Rapid synthesis of hollow PtPdCu trimetallic octahedrons at room temperature for oxygen reduction reactions in acid media

CrystEngComm ◽  
2020 ◽  
Vol 22 (9) ◽  
pp. 1586-1592 ◽  
Author(s):  
Ruopeng Zhao ◽  
Zhijing Chen ◽  
Shaoming Huang

Hollow PtPdCu trimetallic octahedrons were prepared under mild conditions, exhibiting enhanced activity toward the oxygen reduction reaction in acid media.

Author(s):  
Saravanan Nagappan ◽  
Malarkodi Duraivel ◽  
Shamim Ahmed Hira ◽  
Kandasamy Prabakar ◽  
Chang-Sik Ha ◽  
...  

Recently, heteroatom doped core–shell nanostructures (HCSNs) have been widely used as superior electrocatalysts for oxygen reduction reactions (ORRs) owing to their enhanced ORR performance and stability under harsh environmental conditions....


Nanoscale ◽  
2019 ◽  
Vol 11 (30) ◽  
pp. 14266-14275 ◽  
Author(s):  
Ik Seon Kwon ◽  
In Hye Kwak ◽  
Ju Yeon Kim ◽  
Hafiz Ghulam Abbas ◽  
Tekalign Terfa Debela ◽  
...  

2D hybrid nanostructures consisting of 1T′ phase MoS2 and Fe-phthalocyanine molecules exhibit excellent catalytic activity toward both the hydrogen evolution reaction and oxygen reduction reaction.


2019 ◽  
Vol 48 (7) ◽  
pp. 2352-2358 ◽  
Author(s):  
Lili Fan ◽  
Xinxin Du ◽  
Yuming Zhang ◽  
Mengfei Li ◽  
Meilian Wen ◽  
...  

N,P-doped carbon with encapsulated Co nanoparticles is fabricated from a Co-MOF and triphenylphosphine mixture as an efficient electrocatalyst for oxygen reduction reaction.


2017 ◽  
Vol 5 (7) ◽  
pp. 3320-3329 ◽  
Author(s):  
Xinyu Li ◽  
Zongbao Li ◽  
Xiaofeng Yang ◽  
Lichao Jia ◽  
Yong Qing Fu ◽  
...  

The initial oxygen reduction reactions on stoichiometric and reduced CeO2 (111) surfaces as a cathode catalyst for lithium-oxygen batteries have been investigated by a first-principles method.


2020 ◽  
Vol 8 (42) ◽  
pp. 22389-22400
Author(s):  
Liuxuan Luo ◽  
Cehuang Fu ◽  
Shuiyun Shen ◽  
Fengjuan Zhu ◽  
Junliang Zhang

Composition-graded Cu–Pd nanospheres are annealed for highly efficient alkaline oxygen reduction reaction, and further coated with Pt monolayer shells for high-performance acidic oxygen reduction reaction.


Nanoscale ◽  
2018 ◽  
Vol 10 (36) ◽  
pp. 17140-17147 ◽  
Author(s):  
Muhammad Aizaz Ud Din ◽  
Faisal Saleem ◽  
Muhammad Zulfiqar ◽  
Xun Wang

Oxygen reduction reaction-favoring PtPdAg hollow nanoparticle, nanodimer and nanowire catalysts are synthesized, all of which have been demonstrated to be promoting factors for the ORR. PtPdAg/C nanodimers exhibit excellent performance for the ORR with the highest mass activity.


2016 ◽  
Vol 4 (19) ◽  
pp. 7148-7154 ◽  
Author(s):  
Baosheng Li ◽  
Lili Zhang ◽  
Luwei Chen ◽  
Xiaoyi Cai ◽  
Linfei Lai ◽  
...  

Metal nitrides (FeCoN) surrounded by pyridinic N were identified as the active center for the oxygen reduction reaction.


2015 ◽  
Vol 3 (44) ◽  
pp. 22031-22034 ◽  
Author(s):  
Seung Hyo Noh ◽  
Min Ho Seo ◽  
Xiao Ye ◽  
Yuki Makinose ◽  
Takeyoshi Okajima ◽  
...  

Cu@N-C with the Cu particles encapsulated in N-doped carbon shells, which was activated by CO2 treatment, is an excellent electrocatalyst for the oxygen reduction reaction.


2013 ◽  
Vol 17 (04) ◽  
pp. 252-258 ◽  
Author(s):  
Qinggang He ◽  
Xiao Cheng ◽  
Ying Wang ◽  
Ruimin Qiao ◽  
Wanli Yang ◽  
...  

The dicobalt complex [ Co2(L2) ] of a Schiff-base pyrrole macrocycle adopts a Pacman structure in solution and the solid state and shows much greater catalytic activity and selectivity for the four-electron oxygen reduction reaction (ORR) than the mononuclear cobalt phthalocyanine (CoPc) counterpart. Soft X-ray absorption spectroscopy (XAS) shows that the Co center in Co2(L2) is of the same valence as mononuclear CoPc . However, the former complex shows higher unoccupied Co 3d density which is believed to be beneficial for electron transfers. Furthermore, the XAS data suggests that the crystal fields for Co2(L2) and CoPc are different, and that an interaction remains between two Co atoms in Co2(L2) . DFT calculations imply that the sterically hindered, cofacial structure of the dicobalt complex is critical for the operation of the four-electron reaction pathway during the ORR.


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