Template effect of innocent and coordinating anions on the formation of interpenetrated 2D and 3D networks: methyl orange and iodine sorption studies

CrystEngComm ◽  
2020 ◽  
Vol 22 (4) ◽  
pp. 751-766 ◽  
Author(s):  
Fayaz Baig ◽  
Krishnan Rangan ◽  
Shibu M. Eappen ◽  
Sanjay K. Mandal ◽  
Madhushree Sarkar
Keyword(s):  
Schiff Base ◽  
Methyl Orange ◽  
Coordination Polymer ◽  
Counter Anion ◽  
Template Effect ◽  
2D And 3D ◽  
3D Networks

A pyridyl based Schiff base resulted in a 2D staircase network (CP1) with Cd(ii) when ClO4− is the counter anion while the use of benzene-1,3-disulphonate counter anion resulted in a novel 3D Cd(ii) coordination polymer with threefold interpenetration (CP2).

Cd(II) coordination polymer of fumaric acid and pyridyl-hydrazide Schiff base: Structure, photoconductivity and theoretical interpretation

2021 ◽  
Vol 518 ◽  
pp. 120253
Author(s):  
Angeera Chandra ◽  
Dhananjoy Das ◽  
Joaquín-Ortega Castro ◽  
Kaushik Naskar ◽  
Srikanta Jana ◽  
...  
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Fumaric Acid ◽  
Theoretical Interpretation ◽  
Base Structure

scholarly journals Probing the unpaired Fe spins across the spin crossover of a coordination polymer

2021 ◽  
Author(s):  
Thilini K. Ekanayaka ◽  
Hannah Kurz ◽  
Ashley S. Dale ◽  
Guanhua Hao ◽  
Aaron Mosey ◽  
...  
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Spin State ◽  
Spin Crossover ◽  
State Transition ◽  
Spin State Transition

For the spin crossover coordination polymer [Fe(L1)(bipy)]n (where L1 is a N2O22− coordinating Schiff base-like ligand bearing a phenazine fluorophore and bipy = 4,4′-bipyridine), there is compelling additional evidence of a spin state transition.

Construction of a 1-D Sm(iii) coordination polymer with a long-chain Schiff base ligand: dual-emissive response to metal ions

2020 ◽  
Vol 7 (2) ◽  
pp. 464-469 ◽  
Author(s):  
Jieni Liu ◽  
Ting Zhu ◽  
Xiaoping Yang ◽  
Hongfen Chen ◽  
Dongliang Shi ◽  
...  
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Metal Ions ◽  
Schiff Base Ligand ◽  
Ppm Level ◽  
Long Chain

A 1-D coordination polymer [Sm(HL)2(NO3)]n was constructed using a new flexible Schiff base ligand that has a long-chain (CH2)10 backbone, and it shows dual-emissive response to metal ions, especially to Co2+ at the ppm level.

Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer

2004 ◽  
Vol 43 (20) ◽  
pp. 2684-2687 ◽  
Author(s):  
Ryo Kitaura ◽  
Goro Onoyama ◽  
Hirotoshi Sakamoto ◽  
Ryotaro Matsuda ◽  
Sin-ichiro Noro ◽  
...  
Keyword(s):  
Schiff Base ◽  
Coordination Polymer
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