A radical exchange process: synthesis of bicyclo[1.1.1]pentane derivatives of xanthates

2019 ◽  
Vol 55 (99) ◽  
pp. 14976-14979 ◽  
Author(s):  
Saroj Kumar Rout ◽  
Gilles Marghem ◽  
Junjie Lan ◽  
Tom Leyssens ◽  
Olivier Riant
Keyword(s):  
Exchange Process ◽  
Process Synthesis ◽  
New Approach ◽  
Derivatives Of

A new approach for the installation of the bicyclo[1.1.1]pentane unit on the xanthate moiety by means of a radical exchange process.

scholarly journals New approach in the application of lignin for the synthesis of hybrid materials

2017 ◽  
Vol 89 (1) ◽  
pp. 161-171 ◽  
Author(s):  
Beata Podkościelna ◽  
Marta Goliszek ◽  
Olena Sevastyanova
Keyword(s):  
Suspension Polymerization ◽  
Nitrogen Adsorption ◽  
Experimental Protocol ◽  
New Approach ◽  
Surface Areas ◽  
Adsorption Data ◽  
Novel Method ◽  
Derivatives Of ◽  
Polymerization Method ◽  
Nitrogen Adsorption Data

AbstractIn this study, a novel method for the synthesis of hybrid, porous microspheres, including divinylbenzene (DVB), triethoxyvinylsilane (TEVS) and methacrylated lignin (L-Met), is presented. The methacrylic derivatives of kraft lignin were obtained by reaction with methacryloyl chloride according to a new experimental protocol. The course of the modification of lignin was confirmed by attenuated total reflectance (ATR-FTIR) and nuclear magnetic resonance (NMR) spectroscopy. The emulsion-suspension polymerization method was employed to obtain copolymers of DVD, TEVS and L-Met in spherical forms. The porous structures and morphologies of the obtained lignin-containing functionalized microspheres were investigated by low-temperature nitrogen adsorption data and scanning electron microscopy (SEM). The microspheres are demonstrated to be mesoporous materials with specific surface areas in the range of 430–520 m2/g. The effects of the lignin component on the porous structure, shape, swelling and thermal properties of the microspheres were evaluated.

Coupling of Steroid O-(Carboxymethyl)oxime Derivatives with Amino Alcohols

1996 ◽  
Vol 61 (2) ◽  
pp. 288-297 ◽  
Author(s):  
Vladimír Pouzar ◽  
Ivan Černý
Keyword(s):  
Amino Acids ◽  
Hydroxy Group ◽  
Building Blocks ◽  
Amino Alcohols ◽  
New Approach ◽  
Alternative Synthesis ◽  
Oxime Derivatives ◽  
A Chain ◽  
Derivatives Of

New approach to the preparation of steroids with connecting bridge, based on an O-carboxymethyloxime (CMO) structure, and with terminal hydroxy group, is presented. 17-CMO derivatives of 3β-acetoxy- and 3β-methoxymethoxyandrost-5-en-17-one were condensed with α,ω-amino alcohols to give derivatives with a chain of seven to nine atoms. After THP-protection, these compounds were converted to 3-keto-4-ene derivatives. An alternative synthesis consisted in transformation of 17-CMO derivatives with bonded amino acids by reduction of the terminal carboxyl. The resulting compounds were designed as building blocks for the preparation of bis-haptens for sandwich immunoassays.

A New Approach to the Synthesis of Functional Derivatives of 3-(4-Pyridinyl)-1H-indole and 4-(1H-Indol-3-yl)thieno[2,3-b]pyridine

2018 ◽  
Vol 88 (4) ◽  
pp. 682-688 ◽  
Author(s):  
V. V. Dotsenko ◽  
S. G. Krivokolysko ◽  
B. S. Krivokolysko ◽  
K. A. Frolov
Keyword(s):  
New Approach ◽  
Functional Derivatives ◽  
Derivatives Of

Rapid computation of rotary derivatives for subsonic and low transonic flows

2019 ◽  
Vol 36 (9) ◽  
pp. 3108-3121
Author(s):  
Jian-Ming Fu ◽  
Hai-Min Tang ◽  
Hong-Quan Chen
Keyword(s):  
Mach Number ◽  
Normal Velocity ◽  
New Approach ◽  
Content Type ◽  
Strip Theory ◽  
Model Aircraft ◽  
Computational Fluid Dynamics Cfd ◽  
Steady Solutions ◽  
State Pressure ◽  
Derivatives Of

