioinspired hierarchical cross-linked graphene–silicon nanofilms via synergistic interfacial interactions as integrated negative electrodes for high-performance lithium storage

2020 ◽  
Vol 22 (4) ◽  
pp. 2105-2114
Author(s):  
Bo Wang ◽  
Xiaoyu Wu ◽  
Jinhui Zhang ◽  
Xiaoyu Zhang ◽  
Songmei Li

Inspired by the relationship between nacre's unique structure and outstanding mechanical properties, a flexible and robust bioinspired rGO–Si–CMC–PAA film was prepared via a vacuum-assisted self-assembly process and thermal condensation reaction.

2018 ◽  
Vol 6 (27) ◽  
pp. 13321-13330 ◽  
Author(s):  
Kyungbae Kim ◽  
Jae-Hun Kim

Cluster microspheres are prepared by self-assembly process, where two dissimilar metal oxide materials are inversely placed.


2020 ◽  
Vol 44 (34) ◽  
pp. 14453-14462
Author(s):  
Bo Wang ◽  
Yue Li ◽  
Kun Liu ◽  
Jinhui Zhang ◽  
Xiaoyu Wu

Porous network-like Ni3S2 nanoarchitectures have been successfully synthesized on nickel foam via a facile eco-friendly biomolecule-assisted hydrothermal process, in which l-cysteine is served as both the sulfur source and the directing molecule.


2019 ◽  
Vol 21 (40) ◽  
pp. 22283-22292 ◽  
Author(s):  
Mingxia Lu ◽  
Gang Wang ◽  
Bo Li ◽  
Jing Chen ◽  
Jingchao Zhang ◽  
...  

Stepwise ultrasonication and self-assembly process enables good separation between disequilibrium and equilibrium thermodynamic molecular interactions, which allow excellent electrochemical charge storage based on ratio-dependent 1D–2D hybridisation.


2019 ◽  
Vol 31 (5) ◽  
pp. 557-569 ◽  
Author(s):  
Tong Sun ◽  
Huawei Zou ◽  
Ya Zhou ◽  
Rui Li ◽  
Mei Liang ◽  
...  

In this article, two types of functional graphene oxide (GO) with amine-rich surface were synthesized through chemically grafting two different molecular chain length trifunctional poly(oxypropylene)amines T5000 and T403, which were named as T5000-GO and T403-GO, respectively. The functionalized GO was then added to epoxy (EP) resin. Fourier transform infrared spectra analysis confirmed successful chemical functionalization on GO. Both T403-GO and T5000-GO were tightly embedded in the EP, because the amine-rich surface of functionalized-GO could form covalent bonds with the EP matrix, thereby contributing to the enhancement of mechanical properties. Particularly, T5000-GO, which has longer grafting molecule chains, achieved better compatibility and dispersibility in the EP matrix, resulting in a better reinforcing efficiency in mechanical properties. For example, the T5000-GO/EP composites showed an incremental enhancement in tensile strength with increasing filler concentrations, whereas their T403-GO/EP counterparts failed to follow the same trend. Meanwhile, the T5000-GO/EP composites with only 0.1-wt% T5000-GO achieved a prominent increase in flexural strength (approximately 50%) and flexural modulus (approximately 26.8%), which were higher than those of T403-GO-filled counterparts. This work indicated that the compatibility and interphase between GO and EP could be designed by manipulating the length of grafting molecule chains, thereby providing a better understanding of the relationship between the structure and mechanical properties of the graphene/EP nanocomposites.


RSC Advances ◽  
2015 ◽  
Vol 5 (118) ◽  
pp. 97289-97294 ◽  
Author(s):  
Xiurong Guan ◽  
Lina Wang ◽  
Jia Yu ◽  
Yuchao Li ◽  
Shimou Chen ◽  
...  

A Si/SWNT 3D-composite-nanonetwork integrated anode for high-performance lithium storage, through a combined process of electrostatic induced self-assembly and film transfer.


Soft Matter ◽  
2020 ◽  
Vol 16 (23) ◽  
pp. 5497-5505 ◽  
Author(s):  
P. Xu ◽  
T. Erdem ◽  
E. Eiser

Inspired by the relationship between the ordered architecture of aragonite crystals and biopolymers found in natural nacre, we present a facile strategy to construct organic/inorganic nanocomposites with hierarchical structure via a water-evaporation driven self-assembly process.


RSC Advances ◽  
2016 ◽  
Vol 6 (32) ◽  
pp. 26856-26862 ◽  
Author(s):  
Xiao-Ning Ren ◽  
Liang Wu ◽  
Jun Jin ◽  
Jing Liu ◽  
Zhi-Yi Hu ◽  
...  

A 3D interconnected hierarchically macro-mesoporous TiO2 network optimized by the mediation of biomolecular self-assembly has been used for high performance lithium storage.


Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1794
Author(s):  
José Pérez-Rigueiro ◽  
Manuel Elices ◽  
Gustavo R. Plaza ◽  
Gustavo V. Guinea

The prominence of spider silk as a hallmark in biomimetics relies not only on its unrivalled mechanical properties, but also on how these properties are the result of a set of original design principles. In this sense, the study of spider silk summarizes most of the main topics relevant to the field and, consequently, offers a nice example on how these topics could be considered in other biomimetic systems. This review is intended to present a selection of some of the essential design principles that underlie the singular microstructure of major ampullate gland silk, as well as to show how the interplay between them leads to the outstanding tensile behavior of spider silk. Following this rationale, the mechanical behavior of the material is analyzed in detail and connected with its main microstructural features, specifically with those derived from the semicrystalline organization of the fibers. Establishing the relationship between mechanical properties and microstructure in spider silk not only offers a vivid image of the paths explored by nature in the search for high performance materials, but is also a valuable guide for the development of new artificial fibers inspired in their natural counterparts.


2014 ◽  
Vol 633 ◽  
pp. 82-87
Author(s):  
Shui Qing Xiao ◽  
Shang Hua Wu

The present review will try to sum up the research on the microstructure and properties of the Ti(C,N)-based cermets materials in recent years. Firstly, the development history, the microstructure and mechanical properties of Ti(C,N)-based cermets, and the relationship between Ti(C,N)-based cermets microstructure and their properties were introduced respectively. Secondly, Compared with different microstructure and properties of Ti(C,N)-based cermets material which were made by different composite constituent. Furthermore, the relationship between mechanical properties of Ti(C,N)-based cermets and sintering method was introduced. Results show that the high performance products can be produced by means of fast sintering techniques at low temperature successfully, such as spark plasma sintering technology. However, the most widely used way is vacuum sintering method. Lastly, the development trend of Ti(C,N)-based cermets were included.


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