Supramolecular organisation of sulphate salt hydrates exemplified with brucine sulphate

CrystEngComm ◽  
2020 ◽  
Vol 22 (43) ◽  
pp. 7204-7216 ◽  
Author(s):  
Doris E. Braun
Keyword(s):  
Relative Humidity ◽  
Hydrate Formation ◽  
Salt Hydrates ◽  
Supramolecular Organisation ◽  
Sulphate Salts

The frequency of hydrate formation among organic sulphate salts is unravelled. Interconversion of the hydrates of brucine sulphate occurs with small changes in the relative humidity.

Inorganic salt hydrates and zeolites composites studies for thermochemical heat storage

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Ata Ur Rehman ◽  
Muhammad Zahir Shah ◽  
Shehla Rasheed ◽  
Wasim Afzal ◽  
Muhammad Arsalan ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Water Sorption ◽  
Inorganic Salt ◽  
Heat Storage ◽  
Water Molecules ◽  
Thermochemical Heat Storage ◽  
Dehydration Enthalpy ◽  
Salt Hydrates ◽  
Heat Storage Materials ◽  
Pure Salt

Abstract Salt hydrates (MgSO4 and ZnSO4) impregnated in zeolites, offer a variety of improvements, mostly providing a large surface area for salt hydrates and water molecules. A composite of 5 and 10% of salt contents were prepared as heat storage materials. The study’s finding showed that dehydration enthalpy of MgSO4 (1817 J g−1) and ZnSO4 (1586 J g−1) were 10 and 15% improved than pure salt hydrates by making composites. During the hydration process of composites, the water sorption is 30–37% improved and further the increasing of salt contents in composites enhances more 10% increase in the water resorption. The cyclicability of MgSO4/zeolite and ZnSO4/zeolite were 45 and 51% improved than their corresponding pure salt hydrates. The effect of humidity on the water sorption result reveals that composites of MgSO4/zeolite and ZnSO4/zeolite at 75% relative humidity (RH), the mass of water are 51 and 40% increase than 55% RH.

scholarly journals The influence of light and relative humidity on the formation of epsomite in cadmium yellow and French ultramarine modern oil paints

2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Jessie Harrison ◽  
Judith Lee ◽  
Bronwyn Ormsby ◽  
David J. Payne
Keyword(s):  
Relative Humidity ◽  
Magnesium Sulphate ◽  
Degradation Product ◽  
Water Soluble ◽  
Light Conditions ◽  
X Ray ◽  
Oil Paintings ◽  
Water Sensitivity ◽  
Oil Paints ◽  
Sulphate Salts

AbstractThe effect of relative humidity (RH) and light on the development of epsomite (MgSO4·7H2O) in Winsor & Newton cadmium yellow (CY) and French ultramarine (FU) artists’ oil colour paints was investigated. Tube paint samples were aged for 12 weeks at either 50% or 75% RH, under ambient light (200 ± 1 lx), elevated light (11,807 ± 328 lx), and near-dark conditions. Aged paint samples were characterised using light microscopy (LM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Results indicated that ageing at 75% RH in elevated light conditions, promoted the formation of hydrated magnesium sulphate (MgSO4·6–7H2O) crystals on the surface of both paints. The formation of sodium sulphate (Na2SO4) as a degradation product of French ultramarine oil paints after ageing at 75% RH in elevated light conditions is described. The formation of magnesium sulphate crystals in the absence of elevated SO2 is a new finding. For both cadmium yellow and French ultramarine oil paints, the pigments present are a likely source of sulphur, enabling the formation of sulphate salts, i.e., cadmium sulphide (CdS) yellow, and the sulphur radical anions (S3−) present in ultramarine pigment. Sulphur-containing impurities arising from pigment manufacture are an additional possibility. It was previously theorised that epsomite formation in water-sensitive twentieth century oil paintings resulted from exposure to the elevated atmospheric sulphur dioxide (SO2) levels of the 1950s–1970s. This study demonstrates that hydromagnesite-containing cadmium yellow and French ultramarine oil paints of any period may be vulnerable to water-soluble sulphate salts formation and that this process is promoted by exposure to light and high (75%) RH environments. The formation of sulphate salts as a degradation product is known to contribute toward the development of water sensitivity of modern oil paintings which can pose significant challenges to conservation. Therefore this study highlights the importance of minimising exposure to light and raised relative humidity for paintings containing such CY and FU oil paint passages, to help slow down these types of degradation phenomena which have implications for preservation.

scholarly journals Predicting Deliquescence Relative Humidities of Crystals and Crystal Mixtures

