A structural exploration of anisole accessed through extreme crystallisation conditions

CrystEngComm ◽  
2019 ◽  
Vol 21 (30) ◽  
pp. 4422-4426 ◽  
Author(s):  
Ellie Louvain Smith ◽  
Joe Ridout ◽  
Jonathan David Sellars ◽  
Michael Richard Probert
Keyword(s):  
High Pressure ◽  
Low Temperature ◽  
Temperature Form

A novel high pressure polymorph of anisole has been discovered and investigated with respect to the known low temperature form.

The Application of X-Ray Diffraction at Elevated Temperatures to Study the Mechanism of Formation of Sodium Tripolyphosphate

1961 ◽  
Vol 5 ◽  
pp. 276-284
Author(s):  
E. L. Moore ◽  
J. S. Metcalf
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Amorphous Phase ◽  
Elevated Temperatures ◽  
Sodium Tripolyphosphate ◽  
X Ray Diffraction ◽  
Mechanism Of Formation ◽  
X Ray ◽  
Temperature Form ◽  
High Temperature Form

AbstractHigh-temperature X-ray diffraction techniques were employed to study the condensation reactions which occur when sodium orthophosphates are heated to 380°C. Crystalline Na4P2O7 and an amorphous phase were formed first from an equimolar mixture of Na2HPO4·NaH2PO4 and Na2HPO4 at temperatures above 150°C. Further heating resulted in the formation of Na5P3O10-I (high-temperature form) at the expense of the crystalline Na4P4O7 and amorphous phase. Crystalline Na5P3O10-II (low-temperature form) appears after Na5P3O10-I.Conditions which affect the yield of crystalline Na4P2O7 and amorphous phase as intermediates and their effect on the yield of Na5P3O10 are also presented.

Low-Temperature Hydrogenation of Mg-Ni-Nb2O5 Alloy Processed by High-Pressure Torsion

2021 ◽  
pp. 160309
Author(s):  
M. Osorio-García ◽  
K. Suárez-Alcántara ◽  
Y. Todaka ◽  
A. Tejeda-Ochoa ◽  
M. Herrera Ramírez ◽  
...  
Keyword(s):  
High Pressure ◽  
Low Temperature ◽  
High Pressure Torsion

Study of high-pressure air jet controlled compression ignition with compound thermodynamic cycle for combustion and emission formation process

2020 ◽  
pp. 146808742096933
Author(s):  
Xiangyu Meng ◽  
Sicheng Liu ◽  
Jingchen Cui ◽  
Jiangping Tian ◽  
Wuqiang Long ◽  
...  
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Low Temperature ◽  
Formation Process ◽  
Combustion Process ◽  
Thermodynamic Cycle ◽  
Compression Ignition ◽  
Temperature Reaction ◽  
Air Jet ◽  
High Temperature Reaction

A novel method called high-pressure air (HPA) jet controlled compression ignition (JCCI) based on the compound thermodynamic cycle was investigated in this work. The combustion process of premixed mixture can be controlled flexibly by the high-pressure air jet compression, and it characterizes the intensified low-temperature reaction and two-stage high-temperature reaction. The three-dimensional (3D) computational fluid dynamics (CFD) numerical simulation was employed to study the emission formation process and mechanism, and the effects of high-pressure air jet temperature and duration on emissions were also investigated. The simulation results showed that the NOx formation is mainly affected by the first-stage high-temperature reaction due to the higher reaction temperature. Overall, this combustion mode can obtain ultra-low NOx emission. The second-stage high-temperature reaction plays an important role in the CO and THC formation caused by the mixing effect of the high-pressure air and original in-cylinder mixture. The increasing air jet temperature leads to a larger high-temperature in-cylinder region and more fuel in the first-stage reaction, and therefore resulting in higher NOx emission. However, the increasing air jet temperature can significantly reduce the CO and THC emissions. For the air jet duration comparisons, both too short and too long air jet durations could induce higher NOx emission. A higher air jet duration would result in higher CO emission due to the more high-pressure air jet with relatively low temperature.

Low Temperature (4K) and High Pressure (6.5 Kbars) Crystal Structures of (TMTSF)2PF6

1985 ◽  
Vol 119 (1) ◽  
pp. 225-232 ◽  
Author(s):  
Bernard Galiois ◽  
Jacques Gaultier ◽  
Christian Hauw ◽  
Daniel Chasseau ◽  
Alain Meresse ◽  
...  
Keyword(s):  
High Pressure ◽  
Low Temperature ◽  
Crystal Structures
Sign in / Sign up

Export Citation Format

Share Document