A stable dual-emitting dye@LMOF luminescence probe for the rapid and visible detection of organophosphorous pesticides in aqueous media

CrystEngComm ◽  
2020 ◽  
Vol 22 (6) ◽  
pp. 1050-1056 ◽  
Author(s):  
Jie Zhang ◽  
Wendi Zhou ◽  
Lijun Zhai ◽  
Xiaoyan Niu ◽  
Tuoping Hu

The composite RhB@LMOF 1 was synthesized and exhibited sensitive and selective recognition ability for the detection of organophosphorous (OPs) pesticides in aqueous media.

Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 280 ◽  
Author(s):  
Wanwan Ma ◽  
Kyung Ho Row

A type of molecular-imprinted polymer with magnetic molybdenum disulfide as a base and deep eutectic solvent as a functional monomer (Fe3O4@MoS2@DES-MIP) was prepared with surface molecular imprinting method. It was applied as the adsorbent for the selective recognition and separation of (+)-catechin, (−)-epicatechin, (−)-epigallocatechin, (−)-epicatechin gallate, and (−)-epigallocatechin gallate in green tea in the process of magnetic solid-phase extraction (MSPE) combined with high-performance liquid chromatography (HPLC). The structure of Fe3O4@MoS2@DES-MIP was characterized by Fourier transform infrared spectroscopy and field emission scanning electron microscopy. The adsorption properties and selective recognition ability on (−)-epigallocatechin gallate and the other four structural analogues were examined and compared. The results show that the polymer has excellent selective recognition ability for (−)-epigallocatechin gallate, and its adsorption capacity was much higher than that of structural analogues. The Fe3O4@MoS2@DES-MIP not only has the special recognition ability to template a molecule, but also can be separated by magnets with high separation efficiency and can be used in MSPE.


2011 ◽  
Vol 71-78 ◽  
pp. 1425-1428
Author(s):  
Kai Cheng Zhang ◽  
Si Ying Zhao ◽  
Ming Yang

A new method of removing rotenone from contaminated water using molecularly imprinted polymeric microspheres (MIPMs) is described. The MIPMs were prepared by the emulsifier-free polymerization method. The removal efficiency and selective recognition ability of the MIPMs were studied. The highest removal efficiency was observed at pH = 8. Moreover, the MIPMs can be re-used for at least 10 times without losing any removal efficiency. The MIPMs provided a selective, simple, reliable and practicable solution to remove rotenone from contaminated water.


RSC Advances ◽  
2015 ◽  
Vol 5 (117) ◽  
pp. 96905-96910 ◽  
Author(s):  
Xueyi Sun ◽  
Yu Wang ◽  
Xiaofeng Zhang ◽  
Shihong Zhang ◽  
Zhao Zhang

The optical behavior of a simple intramolecular charge transfer (ICT) fluorescent probe, a coumarin-nitrobenzene conjugate (CNB), has been described to detect cyanide (CN−) selectively in buffered aqueous media.


2019 ◽  
Author(s):  
Qing-Xiang Liu ◽  
Shao-Cong Yu ◽  
Zhi-Xiang Zhao ◽  
Feng Yang ◽  
Yue Ding

A novel anthracene-based tetra-perimidine hexafluorophosphate, 9,10-di{bi[2’-(N-ethylperimidinyl)ethyl]aminomethyl}anthracene PF6- (3) was prepared, and its structure was determined through X-ray analysis, 1H and 13C NMR. There are two soft (N-ethylperimidinylCH2CH2)2NCH2- moities on 9,10-locations of anthracene in the cationic part of 3. Compound 3 was used as a chemosensor to research the recognition ability for Cr3+ by fluorescence and UV titrations, IR, 1H NMR and HRMS. The results indicate that 3 is an effective chemosensor for Cr3+.


2019 ◽  
Vol 55 (27) ◽  
pp. 3872-3875 ◽  
Author(s):  
Takashi Nakamura ◽  
Sota Yonemura ◽  
Tatsuya Nabeshima

An amide cyclodextrin with anion recognition ability exhibits unique binding mode in which unsymmetrically arranged functional groups play distinctive roles.


2019 ◽  
Vol 284 ◽  
pp. 55-62 ◽  
Author(s):  
Keyuan Liu ◽  
Ganhong Du ◽  
Long Ye ◽  
Liming Jiang

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