Controllable synthesis of a 3D ZnS@MoO3 heterojunction via a hydrothermal method towards efficient NO purification under visible light

CrystEngComm ◽  
2020 ◽  
Vol 22 (2) ◽  
pp. 257-266 ◽  
Author(s):  
Ziyang Guo ◽  
Wangchen Huo ◽  
Tong Cao ◽  
Fangzheng Fan ◽  
Guangxu Ge ◽  
...  

Heterojunctions can deliver superior photocatalytic efficiency via modulating the surface-interface reaction, enhancing light absorption and hindering charge carrier recombination.

2022 ◽  
Author(s):  
Qingqing Gao ◽  
Qian Lei ◽  
Ruoyan Miao ◽  
Manyi Gao ◽  
Fang Song ◽  
...  

Polymeric carbon nitride (PCN) is an emerging metal-free photocatalysts with high stability but is plagued by low photocatalytic efficiency due to the rapid charge carrier recombination behavior. Herein, Bi doped...


NANO ◽  
2018 ◽  
Vol 13 (11) ◽  
pp. 1850129 ◽  
Author(s):  
Chujun Chen ◽  
Xia Xin ◽  
Jinniu Zhang ◽  
Gang Li ◽  
Yafeng Zhang ◽  
...  

To improve the high charge carrier recombination rate and low visible light absorption of {001} facets exposed TiO2 [TiO2(001)] nanosheets, few-layered MoS2 nanoparticles were loaded on the surfaces of TiO2(001) nanosheets by a simple photodeposition method. The photocatalytic activities towards Rhodamine B (RhB) were investigated. The results showed that the MoS2–TiO2(001) nanocomposites exhibited much enhanced photocatalytic activities compared with the pure TiO2(001) nanosheets. At an optimal Mo/Ti molar ratio of 25%, the MoS2–TiO2(001) nanocomposites displayed the highest photocatalytic activity, which took only 30[Formula: see text]min to degrade 50[Formula: see text]mL of RhB (50[Formula: see text]mg/L). The active species in the degradation reaction were determined to be h[Formula: see text] and [Formula: see text]OH according to the free radical trapping experiments. The reduced charge carrier recombination rate, enhanced visible light utilization and increased surface areas contributed to the enhanced photocatalytic performances of the 25% MoS2–TiO2(001) nanocomposites.


2019 ◽  
Vol 11 (11) ◽  
pp. 1540-1546
Author(s):  
Maha Alhaddad ◽  
Reda M. Mohamed

The split of charge carriers is an essential point that raises the rate of hydrogen evolution in the reaction of water splitting. The avoidance of charge carrier recombination can be attained by deposition of co-catalysts onto the surface of semiconductor materials. In this work, PbTiO3 nanorods were prepared using hydrothermal route in the presence of polyvinylpyrrolidone as a surfactant. Finally, PbTiO3 nanorods were decorated by RuO2 nanoparticles and the weight percent of RuO2 changed from 0.5 to 2.0 wt%. PbTiO3 nanorods and RuO2–PbTiO3 nanocomposites were investigated for their production of hydrogen under visible light illumination in the presence of glycerol as a scavenger. The outcomes recorded that the photocatalytic activity of PbTiO3 nanorods was improved by RuO2 nanoparticles decoration. The content of RuO2 nanoparticles had an important effect on the photocatalytic activity of PbTiO3 nanorods. The best weight percent of decorated RuO2 was 1.5 wt%, which improved photocatalytic activity of PbTiO3 nanorods by about 6 times. Moreover, the photocatalytic activity of 1.5 wt% RuO2–PbTiO3 nanocomposites was almost stable for five times. The enlargement of photocatalytic activity of PbTiO3 nanorods by RuO2 decoration was due to high surface area, small bandgap and avoidance of charge carrier recombination.


Author(s):  
Jing Ren ◽  
Shurong Wang ◽  
Jianxing Xia ◽  
Chengbo Li ◽  
Lisha Xie ◽  
...  

Defects, inevitably produced in the solution-processed halide perovskite films, can act as charge carrier recombination centers to induce severe energy loss in perovskite solar cells (PSCs). Suppressing these trap states...


2005 ◽  
Vol 155 (2) ◽  
pp. 242-245 ◽  
Author(s):  
A. Pivrikas ◽  
R. Österbacka ◽  
G. Juška ◽  
K. Arlauskas ◽  
H. Stubb

2020 ◽  
Vol 69 (4) ◽  
pp. 046101
Author(s):  
Qing-Zhong Zhou ◽  
Feng Guo ◽  
Ming-Rui Zhang ◽  
Qing-Liang You ◽  
Biao Xiao ◽  
...  

Nanoscale ◽  
2018 ◽  
Vol 10 (18) ◽  
pp. 8483-8495 ◽  
Author(s):  
Shengli Niu ◽  
Zhiyong Liu ◽  
Ning Wang

A dihydronaphthyl-based C60 bisadduct (NCBA) acceptor was introduced as a third component material to typical binary polymer solar cells (PSCs).


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