Eco-friendly nanostructured Zn–Al layered double hydroxide photocatalysts with enhanced photocatalytic activity

CrystEngComm ◽  
2019 ◽  
Vol 21 (31) ◽  
pp. 4607-4619 ◽  
Author(s):  
Zhe Zhang ◽  
Zhong Hua ◽  
Jihui Lang ◽  
Yuxin Song ◽  
Qi Zhang ◽  
...  

Zn–Al layered double hydroxides (Zn–Al LDHs) with various reaction times were synthesized by a hydrothermal method at constant pH, and they were tested for the removal of RhB with or without post-calcination treatment.

RSC Advances ◽  
2021 ◽  
Vol 11 (40) ◽  
pp. 24747-24751
Author(s):  
Dimy Nanclares ◽  
Alysson F. Morais ◽  
Thainá Calaça ◽  
Ivan G. N. Silva ◽  
Danilo Mustafa

The incorporation of triply charged lanthanides in layered double hydroxides (LDHs) enables the curvature of the LDH sheets, unlocking the possibility of using a soft templating strategy to produce a class of luminescent, hierarchical LDH nanotubes.


Clay Minerals ◽  
2004 ◽  
Vol 39 (2) ◽  
pp. 115-121 ◽  
Author(s):  
Deng-Shiu Yang ◽  
Ming-Kuang Wang ◽  
Shan-Li Wang

AbstractLayered double hydroxides (LDHs) are known as ‘anionic clays’. They comprise a class of material with positively charged octahedral double hydroxyl layers and exchangeable anions. The Li/Al LDH term includes a group of LDHs with Li/Al octahedral double hydroxyl layers. We have demonstrated a modifed method, using Li/Al LDH-OH (OH− as interlayer anions) as the starting material, for preparing Li/Al LDH-X (X represents interlayer anions, including dioctyl sulphosuccinate (DOSS), dodecyl sulphate (DDS), mercaptoacetate (MA), EDTA, Tiron and dichromate) under mild acid conditions (pH in the range 4 to 5). However, in the case of acidsensitive anions, Fe(CN)64−, Li/Al LDH-Fe(CN)64− can be prepared by a two-step procedure using Li/Al LDH-DOSS or similar compounds as intermediates to react with acid-sensitive anions under mild alkaline conditions (pH ≈ 9).


2019 ◽  
Vol 7 (6) ◽  
pp. 2831-2837 ◽  
Author(s):  
Qing Yan ◽  
Peng Yan ◽  
Tong Wei ◽  
Guiling Wang ◽  
Kui Cheng ◽  
...  

A highly-efficient water splitting device is assembled with the platinum sub-nanoclusters functionalized nickel iron layered double hydroxides and hierarchical nickel iron selenides.


RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16419-16436 ◽  
Author(s):  
Michele A. Rocha ◽  
Philippe A. D. Petersen ◽  
Erico Teixeira-Neto ◽  
Helena M. Petrilli ◽  
Fabrice Leroux ◽  
...  

Systems comprising anti-inflammatory sulindac intercalated into biocompatible layered double hydroxides nanovehicles were isolated through one pot synthetic method and showed high crystallinity and curled or scrolled particles.


2018 ◽  
Vol 42 (16) ◽  
pp. 13963-13970 ◽  
Author(s):  
Leila Jafari Foruzin ◽  
Biuck Habibi ◽  
Zolfaghar Rezvani

In this study, ultrasonication, a facile and rapid process, was utilized for the preparation of ternary-component layered double hydroxides (LDHs), Ni3AlxFe1−x-LDHs, as the electrocatalyst material for the oxygen evolution reaction (OER) in a neutral solution.


RSC Advances ◽  
2019 ◽  
Vol 9 (24) ◽  
pp. 13503-13514 ◽  
Author(s):  
Shimaa Gamil ◽  
Waleed M. A. El Rouby ◽  
Manuel Antuch ◽  
I. T. Zedan

Methanol electrooxidation over layered double hydroxides.


2019 ◽  
Vol 7 (24) ◽  
pp. 14483-14488 ◽  
Author(s):  
Zhijuan Liu ◽  
Chung-Li Dong ◽  
Yu-Cheng Huang ◽  
Jiajie Cen ◽  
Haotian Yang ◽  
...  

Herein, we effectively modulate the electronic structure of Co3Fe layered double hydroxides (LDHs) by F-doping using a CHF3-plasma etching technique.


2016 ◽  
Vol 7 (2) ◽  
pp. 1457-1461 ◽  
Author(s):  
Chunping Chen ◽  
Coral F. H. Byles ◽  
Jean-Charles Buffet ◽  
Nicholas H. Rees ◽  
Yue Wu ◽  
...  

We report a general method for the synthesis of core–shell hybrid materials containing a microporous zeolite core with an aqueous miscible organic-layered double hydroxide (AMO-LDH) shell using a simplein situcoprecipitation method.


Clay Minerals ◽  
2017 ◽  
Vol 52 (2) ◽  
pp. 203-215 ◽  
Author(s):  
Kaouther Abderrazek ◽  
Najoua Frini Srasra ◽  
Ezzeddine Srasra

Abstract[Zn-Al] layered double hydroxides (LDH) with cationic molar ratios of R = Zn/Al 1–5 were synthesized by the coprecipitation method at constant pH = 10. The samples synthesized and their derived forms obtained after calcination at 500°C and at 900°C (denoted Zn-Al-R, Zn-Al-R-500 and Zn-Al-R-900, respectively), were characterized by X-ray diffraction (XRD), inductively coupled plasmamass spectrometry, scanning electron microscopy, energy-dispersive X-ray spectroscopy, diffuse reflectance spectroscopy and nitrogen physisorption at −196°C. The XRD study showed: (1) the presence of accessory ZnO with the LDH in samples synthesized with R ≥ 3; and (2) the lamellar structure was destroyed at 500°C which made room for a poorly ordered ZnO phase, while calcination at 900°C yielded well crystallized ZnO and ZnAl2O4. The photocatalytic activity of the calcined and the unheated samples was evaluated for the decolourization of methylene blue. The photocatalytic activity was dependent on the cationic ratio R and on the calcination temperature. The sample Zn-Al-3 displayed maximum photocatalytic activity. Calcination at 500 and 900°C improved the photocatalytic activity of LDH synthesized at R = 1 and 2.


Nanoscale ◽  
2020 ◽  
Vol 12 (14) ◽  
pp. 7888-7894 ◽  
Author(s):  
Wendi Liu ◽  
Ruizheng Liang ◽  
Yanjun Lin

CDs with gradual modulation in structures and optical properties can be obtained through a confined reaction in 2-dimentsonal layered double hydroxides.


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