scholarly journals H2 activation by zirconaziridinium ions: σ-bond metathesis versus frustrated Lewis pair reactivity

2020 ◽  
Vol 56 (17) ◽  
pp. 2542-2545 ◽  
Author(s):  
Peter H. M. Budzelaar ◽  
David L. Hughes ◽  
Manfred Bochmann ◽  
Alceo Macchioni ◽  
Luca Rocchigiani
Keyword(s):  
Stepwise Mechanism ◽  
Frustrated Lewis Pair ◽  
Metal Amine

Zirconaziridinium salts cleave H2 by a stepwise mechanism, where initial σ-bond metathesis of the Zr–C bond enables subsequent heterolytic splitting through metal–amine cooperation.

scholarly journals Hydrogenation of secondary amides using phosphane oxide and frustrated Lewis pair catalysis

2021 ◽  
Author(s):  
Laura Köring ◽  
Nikolai A. Sitte ◽  
Markus Bursch ◽  
Stefan Grimme ◽  
Jan Henry Hakan Paradies
Keyword(s):  
Frustrated Lewis Pair ◽  
Secondary Amides

Bis(perchlorocatecholato)silane and Heteroleptic Bidonors: Hidden Frustrated Lewis Pairs by Ring Strain

2021 ◽  
Author(s):  
Deborah Hartmann ◽  
Sven Braner ◽  
Lutz Greb
Keyword(s):  
Ammonia Borane ◽  
Frustrated Lewis Pairs ◽  
Ring Strain ◽  
Frustrated Lewis Pair ◽  
Lewis Pairs

Bis(perchlorocatecholato)silane and bidentate N,N- or N,P-heteroleptic donors form hexacoordinated complexes. Depending on the ring strain and hemilability in the adducts, Frustrated Lewis pair reactivity with aldehydes and catalytic ammonia borane...

A stepwise mechanism for gas-phase unimolecular ion decompositions. Isotope effects in the fragmentation of tert-butoxide anion

1987 ◽  
Vol 109 (4) ◽  
pp. 961-970 ◽  
Author(s):  
William Tumas ◽  
Robert F. Foster ◽  
Mark J. Pellerite ◽  
John I. Brauman
Keyword(s):  
Gas Phase ◽  
Isotope Effects ◽  
Stepwise Mechanism

scholarly journals A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes

2013 ◽  
Vol 5 (8) ◽  
pp. 718-723 ◽  
Author(s):  
Konstantin Chernichenko ◽  
Ádám Madarász ◽  
Imre Pápai ◽  
Martin Nieger ◽  
Markku Leskelä ◽  
...  
Keyword(s):  
Catalytic Reduction ◽  
Frustrated Lewis Pair

Borocation catalysis

2017 ◽  
Vol 46 (15) ◽  
pp. 4874-4887 ◽  
Author(s):  
P. Eisenberger ◽  
C. M. Crudden
Keyword(s):  
Pair Type ◽  
Frustrated Lewis Pair ◽  
Catalytic Reactivity

The synthesis, stability and catalytic reactivity of borocations are described in the context of their reaction in frustrated Lewis pair-type processes.

scholarly journals H2 activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

RSC Advances ◽  
2021 ◽  
Vol 11 (45) ◽  
pp. 28420-28432
Author(s):  
Miho Isegawa ◽  
Takahiro Matsumoto ◽  
Seiji Ogo
Keyword(s):  
Fossil Fuels ◽  
Bond Cleavage ◽  
Clean Fuel ◽  
Frustrated Lewis Pair

Hydrogen is a clean fuel alternative to fossil fuels, and it is vital to develop catalysts for its efficient activation and production.

ChemInform Abstract: Frustrated Lewis Pair Chemistry of Carbon, Nitrogen and Sulfur Oxides

ChemInform ◽  
2014 ◽  
Vol 45 (36) ◽  
pp. no-no
Author(s):  
Douglas W. Stephan ◽  
Gerhard Erker
Keyword(s):  
Sulfur Oxides ◽  
Frustrated Lewis Pair
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