scholarly journals Water binding to FeIII hemes studied in a cooled ion trap: characterization of a strong ‘weak’ ligand

2019 ◽  
Vol 21 (38) ◽  
pp. 21329-21340 ◽  
Author(s):  
Mohammad Aarabi ◽  
Satchin Soorkia ◽  
Gilles Grégoire ◽  
Michel Broquier ◽  
Aurélien de la Lande ◽  
...  

Characterizing in the gas phase the intense water ligation to ferric heme, dramatically distinct from protonated heme.

2020 ◽  
Author(s):  
Oisin Shiels ◽  
P. D. Kelly ◽  
Cameron C. Bright ◽  
Berwyck L. J. Poad ◽  
Stephen Blanksby ◽  
...  

<div> <div> <div> <p>A key step in gas-phase polycyclic aromatic hydrocarbon (PAH) formation involves the addition of acetylene (or other alkyne) to σ-type aromatic radicals, with successive additions yielding more complex PAHs. A similar process can happen for N- containing aromatics. In cold diffuse environments, such as the interstellar medium, rates of radical addition may be enhanced when the σ-type radical is charged. This paper investigates the gas-phase ion-molecule reactions of acetylene with nine aromatic distonic σ-type radical cations derived from pyridinium (Pyr), anilinium (Anl) and benzonitrilium (Bzn) ions. Three isomers are studied in each case (radical sites at the ortho, meta and para positions). Using a room temperature ion trap, second-order rate coefficients, product branching ratios and reaction efficiencies are reported. </p> </div> </div> </div>


2021 ◽  
pp. 1-13
Author(s):  
Li Tan ◽  
Ning Wang ◽  
Yingjian Dong ◽  
Siyuan Li ◽  
Xuehan Wang ◽  
...  

2019 ◽  
Vol 150 (14) ◽  
pp. 144304 ◽  
Author(s):  
Anh T. Le ◽  
Sanjay G. Nakhate ◽  
Duc-Trung Nguyen ◽  
Timothy C. Steimle ◽  
Michael C. Heaven
Keyword(s):  

2011 ◽  
Vol 59 (1) ◽  
pp. 256-262 ◽  
Author(s):  
Xiaowen Lv ◽  
Lei Wu ◽  
Jing Wang ◽  
Junguo Li ◽  
Yuchang Qin

2006 ◽  
Vol 20 (20) ◽  
pp. 3101-3110 ◽  
Author(s):  
Stefanie Leonard ◽  
Monica Ferraro ◽  
Erwin Adams ◽  
Jos Hoogmartens ◽  
Ann Van Schepdael

Sign in / Sign up

Export Citation Format

Share Document