The dilemma between acid and base catalysis in the synthesis of benzimidazole from o-phenylenediamine and carbon dioxide

2019 ◽  
Vol 55 (87) ◽  
pp. 13089-13092 ◽  
Author(s):  
Martin Hulla ◽  
Simon Nussbaum ◽  
Alexy R. Bonnin ◽  
Paul J. Dyson
Keyword(s):  
Carbon Dioxide ◽  
Base Catalysis ◽  
Cyclization Reaction ◽  
Substituted Anilines ◽  
Acid And Base ◽  
Acid And Base Catalysis

Synthesis of azoles from ortho-substituted anilines and CO2 is limited by the cyclization reaction and not by CO2 reduction.

General Acid and Base Catalysis by Phosphate in Peroxyoxalate Chemiluminescence

2016 ◽  
Vol 1 (10) ◽  
pp. 2307-2315 ◽  
Author(s):  
Glalci A. Souza ◽  
Mônica M. M. Peixoto ◽  
Ana P. F. Santos ◽  
Wilhelm J. Baader
Keyword(s):  
Base Catalysis ◽  
Peroxyoxalate Chemiluminescence ◽  
General Acid ◽  
Acid And Base ◽  
Acid And Base Catalysis

scholarly journals “Goldilocks Effect” of Water in Lewis-Brønsted Acid and Base Catalysis

ACS Catalysis ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 4189-4194 ◽  
Author(s):  
Benedict J. Barron ◽  
Wing-Tak Wong ◽  
Pauline Chiu ◽  
King Kuok Hii
Keyword(s):  
Base Catalysis ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Effect Of Water ◽  
Brönsted Acid ◽  
Acid And Base ◽  
Acid And Base Catalysis
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