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3176
Author(s):  
Heiner Veith ◽  
Christian Luebbert ◽  
Gabriele Sadowski
Keyword(s):  
Relative Humidity ◽  
Food Industry ◽  
Hydrate Formation ◽  
Aqueous Solubility ◽  
Artificial Sweeteners ◽  
Temperature Influence ◽  
Statistical Associating Fluid Theory ◽  
Fluid Theory ◽  
The Stability ◽  
Formation Of Hydrates

The presence of water in the form of relative humidity (RH) may lead to deliquescence of crystalline components above a certain RH, the deliquescence RH (DRH). Knowing the DRH values is essential, e.g., for the agrochemical industry, food industry, and pharmaceutical industry to identify stability windows for their crystalline products. This work applies the Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) to purely predict the DRH of single components (organic acids, sugars, artificial sweeteners, and amides) and multicomponent crystal mixtures thereof only based on aqueous solubility data of the pure components. The predicted DRH values very well agree with the experimental ones. In addition, the temperature influence on the DRH value could be successfully predicted with PC-SAFT. The DRH prediction also differentiates between formation of hydrates and anhydrates. PC-SAFT-predicted phase diagrams of hydrate-forming components illustrate the influence of additional components on the hydrate formation as a function of RH. The DRH prediction via PC-SAFT allows for the determining of the stability of crystals and crystal mixtures without the need for time-consuming experiments.

EPIDEMIOLOGY, ECOLOGY AND PREVALENCE OF SOIL TRANSMITTED HELMINTHS FROM KOSHI REGION OF NORTH BIHAR.

2018 ◽  
Vol 24 (1) ◽  
Author(s):  
LAKSHMI CHOUDHARY ◽  
PRABHAWATI PRABHAWATI
Keyword(s):  
Relative Humidity ◽  
Ascaris Lumbricoides ◽  
Rainy Season ◽  
Climatic Factors ◽  
Trichuris Trichiura ◽  
Hookworm Infection ◽  
Soil Transmitted Helminths ◽  
High Incidence ◽  
Apparently Healthy

Prevalence of soil transmitted helminthes infections in apparently healthy school going children and other 528 people of different districts of Koshi regions of North Bihar were evaluated. Over all incidences of STHs infection was 39.39% during study. High incidence of STH was seen in the rainy season i.e., in the month of July and August, September, significantly higher (P<0.05) .The incidence of Ascaris lumbricoides was highest in the month of August (18.64%). The month of September was 15.25% followed by that of July (14.4%) and October with 10.16%. Also the incidence of hookworm registered the highest incidence in the month of June (19.27%) and lowest in the month of December (4.82%) during the study period. However prevalence of Trichuris trichiura was negligible and it was almost nil in the most of the months but was highest in month of September with 28.57% and lowest in October with 14.00% The climatic factors are responsible for soil transmitted helminthes which are temperature, rainfall and relative humidity. Ascariasis, Trichuriasis and Ancyclostomiasis (Hookworm infection) are found to be endemic in this region.

EL NINO RELATED CLIMATE AND DENGUE FEVER CASES IN JEDDAH, SAUDI ARABIA

2019 ◽  
Vol 25 (1) ◽  
Author(s):  
MASROOR ALI KHAN ◽  
KHALID AL GHAMDI ◽  
JAZEM A. MEHYOUB ◽  
RAKHSHAN KHAN
Keyword(s):  
Relative Humidity ◽  
Dengue Fever ◽  
El Niño ◽  
Significant Relationship ◽  
El Nino ◽  
Climate Data ◽  
Light Traps ◽  
Mosquito Abundance ◽  
Dengue Transmission ◽  
The Relationship

The focus of this study is to find the relationship between El Nino and dengue fever cases in the study area.Mosquito density was recorded with the help of light traps and through aspirators collection. Climate data were obtained from National Meteorology and Environment centre. (Year wise El Nino and La Nina data are according to NOAA & Golden Gate Weather Services). Statistical methods were used to establish the correlation coefficient between different factors. A high significant relationship was observed between Relative Humidity and Dengue fever cases, but Aedes abundance had no significant relationship with either Relative humidity and Temperature. Our conclusion is that the El Nino does not affect the dengue transmission and Aedes mosquito abundance in this region, which is supported by earlier works.

Effect of interlayer cation and relative humidity on the hydration properties of a dioctahedral smectite

2007 ◽  
Vol 2007 (suppl_26) ◽  
pp. 417-422 ◽  
Author(s):  
W. Oueslati ◽  
M. S. Karmous ◽  
H. Ben Rhaiem ◽  
B. Lanson ◽  
A. Ben Haj Amara
Keyword(s):  
Relative Humidity ◽  
Interlayer Cation ◽  
Hydration Properties ◽  
Dioctahedral Smectite
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