Purpose The purpose of this paper is to develop a new approach for rapid computation of subsonic and low-transonic rotary derivatives with the available steady solutions obtained by Euler computational fluid dynamics (CFD) codes. Design/methodology/approach The approach is achieved by the perturbation on the steady-state pressure of Euler CFD codes. The resulting perturbation relation is established at a reference Mach number between rotary derivatives and normal velocity on surface due to angular velocity. The solution of the reference Mach number is generated technically by Prandtl–Glauert compressibility correction based on any Mach number of interest under the assumption of simple strip theory. Rotary derivatives of any Mach number of interest are then inversely predicted by the Prandtl–Glauert rule based on the reference Mach number aforementioned. Findings The resulting method has been verified for three typical different cases of the Basic Finner Reference Projectile, the Standard Dynamics Model Aircraft and the Orion Crew Module. In comparison with the original perturbation method, the performance at subsonic and low-transonic Mach numbers has significantly improved with satisfactory accuracy for most design efforts. Originality/value The approach presented is verified to be an efficient way for computation of subsonic and low-transonic rotary derivatives, which are performed almost at the same time as an accounting solution of steady Euler equations.

A new approach to the synthesis of functional derivatives of nido-carborane: alkylation of [9-MeS-nido-7,8-C2B9H11]−

2014 ◽  
Vol 43 (13) ◽  
pp. 5044-5053 ◽  
Author(s):  
Maria V. Zakharova ◽  
Igor B. Sivaev ◽  
Sergey A. Anufriev ◽  
Sergey V. Timofeev ◽  
Kyrill Yu. Suponitsky ◽  
...  
Keyword(s):  
New Approach ◽  
Functional Derivatives ◽  
Derivatives Of

scholarly journals Ablative Acceleration of Foils, Their Pulsations, and Interchange Instability

1997 ◽  
Vol 15 (4) ◽  
pp. 495-506
Author(s):  
N.A. Inogamov
Keyword(s):  
Inertial Confinement Fusion ◽  
Inertial Confinement ◽  
Inhomogeneous Distribution ◽  
New Approach ◽  
Promising Tool ◽  
Current State ◽  
Confinement Fusion ◽  
Interchange Instability ◽  
Definition Of ◽  
Derivatives Of

The problem of hydrodynamic stability is important for inertial confinement fusion (ICF) systems based upon high compression of fuel before its ignition. This problem for the case of complicated multilayer foils has been studied here by a new approach describing the development of Rayleigh-Taylor or interchange instability in compressible media with inhomogeneous distribution of “entropy”s = ρ/ρk, ∂ where K = (∂ In ρ/∂ In ρ)s is an adiabatic derivative taken in the local hydrostatic values of ρ and ρ. Inhomogeneous distribution of s simulates the dynamics of development of perturbations of multilayer flyer foils and shells. Besides instability, the same approach has been used for analysis of ID pulsations of a levitated foil. The problem of pulsations is real in the case of foils. Indeed, (1) an ablative acceleration is equivalent to an effective gravity field, which causes the appearance of an atmospheric-type distribution of thermodynamic functions, (2) the duration of ablative flight of foil is at least several times larger than the time that is necessary for an acoustic wave to travel from one side of the foil to another side, and (3) there is a strong initial impulse that initiates the motion of foil. This impulse together with (1, 2) is a reason for the powerful pulsations of foils. The period of pulsations is defined by the velocity of sound in the foil material, which is dependent on the derivatives of an equation of state (EOS). The check of the derivatives gives us finer information concerning the current state of matter and the EOS than the usual measurements of material velocity and pressure that are rougher measures. Therefore, an analysis of pulsations seems to be a promising tool for tracking the dynamics of flyer foil and for the definition of thermodynamic properties of matter.

A New Approach to the Synthesis of Benzylidene Derivatives of 1-(α-Aminobenzyl)-2-naphthols (Betti Bases), Promising Chiral Inductors.

ChemInform ◽  
2007 ◽  
Vol 38 (47) ◽  
Author(s):  
Victor F. Zheltukhin ◽  
Kirill E. Metlushka ◽  
Dilyara N. Sadkova ◽  
Charles E. McKenna ◽  
Boris A. Kashemirov ◽  
...  
Keyword(s):  
New Approach ◽  
Derivatives Of
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