Synthesis of catalytically active bimetallic nanoparticles within solution-processable metal–organic-framework scaffolds

CrystEngComm ◽  
2019 ◽  
Vol 21 (26) ◽  
pp. 3954-3960 ◽  
Author(s):  
Wendi Zhang ◽  
Shuping Wang ◽  
Fei Yang ◽  
Zhijie Yang ◽  
Huiying Wei ◽  
...  
Keyword(s):  
Metal Ions ◽  
Bimetallic Nanoparticles ◽  
Metal Organic Framework ◽  
Alloy Nanoparticles ◽  
Mixed Metal ◽  
Bimetallic Alloy ◽  
Catalytically Active ◽  
Metal Organic ◽  
Organic Framework

Bimetallic alloy nanoparticles are synthesized by in situ reduction of mixed metal ions inside CD-MOFs.

A dual-functional Cd(ii)–organic-framework demonstrating selective sensing of Zn2+ and Fe3+ ions exclusively and size-selective catalysis towards cyanosilylation

RSC Advances ◽  
2015 ◽  
Vol 5 (14) ◽  
pp. 10119-10124 ◽  
Author(s):  
Xiao-Nan Zhang ◽  
Lin Liu ◽  
Zheng-Bo Han ◽  
Ming-Liang Gao ◽  
Da-Qiang Yuan
Keyword(s):  
Metal Ions ◽  
Metal Organic Framework ◽  
Mixed Metal ◽  
Dual Functional ◽  
Metal Organic ◽  
Selective Catalysis ◽  
Organic Framework

A dual-functional metal–organic-framework can selectively sense Zn2+ and Fe3+ ions over mixed metal ions and displays size-selective catalysis towards cyanosilylation of aldehydes.

Multifunctional luminescent Zn(ii)-based metal–organic framework for high proton-conductivity and detection of Cr3+ ions in the presence of mixed metal ions

2018 ◽  
Vol 47 (5) ◽  
pp. 1383-1387 ◽  
Author(s):  
Xing Meng ◽  
Mei-Jie Wei ◽  
Hai-Ning Wang ◽  
Hong-Ying Zang ◽  
Zi-Yan Zhou
Keyword(s):  
Metal Ions ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
Sensing Properties ◽  
Mixed Metal ◽  
High Proton ◽  
Rectangular Channels ◽  
Metal Organic ◽  
Organic Framework

A luminescent MOF with rectangular channels shows high proton conductivity up to 0.95 × 10−2 S cm−1 and selective Cr3+ sensing properties in presence of mixed metal ions.

Metal ions responsive nanochannel by H2S absorbed in Metal-Organic Framework-based micropipette

2021 ◽  
Author(s):  
Shiyi Tan ◽  
Chenglong Liang ◽  
Yue Zhu ◽  
Nannan Liu ◽  
Jinzheng Zhang ◽  
...  
Keyword(s):  
Metal Ions ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Glass Micropipette ◽  
Organic Framework

Glass micropipette has characteristics of easy fabrication, excellent flexibility and stable properties. The HKUST-1 and MIL-68(In) in-situ grow into the tip of micropipette to construct the porous nanochannel. After absorbing...

Catalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal–Organic Framework Composites

2016 ◽  
Vol 138 (36) ◽  
pp. 11872-11881 ◽  
Author(s):  
Hui Yang ◽  
Siobhan J. Bradley ◽  
Andrew Chan ◽  
Geoffrey I. N. Waterhouse ◽  
Thomas Nann ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Bimetallic Nanoparticles ◽  
Metal Organic Framework ◽  
Catalytically Active ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

An in situ investigation of the thermal decomposition of metal-organic framework NH2-MIL-125 (Ti)

2021 ◽  
Vol 316 ◽  
pp. 110957
Author(s):  
Mian Zahid Hussain ◽  
Mounib Bahri ◽  
Werner R. Heinz ◽  
Quanli Jia ◽  
Ovidiu Ersen ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Metal Organic Framework ◽  
In Situ Investigation ◽  
Metal Organic ◽  
Organic Framework
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